-
2
-
-
0032317917
-
-
An early review on coordination polymerization of epoxides is available Kuran, W. Prog. Polym. Sci. 1998, 23, 919-992
-
An early review on coordination polymerization of epoxides is available Kuran, W. Prog. Polym. Sci. 1998, 23, 919-992.
-
-
-
-
7
-
-
55649124260
-
-
Kutner, A, Vandenberg, E. J, Hercules Powder Company Polymerization of Epoxides. U.S. Patent 3,186,958, June 1, 1965
-
Kutner, A.; Vandenberg, E. J. (Hercules Powder Company) Polymerization of Epoxides. U.S. Patent 3,186,958, June 1, 1965.
-
-
-
-
8
-
-
36048992422
-
-
Labbé, A.; Carlotti, S.; Billouard, C.; Desbois, P.; Deffieux, A. Macromolecules 2007, 40, 7842-7847.
-
(2007)
Macromolecules
, vol.40
, pp. 7842-7847
-
-
Labbé, A.1
Carlotti, S.2
Billouard, C.3
Desbois, P.4
Deffieux, A.5
-
9
-
-
0028408475
-
-
Aluminum phenoxide as co-catalyst, see: a
-
Aluminum phenoxide as co-catalyst, see: (a) Sugimoto, H.; Kawamura, C.; Kuroki, M.; Aida, T.; Inoue, S. Macromolecules 1994, 27, 2013-2018.
-
(1994)
Macromolecules
, vol.27
, pp. 2013-2018
-
-
Sugimoto, H.1
Kawamura, C.2
Kuroki, M.3
Aida, T.4
Inoue, S.5
-
10
-
-
0028769236
-
-
(b) Akatsuka, M.; Aida, T.; Inoue, S. Macromolecules 1994, 27, 2820-2825.
-
(1994)
Macromolecules
, vol.27
, pp. 2820-2825
-
-
Akatsuka, M.1
Aida, T.2
Inoue, S.3
-
11
-
-
47749141585
-
-
Xie, H.-Q.; Guo, J.-S.; Yu, G.-Q.; Zu, J. J. Appl. Polym. Sci. 2001, 80, 2446-2454.
-
(2001)
J. Appl. Polym. Sci
, vol.80
, pp. 2446-2454
-
-
Xie, H.-Q.1
Guo, J.-S.2
Yu, G.-Q.3
Zu, J.4
-
12
-
-
0000614744
-
-
(a) Kuran, W.; Listos, T.; Abramczyk, M; Dawidek, A. J. Macromol. Sci., Pure Appl. Chem. 1998, A35, 421-437.
-
(1998)
J. Macromol. Sci., Pure Appl. Chem
, vol.A35
, pp. 421-437
-
-
Kuran, W.1
Listos, T.2
Abramczyk, M.3
Dawidek, A.4
-
13
-
-
0035910215
-
-
(b) Chisholm, M. H.; Navarro-Llobet, D; Simonsick, W. J., Jr Macromolecules 2001, 34, 8851-8857.
-
(2001)
Macromolecules
, vol.34
, pp. 8851-8857
-
-
Chisholm, M.H.1
Navarro-Llobet, D.2
Simonsick Jr, W.J.3
-
14
-
-
0037414923
-
-
(c) Braune, W.; Okuda, J. Angew. Chem., Int. Ed. 2003, 42, 64-68.
-
(2003)
Angew. Chem., Int. Ed
, vol.42
, pp. 64-68
-
-
Braune, W.1
Okuda, J.2
-
15
-
-
0037442478
-
-
(d) Chisholm, M. H.; Gallucci, J.; Navarro-Llobet, D.; Zhen, H. Polyhedron 2003, 22, 557-561.
-
(2003)
Polyhedron
, vol.22
, pp. 557-561
-
-
Chisholm, M.H.1
Gallucci, J.2
Navarro-Llobet, D.3
Zhen, H.4
-
16
-
-
33646776415
-
-
(a) Zevaco, T. A.; Sypien, J.; Janssen, A.; Walter, O.; Dinjus, E. Catal. Today 2006, 115, 151-161.
-
(2006)
Catal. Today
, vol.115
, pp. 151-161
-
-
Zevaco, T.A.1
Sypien, J.2
Janssen, A.3
Walter, O.4
Dinjus, E.5
-
17
-
-
33947572973
-
-
(b) Zevaco, T. A.; Sypien, J, K.; Janssen, A.; Walter, O.; Dinjus, E. J. Orgnomet. Chem. 2007, 692, 1963-1973.
-
(2007)
J. Orgnomet. Chem
, vol.692
, pp. 1963-1973
-
-
Zevaco, T.A.1
Sypien, J.K.2
Janssen, A.3
Walter, O.4
Dinjus, E.5
-
19
-
-
0034090570
-
-
(b) Taden, I.; Kang, H.-C.; Massa, W.; Spaniol, T. P.; Okuda, J. Eur. J. Inorg. Chem. 2000, 441-445.
