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Volumn 47, Issue 41, 2008, Pages 7888-7891

Oxygenation of a Me2Zn/α-diimine system: A unique zinc methylperoxide cluster and evidence for its sequential decomposition pathways

Author keywords

Cubanes; N ligands; Oxygenation; Peroxides; Zinc

Indexed keywords

1,3 BUTADIENE DERIVATIVE; DIMETHYLZINC; ORGANOMETALLIC COMPOUND; OXYGEN; PEROXIDE;

EID: 54749110971     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803254     Document Type: Article
Times cited : (64)

References (44)
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    • To the best of our knowledge, there are no reports of zinc methylperoxide complexes and so far only one transition-metal complex with an OOMe ligand has been structurally authenticated: M. Ahijado, T. Braun, D. Noveski, N. Kocher, B. Neumann, D. Stalke, H.-G. Stammler, Angew. Chem. 2005, 117, 7107-7111;
    • To the best of our knowledge, there are no reports of zinc methylperoxide complexes and so far only one transition-metal complex with an OOMe ligand has been structurally authenticated: M. Ahijado, T. Braun, D. Noveski, N. Kocher, B. Neumann, D. Stalke, H.-G. Stammler, Angew. Chem. 2005, 117, 7107-7111;
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    • 2Zn(R′-DAB) type adducts.
    • 2Zn(R′-DAB) type adducts.
  • 27
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    • 2 are not available.
    • 2 are not available.
  • 28
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    • • radical can be trapped directly by compound 2 to form 3 or, alternatively, this radical can abstract hydrogen from the solution bulk to produce MeOH and subsequently recombine with 2.
    • • radical can be trapped directly by compound 2 to form 3 or, alternatively, this radical can abstract hydrogen from the solution bulk to produce MeOH and subsequently recombine with 2.
  • 29
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    • 6): δ = 0.93 (s, 9H), 1.02 (s, 9H), 3.09 (br s, 1H), 3.37 (s, 3H), 4,43 (d, J = 7.2 Hz, 2H), 7.28 ppm (d, J = 7.2 Hz, 2H).
    • 6): δ = 0.93 (s, 9H), 1.02 (s, 9H), 3.09 (br s, 1H), 3.37 (s, 3H), 4,43 (d, J = 7.2 Hz, 2H), 7.28 ppm (d, J = 7.2 Hz, 2H).
  • 32
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    • To the best of our knowledge, the only previous well-documented examples of main-group metal alkylperoxide complexes undergoing homolysis are aluminum derivatives: S. S. Kumar, S. Singh, H. W. Roesky, Inorg. Chem. 2005, 44, 1199-1201;
    • To the best of our knowledge, the only previous well-documented examples of main-group metal alkylperoxide complexes undergoing homolysis are aluminum derivatives: S. S. Kumar, S. Singh, H. W. Roesky, Inorg. Chem. 2005, 44, 1199-1201;
  • 34
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    • This mode of decomposition is often observed for transition metal alkylperoxides, where O-O homolytic cleavage is facilitated by oxidation of the metal center: N. Lehnert, R. Y. N. Ho, L. Que, Jr, E. I. Solomon, J. Am. Chem. Soc. 2001, 123, 8271-8290;
    • This mode of decomposition is often observed for transition metal alkylperoxides, where O-O homolytic cleavage is facilitated by oxidation of the metal center: N. Lehnert, R. Y. N. Ho, L. Que, Jr., E. I. Solomon, J. Am. Chem. Soc. 2001, 123, 8271-8290;
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    • and references therein
    • Angew. Chem. Int. Ed. Engl. 2006, 45, 2965-2969, and references therein.
    • (2006) Angew. Chem. Int. Ed. Engl , vol.45 , pp. 2965-2969


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.