Determination of ciprofloxacin, the major metabolite of enrofloxacin, in milk by isopotential fluorimetry

Journal of Agricultural and Food Chemistry

Volumn 56, Issue 19, 2008, Pages 8838-8843

  Murillo Pulgarin J A ^a   Alanon Molina A ^a   Munoz Fernandez L ^a  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

Ciprofloxacin; Enrofloxacin; Fluorimetry; Isopotential; Milk

Indexed keywords

ANTIINFECTIVE AGENT; CIPROFLOXACIN;

ANIMAL; ARTICLE; CHEMISTRY; METHODOLOGY; MILK; PH; SPECTROFLUOROMETRY;

ANIMALS; ANTI-INFECTIVE AGENTS; CIPROFLOXACIN; HYDROGEN-ION CONCENTRATION; MILK; SPECTROMETRY, FLUORESCENCE;

EID: 54449090213     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf801094g     Document Type: Article

References (31)

1. Tyckowska, K. L.; Voyksner, R. D.; Anderson, K. L.; Papich, M. G. Simultaneous determination of enrofloxacin and its primary metabolite ciprofloxacin in bovine milk and plasma by ion-pairing liquid chromatography. J. Chromatogr., B 1994, 658, 341-348.
2. Kaartinen, L.; Salonen, M.; Alli, L.; Pyorala, S. Pharmacokinetics of enrofloxacin after intravenous, intramuscular and subcutaneous injections in lactating cows. J. Vet. Pharmacol. Ther. 1995, 18, 357-362.
3. Roybal, J. E.; Pfenning, A. P.; Turnipseed, S. B.; Walker, C. C.; Hurlbut, J. A. Determination of four fluoroquinolones in milk by liquid chromatography. J. AOAC Int. 1997, 80 (5), 982-987.
4. Idowu, O. R.; Peggins, J. O. Simple, rapid determination of enrofloxacin and ciprofloxacin in bovine milk and plasma by high-performance liquid chromatography with fluorescence detection. J. Pharm. Biomed. Anal. 2004, 35 (1), 143-153.
5. Marazuela, M. D.; Moreno-Bondi, M. C. Multiresidue determination of fluoroquinolones in milk by column liquid chromatography with fluorescence and ultraviolet absorbance detection. J. Chromatogr., A 2004, 1034, 25-32.
6. Ho, C.; Sin, D. W. M.; Tang, H. P. O.; Chung, L. P. K.; Siu, S. M. P. Determination and on-line clean-up of (fluoro)quinolones in bovine milk using column-switching liquid chromatography fluorescence detection. J. Chromatogr., A 2004, 1061, 123-131.
7. Verdon, E.; Couedor, P.; Roudaut, B.; Sanders, P. Multiresidue method for simultaneous determination of ten quinolone antibacterial residues in multimatrix/multispecies animal tissues by liquid chromatography with fluorescence detection: single laboratory validation study. J. AOAC Int. 2005, 88 (4), 1179-1192.
8. Yang, G. X.; Lin, B. Y.; Zeng, Z. L.; Chen, Z. L.; Huang, X. H. Multiresidue determination of eleven quinolones in milk by liquid chromatography with fluorescence detection. J. AOAC Int. 2005, 88 (6), 1688-1694.
9. Cinquina, A. L.; Roberti, P.; Giannetti, L.; Longo, F.; Draisci, R.; Fagiolo, A.; Briziioli, N. R. Determination of enrofloxacin and its metabolite ciprofloxacin in goat milk by high-performance liquid chromatography with diode-array detection. Optimization and validation. J. Chromatogr., A 2003, 987 (1-2), 221-226.
10. Holtzapple, C. K.; Buckley, S. A.; Stanker, L. H. Determination of four fluoroquinolones in milk by on-line immunoaffinity capture coupled with reserved-phase liquid chromatography. J. AOAC Int. 1999, 82 (3), 607-613.
11. Volmer, D. A.; Mansoori, B.; Locke, S. J. Study of 4-quinolone antibiotics in biological samples by short-column liquid chromatography coupled with electrospray ionization tandem mass spectrometry. Anal. Chem. 1997, 69 (20), 4143-4155.