-
(2000)
Eur. J. Inorg. Chem
, pp. 441-445
-
-
Taden, I.1
Kang, H.-C.2
Massa, W.3
Spaniol, T.P.4
Okuda, J.5
-
20
-
-
0035964503
-
-
(c) Liu, Y.-C.; Ko, B.-T.; Lin, C.-C. Macromolecules 2001, 34, 6196-6201.
-
(2001)
Macromolecules
, vol.34
, pp. 6196-6201
-
-
Liu, Y.-C.1
Ko, B.-T.2
Lin, C.-C.3
-
21
-
-
0035956467
-
-
(d) Chen, H.-L.; Ko, B.-T.; Huang, B.-H.; Lin, C.-C. Organometallics 2001, 20, 5076-5083.
-
(2001)
Organometallics
, vol.20
, pp. 5076-5083
-
-
Chen, H.-L.1
Ko, B.-T.2
Huang, B.-H.3
Lin, C.-C.4
-
22
-
-
0037118825
-
-
(e) Hsueh, M.-L.; Huang, B.-H.; Lin, C.-C. Macromolecules 2002, 35, 5763-5768.
-
(2002)
Macromolecules
, vol.35
, pp. 5763-5768
-
-
Hsueh, M.-L.1
Huang, B.-H.2
Lin, C.-C.3
-
23
-
-
0038334918
-
-
(f) Liao, T.-C.; Huang, Y.-L.; Huang, B.-H.; Lin, C.-C. Macromol. Chem. Phys. 2003, 204, 885-892.
-
(2003)
Macromol. Chem. Phys
, vol.204
, pp. 885-892
-
-
Liao, T.-C.1
Huang, Y.-L.2
Huang, B.-H.3
Lin, C.-C.4
-
24
-
-
7544233801
-
-
(g) Chen, C.-T.; Huang, C.-A.; Huang, B.-H. Macromolecules 2004, 37, 7968-7973.
-
(2004)
Macromolecules
, vol.37
, pp. 7968-7973
-
-
Chen, C.-T.1
Huang, C.-A.2
Huang, B.-H.3
-
25
-
-
10644263491
-
-
(h) Lewiński, J.; Horeglad, P.; Tratkiewicz, E.; Grzenda, W.; Lipkowski, J.; Kolodziejczyk, E. Macromol. Rapid Commun. 2004, 25, 1939-1942.
-
(2004)
Macromol. Rapid Commun
, vol.25
, pp. 1939-1942
-
-
Lewiński, J.1
Horeglad, P.2
Tratkiewicz, E.3
Grzenda, W.4
Lipkowski, J.5
Kolodziejczyk, E.6
-
27
-
-
0031556464
-
-
(b) Miyamoto, M.; Saeki, Y.; Lee, C. W.; Kimura, Y.; Maeda, H.; Tsutsui, K. Macromolecules 1997, 30, 6067-6073.
-
(1997)
Macromolecules
, vol.30
, pp. 6067-6073
-
-
Miyamoto, M.1
Saeki, Y.2
Lee, C.W.3
Kimura, Y.4
Maeda, H.5
Tsutsui, K.6
-
28
-
-
0037414923
-
-
Braune, W.; Okuda, J. Angew. Chem., Int. Ed. 2003, 42, 64-68.
-
(2003)
Angew. Chem., Int. Ed
, vol.42
, pp. 64-68
-
-
Braune, W.1
Okuda, J.2
-
29
-
-
13244269745
-
-
Wasserman, E. P.; Annis, I.; Chopin, L. J., III; Price, P. C.; Peterson, J. L.; Abboud, K. A. Macromolecules 2005, 38, 322-333.
-
(2005)
Macromolecules
, vol.38
, pp. 322-333
-
-
Wasserman, E.P.1
Annis, I.2
Chopin III, L.J.3
Price, P.C.4
Peterson, J.L.5
Abboud, K.A.6
-
32
-
-
55649088183
-
-
Cottone, A., III; Scott, M. J, Abstracts of Papers, 220th ACS National Meeting, Washington, DC, August 20-24, 2000; American Chemical Society: Washington, DC, 2000; INOR-031.
-
(a) Cottone, A., III; Scott, M. J, Abstracts of Papers, 220th ACS National Meeting, Washington, DC, August 20-24, 2000; American Chemical Society: Washington, DC, 2000; INOR-031.
-
-
-
-
33
-
-
55649107218
-
-
Scott, M J.; Cottone, A., III; Lecuivre, J. L, Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30, 2000; American Chemical Society: Washington, DC, 2000; INOR-421.
-
(b) Scott, M J.; Cottone, A., III; Lecuivre, J. L, Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30, 2000; American Chemical Society: Washington, DC, 2000; INOR-421.
-
-
-
-
34
-
-
55649116362
-
-
Dinger, M. B.; Scott, M. J, Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30, 2000; American Chemical Society: Washington, DC, 2000; INOR-420.
-
(c) Dinger, M. B.; Scott, M. J, Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30, 2000; American Chemical Society: Washington, DC, 2000; INOR-420.
-
-
-
-
35
-
-
55649108365
-
-
Cottone, A., III; Scott, M. J. , Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30, 2000; American Chemical Society: Washington, DC, 2000; INOR-208.
