Highly active and selective Nb modified MCM-41 catalysts for Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam

Journal of Catalysis

Volumn 260, Issue 1, 2008, Pages 17-29

  Anilkumar, M ^a   Holderich W F ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Caprolactam; Beckmann rearrangement reaction; Cyclohexanone oxime; Gas phase reaction; Nb MCM 41

Indexed keywords

ACIDS; AMMONIUM COMPOUNDS; ATOMIC PHYSICS; ATOMIC SPECTROSCOPY; ATOMS; CATALYSIS; CATALYST ACTIVITY; CATALYST SELECTIVITY; CATALYSTS; COORDINATION REACTIONS; DESORPTION; EMISSION SPECTROSCOPY; INDUCTIVELY COUPLED PLASMA; MAGNETIC RESONANCE; MODEMS; MOLECULAR SIEVES; MOLECULAR SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHYSISORPTION; RESONANCE; SIEVES; SILICON; TEMPERATURE PROGRAMMED DESORPTION; TRANSITION METALS; ZEOLITES;

AMMONIUM BROMIDES; ANGLE SPINNINGS; BECKMANN REARRANGEMENT REACTION; BECKMANN REARRANGEMENTS; CATALYST ACIDITIES; CATALYST SAMPLES; CATALYST STABILITIES; CYCLOHEXANONE OXIME; CYCLOHEXANONE OXIMES; DIFFUSE REFLECTANCES; FOURIER; GAS PHASE REACTION; HEXAGONAL ARRANGEMENTS; HYDROTHERMAL METHODS; ICP-AES; INFRA REDS; IR TECHNIQUES; MAS-NMR; NB ATOMS; NB OXIDES; NB-MCM-41; OPTIMUM TEMPERATURES; ORGANICS; PRODUCT SELECTIVITIES; SPACE VELOCITIES; STRUCTURAL CHARACTERIZATIONS; SURFACE TYPES; TETRAHEDRALLY COORDINATED; TWO TYPES; UNIFORM MESOPORES; X-RAY DIFFRACTIONS;

NIOBIUM;

EID: 54349107124     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2008.08.019     Document Type: Article

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