A comparative study of the 1-hexene hydroformylation either under syngas conditions or with paraformaldehyde catalyzed by rhodium/diphosphine systems

Catalysis Letters

Volumn 126, Issue 3-4, 2008, Pages 367-370

  Rosales, Merlín ^a   Arrieta, Federico ^b   Baricelli, Pablo ^c   González, Ángel ^a   González, Beatriz ^a   Guerrero, Yusbeli ^a   Moratinos, Cristhina ^a   Pacheco, Inés ^a   Pérez, Homero ^a   Urdaneta, Johán ^b  

^a UNIVERSIDAD DEL ZULIA   (Venezuela)

^b FACULTAD DE CIENCIAS VETERINARIAS   (Venezuela)

^c UNIVERSIDAD DE CARABOBO   (Venezuela)

Author keywords

1 Hexene; Diphosphines; Hydroformylation; Paraformaldehyde; Rhodium; Syngas

Indexed keywords

ACETAL RESINS; ADDITION REACTIONS; ALDEHYDES; CHEMICAL REACTIONS; HYDROFORMYLATION; HYDROXYLATION; KETONES; LIGANDS; ORGANIC COMPOUNDS; PHOSPHORUS; REACTION RATES; RHODIUM; RHODIUM COMPOUNDS; SULFUR COMPOUNDS;

1-HEXENE; ACTIVE SYSTEMS; CARBON CHAINS; CARBONYL COMPLEXES; CATALYTIC SYSTEMS; COMPARATIVE STUDIES; DFT CALCULATIONS; DIPHOSPHINE; DIPHOSPHINE LIGANDS; DIPHOSPHINES; HEPTANAL; HEXANAL; IN-SITU; METAL CENTERS; OXIDATIVE ADDITION REACTIONS; PARAFORMALDEHYDE; PHOSPHOROUS ATOMS; PRE CATALYSTS; STERIC EFFECTS; SYN GASSES; SYNGAS;

RATE CONSTANTS;

EID: 55849127426     PISSN: 1011372X     EISSN: 1572879X     Source Type: Journal    
DOI: 10.1007/s10562-008-9633-z     Document Type: Article

References (25)

1. Frohning CD, Kohlpaintner CW, Bohnen H-W (2002) In: Cornils B, Herrmann WA (eds) Applied homogeneous catalysis with organometallic compounds, 2nd edn, vol 1, chap 2.2.1. Wiley-VCH, Weinheim, pp 31-103
2. Gates BC (1992) Catalytic chemistry. Wiley, New York
3. Gates BC, Katzer JR, Schuit GCA (1979) Chemistry of catalytic processes. McGraw-Hill, New York
4. Parshall GW, Ittel SD (1992) Homogeneous catalysis, 2nd edn. Wiley Interscience, New York
5. GW Parshall WA Nugent 1988 Chemtech 18 184
6. Van Leeuwen PCJ, Casey C, Whiteker G (2000) In: Van Leeuwen PCJ, Claver C (eds) Rhodium catalyzed hydroformylation, chap 4. Kluwer Academic Publishers, Dordrecht
7. T Kobayashi H Konishi J Kihi 1982 Tetrahedron Lett 23 4967
8. G Jenner EM Nahmed S Libs-Konrath 1991 J Mol Catal 64 337
9. K Aika H Sekija A Ozaki 1984 C1 Mol Chem 1 65
10. JR Blackborow RJ Daroda G Wilkinson 1982 Coord Chem Rev 43 17
11. JM Lassaletta R Fernández C Gasch J Vasquez 1996 Tetrahedron 52 9143
12. HS Ahn SH Han SJ Uhm WK Scok HN Lee GA Korneeva 1999 J Mol Catal A Chem 144 295
13. M Rosales A González B González C Moratinos H Pérez J Urdaneta RA Sánchez-Delgado 2005 J Organomet Chem 690 3095
14. YS Varshavskii TG Cherkasova 1967 Russ J Inorg Chem (Engl Transl) 12 899
15. J Casado MA López-Quintela FM Lorenzo-Barral 1986 J Chem Ed 63 450
16. AD Becke 1993 J Chem Phys 98 5648
17. C Lee W Yang RG Parr 1988 Phys Rev B 37 785
18. B Miehlich A Savin H Stoll H Preuss 1989 Chem Phys Lett 157 200
19. JB Collins PVR Schleyer JS Binkley JA Pople 1967 J Chem Phys 64 5142
20. KD Dobbs WJ Hehre 1987 J Comput Chem 8 880
21. MS Gordon 1980 Chem Phys Lett 76 163
22. K Raghavachari GW Trucks 1989 J Chem Phys 91 1062
23. M Rosales Á González Y Guerrero I Pacheco RA Sánchez-Delgado 2007 J Mol Catal 270 241
24. LA van der Veen MDK Boele FR Bregman PCJ Kamer PWNM van Leeuwen K Goubitz J Fraanje H Schenk C Bo 1998 J Am Chem Soc 120 11616
25. JM Brown AG Kent J Chem 1987 Soc Perkin Trans 2 1597