-
(d) Cottone, A., III; Scott, M. J. , Book of Abstracts, 219th ACS National Meeting, San Francisco, CA, March 26-30, 2000; American Chemical Society: Washington, DC, 2000; INOR-208.
-
-
-
-
36
-
-
0032544562
-
-
(a) Ooi, T.; Miura, T.; Maruoka, K. Angew. Chem., Int. Ed. 1998, 37, 2347-2349.
-
(1998)
Angew. Chem., Int. Ed
, vol.37
, pp. 2347-2349
-
-
Ooi, T.1
Miura, T.2
Maruoka, K.3
-
37
-
-
0942287127
-
-
(b) Ooi, T.; Takahashi, M.; Yamada, M.; Tayama, E.; Omoto, K.; Maruoka, K. J. Am. Chem. Soc. 2004, 126, 1150-1160.
-
(2004)
J. Am. Chem. Soc
, vol.126
, pp. 1150-1160
-
-
Ooi, T.1
Takahashi, M.2
Yamada, M.3
Tayama, E.4
Omoto, K.5
Maruoka, K.6
-
38
-
-
0032556244
-
-
(c) Konsler, R. G.; Karl, J.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 10780-10781.
-
(1998)
J. Am. Chem. Soc
, vol.120
, pp. 10780-10781
-
-
Konsler, R.G.1
Karl, J.2
Jacobsen, E.N.3
-
39
-
-
33645455679
-
-
Thakur, S. S.; Chen, S.-W; Li, W.; Shin, C.-K.; Kim, S.-J.; Koo, Y.-M.; Kim, G.-J. J Organomet. Chem 2006, 691, 1862-1872.
-
(d) Thakur, S. S.; Chen, S.-W; Li, W.; Shin, C.-K.; Kim, S.-J.; Koo, Y.-M.; Kim, G.-J. J Organomet. Chem 2006, 691, 1862-1872.
-
-
-
-
40
-
-
12344281516
-
-
(e) Yang, J.; Yu, Y.; Li, Q.; Li, Y.; Cao, A J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 373-384.
-
(2005)
J. Polym. Sci., Part A: Polym. Chem
, vol.43
, pp. 373-384
-
-
Yang, J.1
Yu, Y.2
Li, Q.3
Li, Y.4
Cao, A.5
-
41
-
-
55649117911
-
-
Turner, H. W, Dales, G. C, VanErden, L, van Beek, J. A. M, to Symyx Technologies Inc, U.S. Patent No. 6,306,658
-
(a) Turner, H. W.; Dales, G. C., VanErden, L.; van Beek, J. A. M. (to Symyx Technologies Inc.) U.S. Patent No. 6,306,658.
-
-
-
-
43
-
-
55649085456
-
-
Vandenberg demonstrated that addition of 0.05-0.5 equiv of Lewis base brought significant activity improvement for TiBA-catalyzed polymerization of EO, while using 0.25 and 0.5 equiv of Lewis base gave highest activity (ref. 4). We confirmed Vandenberg's finding by testing TiBA as catalysts for EO polymerization in a glass reactor in the presence of various Lewis bases; and found that excess (> 0.5 equiv) base resulted in a loss of activity. Therefore, we used 0.5 equiv of Lewis base in this work.
-
Vandenberg demonstrated that addition of 0.05-0.5 equiv of Lewis base brought significant activity improvement for TiBA-catalyzed polymerization of EO, while using 0.25 and 0.5 equiv of Lewis base gave highest activity (ref. 4). We confirmed Vandenberg's finding by testing TiBA as catalysts for EO polymerization in a glass reactor in the presence of various Lewis bases; and found that excess (> 0.5 equiv) base resulted in a loss of activity. Therefore, we used 0.5 equiv of Lewis base in this work.
-
-
-
-
44
-
-
55649111071
-
-
The ratio of productivities for TiBA- and DEAC-based catalysts based on bulky ligands such as 7e is probably even larger than is shown in Figure 2 because the runs were made at 5 μmol A1. At this catalyst concentration, the productivities of TiBA-based catalysts with very bulky ligands are underestimated, as can be seen in Table 5.
-
The ratio of productivities for TiBA- and DEAC-based catalysts based on bulky ligands such as 7e is probably even larger than is shown in Figure 2 because the runs were made at 5 μmol A1. At this catalyst concentration, the productivities of TiBA-based catalysts with very bulky ligands are underestimated, as can be seen in Table 5.
-
-
-
-
46
-
-
0035827010
-
-
Antelmann, B.; Chisholm, M. H.; Iyer, S. S.; Huffman, J. C.; Navarro-Llobet, D.; Pagel, M.; Simonsick, W. J.; Zhong, W. Macromolecules 2001, 34, 3159-3175.
-
(2001)
Macromolecules
, vol.34
, pp. 3159-3175
-
-
Antelmann, B.1
Chisholm, M.H.2
Iyer, S.S.3
Huffman, J.C.4
Navarro-Llobet, D.5
Pagel, M.6
Simonsick, W.J.7
Zhong, W.8
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