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The [PF6, anion does not appear to act as a nucleophile toward oxidized forms of 1, Co2Fv(CO)4, PF6 ]2 was isolated by performing a bulk electrolysis of 1 in CH2Cl2/0.05 M [NBu4][B(C6F 5)4] at 273 K, Eappl, 0.85 V, to generate 12, followed by addition of [NBu4][PF6, which provided a purple solid having the appropriate IR spectrum in Nujol (2147, 2121, 2100 (sh) cm-1) and elemental analysis [C, 24.94 (25.72 cale, H. 1.23 1.53 cale
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The difficulty in delineating between fast square schemes and concerted electron-transfer/structural change mechanisms has been recently discussed in: Geiger, W. E. Organometallics 2007, 26, 5738
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The difficulty in delineating between fast square schemes and concerted electron-transfer/structural change mechanisms has been recently discussed in: Geiger, W. E. Organometallics 2007, 26, 5738.
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