The effect of dissolution, migration and precipitation of platinum in Nafion®-based membrane electrode assemblies during fuel cell operation at high potential

Journal of Power Sources

Volumn 185, Issue 2, 2008, Pages 1209-1217

  Péron, Jennifer ^a   Nedellec, Yannig ^a   Jones, Deborah J ^a   Rozière, Jacques ^a  

^a UNIVERSITÉ DE MONTPELLIER   (France)

Author keywords

Ageing; Charged platinum species; Degradation; Membrane electrode assembly; Nafion ; Platinum dissolution

Indexed keywords

ABS RESINS; ACIDS; ATOMIC SPECTROSCOPY; CELL MEMBRANES; CONCENTRATION (PROCESS); DEGRADATION; DISSOLUTION; ELECTRIC BATTERIES; ELECTROLYSIS; FREE RADICAL REACTIONS; FREE RADICALS; FUEL CELLS; FUNCTIONAL POLYMERS; HYDROGEN; ION EXCHANGE; MEMBRANES; MICROSCOPIC EXAMINATION; PHOTODEGRADATION; PHOTOELECTRON SPECTROSCOPY; PLATINUM; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); SPECTROSCOPIC ANALYSIS; SPECTRUM ANALYSIS; WATER ANALYSIS;

ACCELERATED AGEING; AGEING; ATOMIC FORCES; CELL POTENTIALS; CELL VOLTAGES; CHARGED PLATINUM SPECIES; CHARGED SPECIES; CONCENTRATION EFFECTS; CROSS OVERS; DISPERSED PARTICLES; END GROUPS; END OF LIVES; ENERGY DISPERSIVE; FUEL CELL OPERATIONS; GAS CONSUMPTIONS; GAS CROSSOVERS; HIGH POTENTIALS; MEMBRANE ELECTRODE ASSEMBLIES; METALLIC CORES; OPEN CIRCUITS; OPERATION CONDITIONS; PENDANT GROUPS; PERFLUOROSULFONIC ACIDS; PLATINUM DISSOLUTION; PLATINUM SPECIES; REPRESENTATIVE SAMPLES; TRANSMISSION ELECTRONS; WATER PRODUCTIONS; X-RAY PHOTOELECTRON SPECTROSCOPIES;

X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 56349150774     PISSN: 03787753     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jpowsour.2008.06.098     Document Type: Article

References (43)

