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Crystal data for 1: C21H35N 5ClCoF6O4P, 660.89 gmol-1, monoclinic P21/c, a, 10.2864(12, b, 26.122(3, c, 11.3897(13) Å, β, 111.063(2)°, V, 2856.0(6) Å3, Z, 4, T, 200 K, R1, 0.0638, Rw, 0.0759 (all, obsd, Crystal data for 2: C 21H35N5Cl2CoO8, 615.37 gmol-1, orthorhombic Pna21, a, 17.039(4, b, 14.977(4, c, 10.774(3) Å, V, 2749.6(12) Å3, Z, 4, T, 200 K, R1, 0.0337, Rw, 0.0606 (all, obsd, CCDC-692610 (for 1) and -692611 (for 2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
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3, Z = 4, T = 200 K, R1 = 0.0337, Rw = 0.0606 (all, obsd.). CCDC-692610 (for 1) and -692611 (for 2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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85163228101
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In the analyses of the magnetic data for 1 and 2, the g value was fixed to 2.0. Note that the orbital term of the cobalt(II) ion was included as the effective angular momentum term. The least-squares calculation for 1 yielded δ, 580.0 K, λ, 275.1 K, and k, 0.70, and the same parameter set was used for 2
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