Ruthenium carbonyl clusters derived from pyrazolyl substituted diphosphazanes: Crystal and molecular structure of a triruthenium cluster featuring a triply bridging μ3-η1: η1:η1 coordination mode of pyrazolate moiety

Journal of Organometallic Chemistry

Volumn 691, Issue 1-2, 2006, Pages 224-228

  Venkatakrishnan, Thengarai S ^a   Nethaji, Munirathinam ^a   Krishnamurthy, Setharampattu S ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

3 1: 1: 1 Pyrazolyl coordination; Chirality; P N ligands; Phosphane phosphido clusters; Ruthenium carbonyl clusters

Indexed keywords

CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; REACTION KINETICS; RUTHENIUM COMPOUNDS; SUBSTITUTION REACTIONS;

P-N LIGANDS; PHOSPHANE-PHOSPHIDO CLUSTERS; RUTHENIUM CARBONYL CLUSTERS;

COMPLEXATION;

EID: 28944445463     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2005.06.047     Document Type: Article

References (44)

1. P. Braunstein L.A. Oro P.R. Raithby Metal Clusters in Chemistry vol. I-III 1999 Wiley-VCH Weinheim See vol. II for an overview on the application of metal clusters in catalysis
2. M. Ichikawa Adv. Catal. 38 1992 283
3. D.F. Shriver H.D. Kaesz R.D. Adams The Chemistry of Metal Cluster Complexes 1990 VCH Publishers New York
4. J.A. Cabeza Eur. J. Inorg. Chem. 2002 1559
5. J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, S. García-Granda, L. Martínez-Méndez, and E. Pérez-Carreñ Chem. Eur. J. 10 2004 6265
6. T.S. Venkatakrishnan, M. Nethaji, and S.S. Krishnamurthy Curr. Sci. 85 2003 969
7. K. Raghuraman, S.S. Krishnamurthy, and M. Nethaji J. Organomet. Chem. 669 2003 79
8. T.S. Venkatakrishnan, S.S. Krishnamurthy, and M. Nethaji J. Organomet. Chem. 690 2005 4001
9. M.S. Balakrishna, V.S. Reddy, S.S. Krishnamurthy, J.F. Nixon, and J.C.T.R. Burckett St. Laurent Coord. Chem. Rev. 129 1994 1
10. K. Raghuraman, S.K. Mandal, T.S. Venkatakrishnan, S.S. Krishnamurthy, and M. Nethaji Proc. Indian Acad. Sci. (Chem. Sci.) 114 2002 233
11. S.K. Mandal, G.A.N. Gowda, S.S. Krishnamurthy, T. Stey, and D. Stalke J. Organomet. Chem. 690 2005 742
12. M. Ganesan, S.S. Krishnamurthy, and M. Nethaji J. Organomet. Chem. 690 2005 1080
13. R.P.K. Babu, S.S. Krishnamurthy, and M. Nethaji Tetrahedron: Asymmetry 6 1995 427
14. R.P.K. Babu, K. Aparna, S.S. Krishnamurthy, and M. Nethaji Phosphorus Sulfur Silicon 103 1995 39
15. M.I. Bruce, T.W. Hambley, B.K. Nicholson, and M.R. Snow J. Organomet. Chem. 235 1982 83
16. Bruker smart, V. 6.028 1998 Bruker AXS Inc. Madison, Wisconsin, USA
17. Bruker saint, V. 6.02 1998 Bruker AXS Inc. Madison, Wisconsin, USA
18. G.M. Sheldrick sadabs 1997 University of Göttingen Germany
19. Bruker shelxtl, NT V. 5.10 1998 Bruker AXS Inc. Madison, Wisconsin, USA
20. L.J. Farrugia J. Appl. Crystallogr. 32 1999 837
21. G.M. Sheldrick shelxl-97, Program for Refinement of Crystal Structures 1997 University of Göttingen Germany
22. -3.
23. G.B. Deacon, E.E. Delbridge, C.M. Forsyth, B.W. Skelton, and A.H. White J. Chem. Soc., Dalton. Trans. 2000 745
24. T. Beringhelli, G. D'Alfanso, M. Panigati, P. Mercandelli, and A. Sironi Chem. Eur. J. 8 2002 5340
25. S. Trofimenko Prog. Inorg. Chem. 34 1986 115
26. G. Lamonica, and G.A. Ardizzoia Prog. Inorg. Chem. 46 1997 151
27. A.P. Sadimenko, and S.S. Basson Coord. Chem. Rev. 147 1996 247
28. J.E. Cosgriff, and G.B. Deacon Angew. Chem. Int. Ed. 37 1998 286
29. A.P. Sadimenko Adv. Heterocyl. Chem. 80 2001 157
30. G.B. Deacon, C.M. Forsyth, A. Gitlits, B.W. Skelton, and A.H. White Dalton Trans. 2004 1239
31. G.B. Deacon, A. Gitlits, P.W. Roesky, M.R. Bürgstein, K.C. Lim, B.W. Skelton, and A.H. White Chem. Eur. J. 7 2001 127
32. G.B. Deacon, C.M. Forsyth, A. Gitlits, R. Harika, P.C. Junk, B.W. Skelton, and A.H. White Angew. Chem. Int. Ed. 41 2002 3249
33. C. Yelamos, M.J. Heeg, and C.H. Winter Inorg. Chem. 37 1998 3892
34. D. Cauzzi, C. Graiff, C. Massera, G. Predieri, and A. Tiripicchio J. Cluster Sci. 12 2001 259
35. E. Simón-Manso, and C.P. Kubiak Inorg. Chem. Commun. 6 2003 1096
36. S-T. Liu, X. Hu, F. Chang, Y.-C. Liu, E.-R. Ding, B.-F. Wu, and Z.-R. Zhao Polyhedron 21 2002 1073
37. Z. Weng, and L.Y. Goh Acc. Chem. Res. 37 2004 187
38. X. Zhong, S.-G. Ang, and H.-G. Ang J. Organomet. Chem. 689 2004 361
39. G. Hogarth, F. Sarýkahya, and O.S. pentürk Polyhedron 21 2002 791
40. N.J. Taylor, P.C. Chieh, and A.J. Carty Chem. Commun. 1975 448
41. R. Bender, S.E. Bouaoud, P. Braunstein, Y. Dusausoy, N. Merabet, J. Raya, and D. Rouag J. Chem. Soc., Dalton Trans. 1999 735
42. M.A. Bennett, D.E. Berry, T. Dirnberger, D.C.R. Hockless, and E. Wenger J. Chem. Soc., Dalton Trans. 1998 2367
43. R. Bender, P. Braunstein, A. Dedieu, P.D. Ellis, B. Huggins, P.D. Harvey, E. Sappa, and A. Tiripichio Inorg. Chem. 35 1996 1223
44. 2)} spectroscopic data; such a cluster is formed as a result of P-N bond cleavage and oxidative sulfur transfer [5].