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No hydrogen bonding could be detected for 1b, 2a or 2b at this concentration. It should therefore be a valid assumption that 1a is also free of intermolecular hydrogen bonding. In addition it seems from the litterature (refs. 4d, 15a, 17, 18a) that amide concentrations around 1 mM are generally found to be free of intermolecular hydrogen bonding.
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3 is certainly lower, probably 2-3 kcal/mol.
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