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Volumn 27, Issue 21, 2008, Pages 5624-5631

Characterization of the successive one-electron oxidation products of the dicobalt fulvalenediyl (Fv) compound Co2Fv(CO)4 and its phosphine-substituted product

Author keywords

[No Author keywords available]

Indexed keywords

AMPEROMETRIC; CO GROUPS; CONTROLLED PROCESSES; DICATION; ELECTRON OXIDATION PRODUCTS; ELECTRON PROCESSES; GLASSY CARBON ELECTRODES; IN-SITU; IR SPECTROSCOPIES; NEUTRAL COMPOUNDS; RADICAL CATIONS; SPECTROELECTROCHEMICAL METHODS; SUBSTITUTED PRODUCTS; SUBSTITUTION PRODUCTS; SUBSTITUTION RATES; SUPPORTING ELECTROLYTES; VOLTAMMETRIC;

EID: 56049083738     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800546d     Document Type: Article
Times cited : (91)

References (68)
  • 1
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    • References for homodinuclear metal carbonyl complexes are given in refs 2-5. For heterodinuclear examples see: (a) Lacoste, M.; DelvilleDesbois, M.-H.; Ardoin, N.; Astruc, D. Organometallics 1997, 16, 2343.
    • References for homodinuclear metal carbonyl complexes are given in refs 2-5. For heterodinuclear examples see: (a) Lacoste, M.; DelvilleDesbois, M.-H.; Ardoin, N.; Astruc, D. Organometallics 1997, 16, 2343.
  • 13
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    • 3.
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    • 2nd ed, Kissinger, P. T, Heineman, W. R, Eds, Marcel Dekker: New York, Chapter 23
    • Geiger, W. E. In Laboratory Techniques in Electroanalytical Chemistry, 2nd ed.; Kissinger, P. T., Heineman, W. R., Eds.; Marcel Dekker: New York, 1996; Chapter 23.
    • (1996) Laboratory Techniques in Electroanalytical Chemistry
    • Geiger, W.E.1
  • 50
    • 56049104804 scopus 로고    scopus 로고
    • The [PF6, anion does not appear to act as a nucleophile toward oxidized forms of 1, Co2Fv(CO)4, PF6 ]2 was isolated by performing a bulk electrolysis of 1 in CH2Cl2/0.05 M [NBu4][B(C6F 5)4] at 273 K, Eappl, 0.85 V, to generate 12, followed by addition of [NBu4][PF6, which provided a purple solid having the appropriate IR spectrum in Nujol (2147, 2121, 2100 (sh) cm-1) and elemental analysis [C, 24.94 (25.72 cale, H. 1.23 1.53 cale
    • -1) and elemental analysis [C, 24.94 (25.72 cale); H. 1.23 (1.53 cale)].
  • 52
    • 56049125867 scopus 로고    scopus 로고
    • Reference 17, pp 210-214
    • Reference 17, pp 210-214.
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    • Bard, A. J, Ed, Marcel Dekker, Inc, New York
    • Osteryoung, J.; O'Dea, J. J. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker, Inc.: New York, 1986; Vol. 14, pp 231-237.
    • (1986) Electroanalytical Chemistry , vol.14 , pp. 231-237
    • Osteryoung, J.1    O'Dea, J.J.2
  • 56
    • 56049108711 scopus 로고    scopus 로고
    • Weil, J. A.; Bolton, J. R.; Wertz, J. E. Electron Paramagnetic Resonance; John Wiley & Sons: New York, 1994; p 116. For the uniaxial hyperfine constant of Co, see p 534
    • Weil, J. A.; Bolton, J. R.; Wertz, J. E. Electron Paramagnetic Resonance; John Wiley & Sons: New York, 1994; p 116. For the uniaxial hyperfine constant of Co, see p 534
  • 68
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    • The difficulty in delineating between fast square schemes and concerted electron-transfer/structural change mechanisms has been recently discussed in: Geiger, W. E. Organometallics 2007, 26, 5738
    • The difficulty in delineating between fast square schemes and concerted electron-transfer/structural change mechanisms has been recently discussed in: Geiger, W. E. Organometallics 2007, 26, 5738.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.