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Volumn 47, Issue 39, 2008, Pages 7457-7460

Highly enantioselective hydrogenation of aryl vinyl ketones to allylic alcohols catalyzed by the tol-binap/Dmapen ruthenium(II) complex

Author keywords

Allylic compounds; Asymmetric catalysis; Hydrogenation; Ketones; Ruthenium

Indexed keywords


EID: 54749115518     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200802533     Document Type: Article
Times cited : (70)

References (34)
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  • 5
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    • Xyl-binap=2,2′-bis(di-3,5-xylylphosphanyl)-1,1′-binaphthyl. Daipen=1,1-di(4-anisyl)-2-isopropyl-1,2-ethylenediamine. Tolbinap= 2,2′-bis(di-4-tolylphosphanyl)-1,1′-binaphthyl. Dmapen=2- dimethylamino-1-phenylethylamine. Dpen=1,2-diphenylethylenediamine.
    • Xyl-binap=2,2′-bis(di-3,5-xylylphosphanyl)-1,1′-binaphthyl. Daipen=1,1-di(4-anisyl)-2-isopropyl-1,2-ethylenediamine. Tolbinap= 2,2′-bis(di-4-tolylphosphanyl)-1,1′-binaphthyl. Dmapen=2- dimethylamino-1-phenylethylamine. Dpen=1,2-diphenylethylenediamine.
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    • Hydrogenation of 1a with a chiral iridium catalyst gave the allylic alcohol in 9% ee and 56% yield. See: C. Bianchini, E. Farnetti, L. Glendenning, M. Graziani, G. Nargin, M. Peruzzini, E. Rocchini, F. Zanobini, Organometallics 1995, 14, 1489-1502.
    • Hydrogenation of 1a with a chiral iridium catalyst gave the allylic alcohol in 9% ee and 56% yield. See: C. Bianchini, E. Farnetti, L. Glendenning, M. Graziani, G. Nargin, M. Peruzzini, E. Rocchini, F. Zanobini, Organometallics 1995, 14, 1489-1502.
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    • Conjugate reduction of 1a by hydrogenation or transfer hydrogenation with metal complexes. See: a L. Dahlenburg, K. Herbst, A. Zahl, J. Organomet. Chem. 2000, 616, 19-28;
    • Conjugate reduction of 1a by hydrogenation or transfer hydrogenation with metal complexes. See: a) L. Dahlenburg, K. Herbst, A. Zahl, J. Organomet. Chem. 2000, 616, 19-28;
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    • Isolated 2h was readily decomposed at ambient temperature.
    • Isolated 2h was readily decomposed at ambient temperature.
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    • Repulsive interaction between the filled p and d orbitals has also been postulated: K. G. Caulton, New J. Chem. 1994, 18, 25-41.
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    • Si.
    • Si.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.