메뉴 건너뛰기




Volumn 14, Issue 32, 2008, Pages 10074-10084

Solvent-mediated generation of cobalt-cluster-stabilised propargyl cations and radicals: Allyl migration versus peroxide formation

Author keywords

Allylsilanes; Benzylsilanes; Cluster compounds; Cobalt; Peroxides

Indexed keywords

CATION; COBALT; MORPHINAN DERIVATIVE; N PROPARGYL; N-PROPARGYL; ORGANOMETALLIC COMPOUND; PEROXIDE; SOLVENT;

EID: 55449100513     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801402     Document Type: Article
Times cited : (14)

References (98)
  • 3
    • 0000134381 scopus 로고
    • Eds, G. Wilkinson, F. G. A. Stone, E. W. Abel) Pergamon, Oxford UK, Chapter 7.1, pp
    • c) A. J. M. Caffyn, K. M. Nicholas, in Comprehensive Organometallic Chemistry II, Vol. 12 (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel) Pergamon, Oxford (UK), 1995, Chapter 7.1, pp. 685-702;
    • (1995) Comprehensive Organometallic Chemistry II , vol.12 , pp. 685-702
    • Caffyn, A.J.M.1    Nicholas, K.M.2
  • 5
    • 0038553029 scopus 로고
    • Coord. Chem. Rev. 1995, 143, 331-381;
    • (1995) Coord. Chem. Rev , vol.143 , pp. 331-381
  • 19
    • 0031882648 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 1998, 37, 161-164.
    • (1998) Angew. Chem. Int. Ed , vol.37 , pp. 161-164
  • 59
    • 59849087241 scopus 로고    scopus 로고
    • available from
    • Mercury 1.4.2, available from http://www.ccdc.cam.ac.uk/mercury/
    • Mercury 1.4.2
  • 61
    • 0000753731 scopus 로고    scopus 로고
    • 6(alkynol)] clusters, see: D. Braga, F. Grepioni, D. Walther, K. Heubach, A. Schmidt, W. Imhof, H. Görls, T. Klettke, Organometallics 1997, 16, 4910-4919.
    • 6(alkynol)] clusters, see: D. Braga, F. Grepioni, D. Walther, K. Heubach, A. Schmidt, W. Imhof, H. Görls, T. Klettke, Organometallics 1997, 16, 4910-4919.
  • 62
    • 0007201961 scopus 로고    scopus 로고
    • Other examples, involving hydrogen-bonded ferrocenylalkynols, have been reported in: a H. Schottenberger, K. Wurst, M. R. Buchmeiser, J. Organomet. Chem. 1999, 584, 301 -309;
    • Other examples, involving hydrogen-bonded ferrocenylalkynols, have been reported in: a) H. Schottenberger, K. Wurst, M. R. Buchmeiser, J. Organomet. Chem. 1999, 584, 301 -309;
  • 65
    • 55449129375 scopus 로고    scopus 로고
    • One could also envisage that the formation of the saturated cluster 24, rather than the fluorenyl analogue of the alcohol 15, may have occurred by dehydration, as from 15 to 11, and subsequent hydrogenation through reaction of the acid with cobalt-containing decomposition products.
    • One could also envisage that the formation of the saturated cluster 24, rather than the fluorenyl analogue of the alcohol 15, may have occurred by dehydration, as from 15 to 11, and subsequent hydrogenation through reaction of the acid with cobalt-containing decomposition products.
  • 66
    • 55449118099 scopus 로고    scopus 로고
    • Crystal data for 24: C24H11Co 3O9, MI=620.12, monoclinic, space group P2 1/n, 14, a, 8.702(6, 6, 30.56(2, c, 26.752(19) Å, β= 98.679(12)°, V=7032(9) Å3, Z, 12, ρcalcd 1.757 g cm3, μ, 2.151 mm-1, 7=173 K, R1, 0.1098
    • 1, = 0.1098.
  • 67
    • 19944411532 scopus 로고    scopus 로고
    • Head-to-tail propargyl-allene dimers, which are conventionally prepared by copper-mediated coupling of bromoallenes, exhibit photochromism in the solid state: J. L. Scott, K. Tanaka, Cryst. Growth Des. 2005, 5, 1209-1213, and references therein.
    • Head-to-tail propargyl-allene dimers, which are conventionally prepared by copper-mediated coupling of bromoallenes, exhibit photochromism in the solid state: J. L. Scott, K. Tanaka, Cryst. Growth Des. 2005, 5, 1209-1213, and references therein.
  • 69
    • 55449115288 scopus 로고    scopus 로고
    • P. D. Robinson, Y. Hou, C. Y. Myers, Acta Crystallogr. Sect. C 1999, 55, 9900147.
    • P. D. Robinson, Y. Hou, C. Y. Myers, Acta Crystallogr. Sect. C 1999, 55, 9900147.
  • 95
    • 55449096016 scopus 로고    scopus 로고
    • SMART, Release 5.611, Bruker AXS Inc, Madison, WI 53711, 2000
    • SMART, Release 5.611, Bruker AXS Inc., Madison, WI 53711, 2000.
  • 96
    • 55449112627 scopus 로고    scopus 로고
    • SAINT, Release 6.02a, Bruker AXS Inc, Madison, WI 53711, 2000
    • SAINT, Release 6.02a, Bruker AXS Inc., Madison, WI 53711, 2000.
  • 97
    • 55449087676 scopus 로고    scopus 로고
    • G.M. Sheldrick, SADABS, Bruker AXS Inc., Madison, WI 53711, 2000.
    • G.M. Sheldrick, SADABS, Bruker AXS Inc., Madison, WI 53711, 2000.
  • 98
    • 55449130353 scopus 로고    scopus 로고
    • G. M. Sheldrick, SHELXTL, Version 5.1, Bruker AXS Inc, Madison, WI 53711, 1998
    • G. M. Sheldrick, SHELXTL, Version 5.1, Bruker AXS Inc., Madison, WI 53711, 1998.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.