1. Jones D.J., and Rozière J. J. Membr. Sci. 185 (2001) 41
2. Rozière J., and Jones D.J. Annu. Rev. Mater. Res. 33 (2003) 503
3. Hickner M.A., Ghassemi H., Kim Y.S., Einsla B.R., and McGrath J.E. Chem. Rev. 104 (2004) 4587
4. Péron J., Ruiz E., Jones D.J., and Rozière J. J. Membr. Sci. 314 (2008) 247
5. Borup R., Meyers J., Pivovar B., Kim Y.S., Mukundan R., Garland N., Myers D., Wilson M., Garzon F., Wood D., Zelenay P., More K., Stroh K., Zawodzinski T., Boncella J., McGrath J.E., Inaba M., Miyatake K., Hori M., Ota K., Ogumi Z., Miyata S., Nishikata A., Siroma Z., Uchimoto Y., Yasuda K., Kimijima K.-i., and Iwashita N. Chem. Rev. 107 (2007) 3904
6. De Bruijn F.A., Dam V.A.T., and Janssen G.J.M. Fuel Cells 8 (2008) 3
7. Curtin D.E., Lousenberg R.D., Henry T.J., Tangeman P.C., and Tisack M.E. J. Power Sources 131 (2004) 41
8. Aragane J., Murahashi T., and Odaka T. J. Electrochem. Soc. 135 (1988) 844
9. Wilson M.S., Garzon F.H., Sickafus K.E., and Gottesfeld S. J. Electrochem. Soc. 140 (1993) 2872
10. Ferreira P.J., la O' G.J., Shao-Horn Y., Morgan D., Makharia R., Kocha S., and Gasteiger H.A. J. Electrochem. Soc. 152 (2005) A2256
11. Ohma A., Suga S., Yamamoto S., and Shinohara K. J. Electrochem. Soc. 154 (2007) B757
12. Peron J., Jones D.J., and Rozière. ECS Trans. 11 Proton Exchange Membrane Fuel Cells 7, Part 1 (2007) 71
13. Yu P., Pemberton M., and Plasse P. J. Power Sources 144 (2005) 11
14. Colon-Mercado H.R., and Popov B.N. J. Power Sources 155 (2006) 253
15. Healy J., Hayden C., Xie T., Olson K., Waldo R., Brundage M., Gasteiger H., and Abbott J. Fuel Cells 5 (2005) 302
16. Mittal V.O., Kunz H.R., and Fenton J.M. J. Electrochem. Soc. 153 (2006) A1755
17. Inaba M., Kinumoto T., Kiriake M., Umebayashi R., Tasaka A., and Ogumi Z. Electrochim. Acta 51 (2006) 5746
18. Liu W., and Zuckerbrod D. J. Electrochem. Soc. 152 (2005) A1165
19. Hommura S., Kawahara K., Shimohira T., and Teraoka Y. J. Electrochem. Soc. 159 (2007) A29
20. Finsterwalder F., Quintus M., Schalsoke M., Guth T., and Frank G.S. Abstract No. 485 210th ECS Meeting. Los Angeles (2006)
21. Aoki M., Uchida H., and Watanabe M. Electrochem. Commun. 8 (2006) 1509
22. Sakai T., Takenaka H., Wakabayashi N., Kawami Y., and Torikai E. J. Electrochem. Soc. 132 (1985) 1328
23. Hommura S., Kawahara K., and Shimohira T.S. Abstract No. 803, 207th ECS Meeting. Quebec City, Canada (2005)
24. Resnick P. seminar (2007), ENSCM, Montpellier, France
25. Chen C., Levitin G., Hess D.W., and Fuller T.F. J. Power Sources 169 (2007) 288
26. Teranishi K., Kawata K., Tsushima S., and Hirai S. Electrochem. Solid-State Lett. 9 (2006) A475
27. Mittal V.O., Kunz H.R., and Fenton J.M. Electrochem. Solid-State Lett. 9 (2006) A299
28. Endoh E., Terazono S., Widjaja H., and Takimoto Y. Electrochem. Solid-State Lett. 7 (2004) A209
29. Xie J., Wood III D.L., More K.L., Atanassov P., and Borup R.L. J. Electrochem. Soc. 152 (2005) A1011
30. Darling R.M., and Meyers J.P. J. Electrochem. Soc. 150 (2003) A1523
31. Dam V.A.T., and de Bruijn F.A. J. Electrochem. Soc. 154 (2007) B494
32. Wang X., Kumar R., and Myers D.J. Electrochem. Solid-State Lett. 9 (2006) A225
33. Yasuda K., Taniguchi A., Akita T., Ioroi T., and Siroma Z. Phys. Chem. Chem. Phys. 8 (2006) 746
34. Yu J., Matsuura T., Yoshikawa Y., Nazrul Islam M., and Hori M. Phys. Chem. Chem. Phys. 7 (2005) 373
35. Guilminot E., Corcella A., Charlot F., Maillard F., and Chatenet M. J. Electrochem. Soc. 154 (2007) B96
36. Akita T., Taniguchi A., Maekawa J., Siroma Z., Tanaka K., Kohyama M., and Yasuda K. J. Power Sources 159 (2006) 461
37. Darling R.M., and Meyers J.P. J. Electrochem. Soc. 152 (2005) A242
38. Schulze M., Schneider A., and Gulzow E. J. Power Sources 127 (2004) 213
39. Schulze M., Lorenz M., Wagner N., and Gulzow E. Fresenius J. Anal. Chem. 365 (1999) 106
40. Huang C., Tan K.S., Lin J., and Tan K.L. Chem. Phys. Lett. 371 (2003) 80
41. Kinumoto T., Inaba M., Nakayama Y., Ogata K., Umebayashi R., Tasaka A., Iriyama Y., Abe T., and Ogumi Z. J. Power Sources 158 (2006) 1222
42. Inaba M., Yamada H., Tokunaga J., Umebayashi R., Matsuzawa A., and Tasaka A. Abstract No. 1196, 210th ECS Meeting. Los Angeles (2006)
43. Markovic N.M., Gasteiger H.A., and Ross P.N. J. Phys. Chem. 99 (1995) 3411