Kinetics and mechanisms of homogeneous catalytic reactions. Part 6. Hydroformylation of 1-hexene by use of Rh(acac)(CO)2/dppe [dppe = 1,2-bis(diphenylphosphino)ethane] as the precatalyst

Journal of Molecular Catalysis A: Chemical

Volumn 270, Issue 1-2, 2007, Pages 241-249

  Rosales, Merlin ^a   González, Angel ^a   Guerrero, YusbeIi ^a   Pacheco, Inés ^a   Sánchez Delgado, Roberto A ^b  

^a FACULTAD DE CIENCIAS VETERINARIAS   (Venezuela)

^b CITY UNIVERSITY OF NEW YORK   (United States)

Author keywords

1 Hexene; Hydroformylation; Kinetics; Mechanisms; Rhodium complexes

Indexed keywords

CARBON MONOXIDE; CATALYST ACTIVITY; COMPLEXATION; HYDROFORMYLATION; OLEFINS; RHODIUM COMPOUNDS;

BRANCHED RATIOS; HYDROGEN CONCENTRATION; PRECATALYSTS; RHODIUM CATALYSTS; RHODIUM COMPLEXES;

HEXANE;

EID: 34247275899     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2007.01.044     Document Type: Article

References (38)

1. Frohning C.D., Kohlpaintner C.W., and Bohnen H.-W. In: Cornils B., and Herrmann W.A. (Eds). Applied Homogeneous Catalysis with Organometallic Compounds. 2nd ed. vol. 1 (2002), Wiley-VCH, Weinheim 31-103 (Ch. 2.2.1)
2. Gates B.C. Catalytic Chemistry (1992), John Wiley & Sons, New York
3. Gates B.C., Katzer J.R., and Schuit G.C.A. Chemistry of Catalytic Processes" (1979), McGraw-Hill, New York
4. Parshall G.W., and Ittel S.D. Homogeneous Catalysis. 2nd ed. (1992), Wiley-Interscience, New York
5. Parshall G.W., and Nugent W.A. CHEMTECH (1988) 184
6. Van Leeuwen P.C.J., and Claver C. Rhodium Catalyzed Hydroformylation (2000), Kluwer Academic Publishers
7. Bianchini C., Lee H.M., Meli A., and Vizza F. Organometallics 19 (2000) 849
8. Cavalieri d'Óro P., Raimondi L., Pagani G., Montrasi G., Gragorio G., and Andreeta A. Chim. Ind. (Milan) 62 (1982) 572
9. Kiss G., Mozeleski E.J., Nadler K.C., VanDriessche E., and DeRoover C. J. Mol. Catal. A: Chem. 138 (1999) 155
10. Deshpande R.M., and Chaudhari R.V. Ind. Eng. Chem. Res. 27 (1988) 1996
11. Divekar S.S., Deshpande R.M., and Chaudhari R.V. Catal. Lett. 21 (1993) 191
12. Bhanage B.M., Divekar S.S., Deshpande R.M., and Chaudhari R.V. J. Mol. Catal. A: Chem. 115 (1997) 247
13. Jongama T., Challa G., and Van Leuwen P.W.N.M. J. Organomet. Chem. 421 (1991) 121
14. Van Rooy A., Orij E.N., Kamer P.C.J., Van der Aardweg F., and Van Leeuwen P.W.N.M. J. Chem. Soc. Chem. Commun. (1991) 1096
15. Van Rooy A., Orij E.N., Kamer P.C.J., and Van Leeuwen P.W.N.M. Organometallics 14 (1995) 34
16. Van Rooy A., De Bruijn J.N.H., Roobeek K.F., Kamer P.C.J., and Van Leeuwen P.W.N.M. J. Organomet. Chem. 507 (1996) 69
17. Horiuchi T., Shirakawa E., Nozaki K., and Takaya H. Organometallics 16 (1997) 2981
18. Van Rooy A., Kamer P.C.J., Van Leeuwen P.W.N.M., Goubitz K., Fraanje J., Veldman N., and Spek A.L. Organometallics 15 (1996) 835
19. Bergounhou C., Neibecker D., and Mathieu R. J. Mol. Catal. A: Chem. 1220 (2004) 167
20. Srivastava V.K., Sharma S.K., Shukla R.S., Subrahmanyam N., and Jasra R.V. Ind. Eng. Chem. Res. 44 (2005) 1764
21. Chapter 4 of reference 3 and references therein.
22. In: Pignolet L.H. (Ed). Homogeneous Catalysis with Metal Phosphine Complexes (1983), Plenum Press, New York Chapters 2, 5, 6 and 8
23. Unruh J.D., and Christenson J.R. J. Mol. Catal. 14 (1982) 19
24. Hughes O.R., and Unruh J.D. J. Mol. Catal. 12 (1981) 71
25. Hughes O.R., and Young D.A. J. Am. Chem. Soc. 103 (1982) 6636
26. del Río I., Pàmies O., Van Leeuwen P.W.N.M., and Claver C. J. Organometal. Chem. 608 (2000) 115
27. Damoense L., Datt M., Green M., and Steenkamp C. Coord. Chem. Rev. 248 (2004) 2393
28. Varshavskii Y.S., and Cherkasova T.G. Russ. J. Inorg. Chem. (Engl. Transl) 12 (1967) 899
29. Casado J., López-Quintela y M.A., and Lorenzo-Barral F.M. J. Chem. Ed. 63 (1986) 450
30. Brunner J. Chem. Eng. Data 30 (1985) 269
31. Jongkee P., Xiaohua Y., Khalid A.M., Robert Jr. L., and Robinson. J. Chem. Data 40 (1995) 245
32. James B.R., and Mahajan D. Can. J. Chem. 57 (1979) 180
33. James B.R., Mahajan D., Rettig S.J., and Williams G.M. Organometallics 2 (1983) 1452
34. Evans D., Yagupsky G., and Wilkinson G. J. Chem. Soc. (A) (1968) 2660
35. Yagupski G., Brown C.K., and Wilkinson G. J. Chem. Soc. (A) (1970) 1392
36. Fung D.C.M., and James B.R. Gazz. Chim. Ital. 122 (1992) 329
37. Castellanos-Páez A., Castillón S., Claver C., van Leeuwen P.W.N.M., and de Lange W.G.J. Organometallics 17 (1998) 2543
38. van der Veen L.A., Keeven P.H., Schoemaker G.C., Reek J.N.H., Kamer P.C.J., van Leeuwen P.W.N.M., Lutz M., and Spek A.L. Organometallics 19 (2000) 872