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The lack of conductivity in acetone rules out for 2 the alternative ionic structure consisting of a cationic dinuclear Pt(ii) complex with a bridging chloride and electrically balanced by the other chloride acting as the counteranion In solution, complex 2 decomposed after few days at RT but was stable for several months at 273 K; hence, NMR spectra were recorded at that temperature -1005
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1H} NMR signals and the appearance of several new signals, conceivably due to blocking intramolecular rearrangements involving different conformers of both isomers, hampered a precise integral calculation The assignment of the absolute configuration was made according to Cahn-Ingold-Prelog system: -291
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55149095252
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2 (D, Table S2). The signals of the latter compound disappeared in the NMR spectrum recorded after few hours at RT
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72
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55149104263
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note
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2, 295 K) which can be removed by washing the dichloromethane solution with water: see Experimental section
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73
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0001240506
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Examples of substitutions of secondary or primary phosphanes with a tertiary one can be found in ref. 3(c) and 5(c)
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