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The change in the interfacial free energy upon removal of a gas layer on a solid in a liquid per unit area is ΔG, γsl- γsg-ylg, where γ is the interfacial free energy and the subscripts s, 1, and g refer to solid, liquid, and gas phases. Using the Young equation, ΔG, γlg- γlg cos θ, ylg(1, cos θ, The contact angle of water on freshly cleaved HOPG is ≈80° (cos θ ≈0.17, that of ethanol is small (cos θ ≈ 1, the surface free energy of water is about γlg, 72 mJ/m2, and that of ethanol is about γlg, 22 mJ/m2 for the experimental temperature. Substituting these numbers yields ΔGwater ≈-72(1, 0.17, 84 mJ/m2 and ΔGethanol; ≈-221, 1, 44 mJ/m2. All ethanol solutions have intermediate ΔG va
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2. All ethanol solutions have intermediate ΔG values. Now we know that micropancakes existed in water despite this greater incentive for micropancakes to disappear. The inevitable conclusion is that the interfacial free energy is of secondary importance.
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