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For selected recent examples, see: a) M. Á. Fernández- Ibáñez, B. Maciá, A. J. Minnaard, B. L. Feringa, Angew. Chem. 2008, 120, 1337-1339;
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Cozzi, P.G.1
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c) P. G. Cozzi, Angew. Chem. 2007, 119, 2620-2623;
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54749113208
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g) for a review, see: M. P. Bertrand, S. Feray, C. Gastaldi, Chimia 2002, 56, 623-638.
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20
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54749101269
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To the best of our knowledge, there are no reports of zinc methylperoxide complexes and so far only one transition-metal complex with an OOMe ligand has been structurally authenticated: M. Ahijado, T. Braun, D. Noveski, N. Kocher, B. Neumann, D. Stalke, H.-G. Stammler, Angew. Chem. 2005, 117, 7107-7111;
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To the best of our knowledge, there are no reports of zinc methylperoxide complexes and so far only one transition-metal complex with an OOMe ligand has been structurally authenticated: M. Ahijado, T. Braun, D. Noveski, N. Kocher, B. Neumann, D. Stalke, H.-G. Stammler, Angew. Chem. 2005, 117, 7107-7111;
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27544431532
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See, for example: a
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See, for example: a) G. van Koten, K. Vrieze, Adv. Organomet. Chem. 1982, 21, 151-239;
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Adv. Organomet. Chem
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van Koten, G.1
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24
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0000981079
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a) M. Kaupp, H. Stall, H. Preuss, W. Kahn, T. Stahl, G. van Koten, E. Wissing, W. J. J. Smeets, A. L. Spek, J. Am. Chem. Soc. 1991, 113, 5606-5618;
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Stahl, T.5
van Koten, G.6
Wissing, E.7
Smeets, W.J.J.8
Spek, A.L.9
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25
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0005998089
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b) E. Wissing, S. van der Lieden, E. Rijnberg, J. Boersma, W. J. J. Smeets, A. L. Spek, G. van Koten, Organometallics 1994, 13, 2602-2608.
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Rijnberg, E.3
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Smeets, W.J.J.5
Spek, A.L.6
van Koten, G.7
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26
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-
54749128705
-
-
2Zn(R′-DAB) type adducts.
-
2Zn(R′-DAB) type adducts.
-
-
-
-
27
-
-
54749121016
-
-
2 are not available.
-
2 are not available.
-
-
-
-
28
-
-
54749108444
-
-
• radical can be trapped directly by compound 2 to form 3 or, alternatively, this radical can abstract hydrogen from the solution bulk to produce MeOH and subsequently recombine with 2.
-
• radical can be trapped directly by compound 2 to form 3 or, alternatively, this radical can abstract hydrogen from the solution bulk to produce MeOH and subsequently recombine with 2.
-
-
-
-
29
-
-
54749154171
-
-
6): δ = 0.93 (s, 9H), 1.02 (s, 9H), 3.09 (br s, 1H), 3.37 (s, 3H), 4,43 (d, J = 7.2 Hz, 2H), 7.28 ppm (d, J = 7.2 Hz, 2H).
-
6): δ = 0.93 (s, 9H), 1.02 (s, 9H), 3.09 (br s, 1H), 3.37 (s, 3H), 4,43 (d, J = 7.2 Hz, 2H), 7.28 ppm (d, J = 7.2 Hz, 2H).
-
-
-
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30
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0035801365
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R. P. Davies, D. J. Linton, P. Schooler, R. Snaith, A. E. H. Wheatley, Chem. Eur. J. 2001, 7, 3696-3704;
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32
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14744295373
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To the best of our knowledge, the only previous well-documented examples of main-group metal alkylperoxide complexes undergoing homolysis are aluminum derivatives: S. S. Kumar, S. Singh, H. W. Roesky, Inorg. Chem. 2005, 44, 1199-1201;
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To the best of our knowledge, the only previous well-documented examples of main-group metal alkylperoxide complexes undergoing homolysis are aluminum derivatives: S. S. Kumar, S. Singh, H. W. Roesky, Inorg. Chem. 2005, 44, 1199-1201;
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33
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33645051475
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H. Li, H. Song, L. Duan, C. Cui, H. W. Roesky, Inorg. Chem. 2006, 45, 1912-1914.
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34
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0034809080
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This mode of decomposition is often observed for transition metal alkylperoxides, where O-O homolytic cleavage is facilitated by oxidation of the metal center: N. Lehnert, R. Y. N. Ho, L. Que, Jr, E. I. Solomon, J. Am. Chem. Soc. 2001, 123, 8271-8290;
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This mode of decomposition is often observed for transition metal alkylperoxides, where O-O homolytic cleavage is facilitated by oxidation of the metal center: N. Lehnert, R. Y. N. Ho, L. Que, Jr., E. I. Solomon, J. Am. Chem. Soc. 2001, 123, 8271-8290;
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35
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