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Volumn , Issue 31, 2008, Pages 4851-4855

Spin canting in a cobalt(II) radical complex with an acentric counter anion

Author keywords

Cobalt; Crystal engineering; Metamagnets; Organic radicals; Spin canting

Indexed keywords

CHLORINE COMPOUNDS; NEGATIVE IONS;

EID: 55249118617     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800824     Document Type: Article
Times cited : (11)

References (30)
  • 12
    • 0033792105 scopus 로고    scopus 로고
    • and references are therein
    • e) O. Kahn, Acc. Chem. Res. 2000, 33, 647-657 and references are therein.
    • (2000) Acc. Chem. Res , vol.33 , pp. 647-657
    • Kahn, O.1
  • 15
    • 85163230723 scopus 로고    scopus 로고
    • Crystal data for 1: C21H35N 5ClCoF6O4P, 660.89 gmol-1, monoclinic P21/c, a, 10.2864(12, b, 26.122(3, c, 11.3897(13) Å, β, 111.063(2)°, V, 2856.0(6) Å3, Z, 4, T, 200 K, R1, 0.0638, Rw, 0.0759 (all, obsd, Crystal data for 2: C 21H35N5Cl2CoO8, 615.37 gmol-1, orthorhombic Pna21, a, 17.039(4, b, 14.977(4, c, 10.774(3) Å, V, 2749.6(12) Å3, Z, 4, T, 200 K, R1, 0.0337, Rw, 0.0606 (all, obsd, CCDC-692610 (for 1) and -692611 (for 2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
    • 3, Z = 4, T = 200 K, R1 = 0.0337, Rw = 0.0606 (all, obsd.). CCDC-692610 (for 1) and -692611 (for 2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 17
    • 85163228101 scopus 로고    scopus 로고
    • In the analyses of the magnetic data for 1 and 2, the g value was fixed to 2.0. Note that the orbital term of the cobalt(II) ion was included as the effective angular momentum term. The least-squares calculation for 1 yielded δ, 580.0 K, λ, 275.1 K, and k, 0.70, and the same parameter set was used for 2
    • In the analyses of the magnetic data for 1 and 2, the g value was fixed to 2.0. Note that the orbital term of the cobalt(II) ion was included as the effective angular momentum term. The least-squares calculation for 1 yielded δ = 580.0 K, λ = -275.1 K, and k = 0.70, and the same parameter set was used for 2.
  • 20
    • 85163231510 scopus 로고    scopus 로고
    • 0 values.
    • 0 values.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.