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56049090619
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In solution exothermic triplet energy transfer is usually nearly diffusion limited and in most cases does not tend to show an inverted behavior at high exothermicities. This may reflect the accommodation of large exothermicities by energy transfer to higher triplet states of A. Exothermic energy transfer involving highly distorted triplets may be less than diffusion limited in solution and give rise to lower h 0 values in rigid media
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56049125096
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For highly-allowed singlet-singlet coulombic energy transfer from 1-cnloroanthracene (1CA) to perylene (P) the half-quenching distance at which the energy-transfer rate constant, ket, equals the radiative rate constant of 1CA of ∼108 s-1 is ∼40 Å (Turro, N. J. Modern Molecular Photochemistry; University Science Books, Sausalito, CA, 1991; pp 322-324, Assuming the extent of overlap of D emission and A absorption remains nearly constant ket varies as the radiative rate, kD, of the excited donor × the extinction coefficient, ε, of the A transition and inversely as the sixth power of the separation distance, r Turro, N. J. Modern Molecular Photochemistry; University Science Books, Sausalito, CA, 1991; p 303, For 3PXAN, kD is only about 10-7 × kD for 1CA, and for the S0-T1 transition of TPDC, ε
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56049090617
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19d indicates that electron-transfer kinetics in rigid media appears to be functionally independent of orientation, i.e., angle averaged, at times > 1 ns.
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19d indicates that electron-transfer kinetics in rigid media appears to be functionally independent of orientation, i.e., angle averaged, at times > 1 ns.
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55
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56049109368
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33D and A in contact may not be appropriate when they are separated by molecules of the medium.
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33D and A in contact may not be appropriate when they are separated by molecules of the medium.
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