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Volumn 130, Issue 44, 2008, Pages 14853-14860

Spiroacetal biosynthesis in insects from diptera to hymenoptera: The Giant Ichneumon wasp Megarhyssa nortoni nortoni Cresson

Author keywords

[No Author keywords available]

Indexed keywords

BIOCHEMICAL ENGINEERING; BIOCHEMISTRY; CARBOXYLATION; KETONES;

EID: 55549137430     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8036433     Document Type: Article
Times cited : (14)

References (26)
  • 9
    • 0033708968 scopus 로고    scopus 로고
    • A survey of the occurrence of spiroacetals in insects across the orders Hymenoptera, Hemiptera, Diptera, and Coleoptera is presented in ref 1. In addition, see: (a) Tu, Y. Q.; Hübener, A.; Zhang, H.; Moore, C. J.; Fletcher, M. T.; Hayes, P.; Dettner, K.; Francke, W.; McErlean, C. S.; Kitching, W. Synthesis 2000, 13, 1956.
    • A survey of the occurrence of spiroacetals in insects across the orders Hymenoptera, Hemiptera, Diptera, and Coleoptera is presented in ref 1. In addition, see: (a) Tu, Y. Q.; Hübener, A.; Zhang, H.; Moore, C. J.; Fletcher, M. T.; Hayes, P.; Dettner, K.; Francke, W.; McErlean, C. S.; Kitching, W. Synthesis 2000, 13, 1956.
  • 13
    • 5044238111 scopus 로고    scopus 로고
    • For a color photo of this spectacular wasp, see: Fletcher, M. T.; Wood, B. J.; Schwartz, B. D.; Rahm, F.; Lambert, L. K.; Brereton, I. M.; Moore, C. J.; De Voss, J. J.; Kitching, W. Arkivoc 2004, 10, 109 (issue dedicated to Professor R. Rickards).
    • (c) For a color photo of this spectacular wasp, see: Fletcher, M. T.; Wood, B. J.; Schwartz, B. D.; Rahm, F.; Lambert, L. K.; Brereton, I. M.; Moore, C. J.; De Voss, J. J.; Kitching, W. Arkivoc 2004, 10, 109 (issue dedicated to Professor R. Rickards).
  • 14
    • 55549122210 scopus 로고    scopus 로고
    • For further discussion of the underlying arguments, see ref 6a and its Supporting Information
    • For further discussion of the underlying arguments, see ref 6a and its Supporting Information.
  • 15
    • 55549117689 scopus 로고    scopus 로고
    • 2 mixture.
    • 2 mixture.
  • 22
    • 55549095881 scopus 로고    scopus 로고
    • A pathway in which hydroxylation of 2,6-undecanediol to the triol precedes C6 oxidation is also possible and is analogous to one recently proposed for B. oleae and B. cacuminata. However, the significant amount of dihydropyran 3 found in M. nortoni (formed via dehydrative cyclization of 21) suggests that 21 is a bona fide intermediate.
    • A pathway in which hydroxylation of 2,6-undecanediol to the triol precedes C6 oxidation is also possible and is analogous to one recently proposed for B. oleae and B. cacuminata. However, the significant amount of dihydropyran 3 found in M. nortoni (formed via dehydrative cyclization of 21) suggests that 21 is a bona fide intermediate.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.