12. van-Hoof, N.; de-Wasch, K.; Okeman, L.; Reybroeck, W.; Poelmans, S.; Noppe, H.; de-Brabander, H. Validation of a liquid chromatography-tandem mass spectrometric method for the quantification of eight quinolones in bovine muscle, milk and aquacultured products. Anal. Chim. Acta 2005, 529, 265-272.
13. Pellegrini, G. E.; Carpico, G.; Coni, E. Electrochemical sensor for the detection and presumptive identification of quinolone and tetracycline residues in milk. Anal. Chim. Acta 2004, 520 (1-2), 13-18.
14. Mellgren, C.; Sternesjo, A. Optical immunobiosensor assay for determining enrofloxacin and ciprofloxacin in bovine milk. J. AOAC Int. 1998, 81 (2), 394-397.
15. Murillo, J. A.; Alañón, A. Matriz isopotential synchronous fluorescence. Direct determination of gentisic acid in urine A. Anal. Chim. Acta 1994, 296, 87-97.
16. Murillo, J. A.; Alañón, A. Ftotal, a program to process total luminescence spectra. Comput. Chem. 1993, 17, 341-354.
17. Murillo, J. A.; Alañón, A. Determination of salicylic and gentisic acids in the presence of each other by matrix isopotential synchronous fluorescence spectrometry. Analyst 1994, 119, 1915-1919.
18. Berzas, J. J.; Murillo, J. A.; Gómez, M. A. Determination of pyridoxamine in urine by matriz isopotential synchronous fluorerscence spectrometry. Analyst 1995, 120, 171-174.
19. Murillo, J. A.; Alañón, A. Direct determination of quinidine in urine. Anal. Chim. Acta 1995, 317, 359-364.
20. Murillo, J. A.; Alañón, A.; Fernández, P. Direct determination of triamterene in urine by matriz isopotential synchronous fluorescente spectrometry. Anal. Chim. Acta 1996, 326, 117-126.
21. Murillo, J. A.; Alañón, A.; Fernández, P. Direct determination of dipyridamole in serum. Anal. Biochem. 1997, 245, 8-16.
22. Murillo, J. A.; Alañón, A. Direct determination of salicylamide in serum by matriz isopotential synchronous fluorimetry. Talanta 2002, 56, 557-564.
23. Murillo Pulgarín, J. A.; Alañón Molina, A.; Alañón Pardo, M. T. Fluorescente characteristics of several whey simples subjected to different treatments and conditions. Anal. Chim. Acta 2005, 536, 153-158.
24. Savitzky, A.; Golay, M. J. E. Smoothing and differentiation of data by simplified least squares procedures. Anal. Chem. 1964, 36, 1627-1639.
25. Steinier, J.; Termonia, Y.; Deltour, J. Smoothing and differentiation of data by simplified least square procedure. Anal. Chem. 1972, 44, 1906-1909.
26. Rousseeuw, P. J.; Leroy, A. M. Robust Regression and Outlier Detection; Wiley: New York, 1987.
27. Lark, P. D.; Craven, B. R.; Bosworth, R. C. L. The Handling of Chemical Data; Pergamon Press: Oxford, U.K., 1968.
28. Nomenclature symbols, units and their usage in spectrochemical analysis-II. data interpretation Analytical chemistry division. Spectrochim. Acta, Part B 1978, 33 (6), 241-245.
29. MacDougal, D.; Crummett, W. B. Guidelines for data acquisition and data quality evaluation in environmental chemistry. Anal. Chem. 1980, 52 (14), 2242-2249.
30. Long, G. L.; Winefordner, J. D. Limit of detection. A closer look at the IUPAC definition. Anal. Chem. 1983, 55, 712A-714A, 716A, 720A, 722A, 724A.
31. Clayton, C. A.; Hines, J. W.; Elkins, P. D. Detection limits with specified assurance probabilities. Anal. Chem. 1987, 59, 2506-2514.