Cu2+-mediated nucleophilic addition of different nucleophiles to dicyanamide - synthesis, structures, and magnetic properties of a family of mononuclear, trinuclear, hexanuclear, and polymeric copper(II) complexes

European Journal of Inorganic Chemistry

Volumn , Issue 29, 2008, Pages 4616-4624

  Zheng, Ling Ling ^a   Leng, Ji Dong ^a   Liu, Wen Ting ^a   Zhang, Wei Xiong ^a   Lu, Jun Xian ^a   Tong, Ming Liang ^a  

^a SUN YAT SEN UNIVERSITY   (China)

Author keywords

Copper(II); Magnetic properties; Nucleophilic addition; Polydentate ligands

Indexed keywords

ADDITION REACTIONS; CHAINS; CHELATION; INDIUM COMPOUNDS; LIGANDS; MAGNETIC SUSCEPTIBILITY; METHANOL; MOLECULES; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

ADDITION PRODUCTS; COPPER(II); DICYANAMIDE; GUEST MOLECULES; MONONUCLEAR COMPLEXES; NUCLEOPHILIC ADDITIONS; POLYDENTATE LIGAND; PYRAZOLES; TRINUCLEAR; TRINUCLEAR COMPLEX;

COPPER COMPOUNDS;

EID: 54249139121     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800486     Document Type: Article

References (50)

1. a) B. N. Storhoff, H. C. Lewis, Coord. Chem. Rev. 1977, 23, 1-29;
2. b) B. Corain, M. Basato, A. C. Veronese, J. Mol. Catal. 1993, 81, 133-155;
3. c) X.-M. Chen, M.-L. Tong, Acc. Chem. Res. 2007, 40, 162-170;
4. d) X.-M. Zhang, Coord. Chem. Rev. 2005, 249, 1201-1219;
5. e) H. Zhao, Z.-R. Qu, H.-Y. Ye, R.-G. Xiong, Chem. Soc. Rev. 2008, 37, 84-100.
6. a) A. G. Sharpe, The Chemistry of Cyano Complexes of the Transition Metals, Academic Press, London, 1976;
7. b) R.W. Hay in Reactions of Coordinated Ligands (Ed.: P. S. Braterman), Plenum Press, New York, 1989, vol. 2, p. 280;
8. c) E. C. Constable, Metals and Ligand Reactivity - An Introduction to the Organic Chemistry, VCH, Weinheim, 1995, p. 65.
9. a) V. Y. Kukushkin, A. J. L. Pombeiro, Chem. Rev. 2002, 102, 1771-1802;
10. b) A. J. L. Pombeiro, V. Y. Kukushkin, "Reactions of Coordinated Nitriles" in Comprehensive Coordination Chemistry (Eds.: J. A. McCleverty, T. J. Meyer), 2nd ed., Elsevier, Oxford, UK, 2003, vol. 1, p. 639;
11. c) R. A. Michelin, M. Mozzon, R. Bertani, Coord. Chem. Rev. 1996, 147, 299-338;
12. d) J.-R. Li, Y. Tao, Q. Yu, X.-H. Bu, Chem. Commun. 2007, 1527-1529.
13. J. Eglin, Comments Inorg. Chem. 2002, 23, 231-238.
14. a) M. N. Kopylovich, V. Y. Kukushkin, M. F. C. Guedes da Silva, M. Haukka, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, J. Chem. Soc. Perkin Trans. 1 2001, 1569-1573;
15. b) J. Burgess, C. D. Hubbard, Adv. Inorg. Chem. 2003, 54, 71-155;
16. c) V. Y. Kukushkin, A. J. L. Pombeiro, Inorg. Chim. Acta 2005, 358, 1-21.
17. See reviews: a) S. R. Batten, K. S. Murray, Coord. Chem. Rev. 2003, 246, 103-130;
18. b) X.-Y. Wang, Z.-M. Wang, S. Gao, Chem. Commun. 2008, 281-294.
19. W. P. Norris, R. A. Henry, J. Org. Chem. 1964, 29, 650-660.
20. J. Kozisek, M. Hvastijova, J. Kohout, Inorg. Chim. Acta 1990, 168, 157-158.
21. R. Boča, M. Hvastijova, J. Kozisek, M. Valko, Inorg. Chem. 1996, 35, 4794-4797.
22. M. B. Michael, F. L. Leonard, M. Srihari, T. Peter, J. Chem. Soc., Dalton Trans. 2000, 233-234.
23. a) I. M. Atkinson, M. M. Bishop, F. L. Leonard, M. Srihari, T. Peter, Chem. Commun. 2002, 2818-2819;
24. b) X.-H. Zhao, X.-D. Chen, M. Du, Acta Crystallogr., Sect. E 2006, 62, m3580-m3581;
25. c) G.-F. Liu, L.-L. Li, Y. Zhang, J.-P. Lang, S. W. Ng, Acta Crystallogr., Sect. C 2007, 63, m1-m3.
26. M. Hvastijová, J. Kohout, J. Buchler, W. Boča, J. Kožíšek, L. Jäger, Coord. Chem. Rev. 1998, 175, 17-42.
27. M.-L. Tong, J. Ru, Y.-M. Wu, X.-M. Chen, H.-C. Chang, K. Mochizuki, S. Kitagawa, New J. Chem. 2003, 27, 779-782.
28. M.-L. Tong, Y.-M. Wu, Y.-X. Tong, X.-M. Chen, H.-C. Chang, S. Kitagawa, Eur. J. Inorg. Chem. 2003, 2385-2388.
29. a) L.-L. Zheng, W.-X. Zhang, L.-J. Qin, J.-D. Leng, J.-X. Lu, M.-L. Tong, Inorg. Chem. 2007, 46, 9548-9557;
30. b) A. Igashira-Kamiyama, T. Kajiwara, T. Konno, T. Ito, Inorg. Chem. 2006, 45, 6460-6466.
31. a) M. Friedrich, J. C. Gálvez-Ruiz, T. M. Klapötke, P. Mayer, B. Weber, J. J. Weigand, Inorg. Chem. 2005, 44, 8044-8052;
32. b) E.-Q. Gao, N. Liu, A.-L. Cheng, S. Gao, Chem. Commun. 2007, 2470-2472;
33. c) L.-L. Zheng, H.-X. Li, J.-D. Leng, J. Wang, M.-L. Tong, Eur. J. Inorg. Chem. 2008, 213-217.
34. J.-P. Zhang, Y.-Y. Lin, X.-C. Huang, X.-M. Chen, J. Am. Chem. Soc. 2005, 127, 5495-5505.
35. a) G. Rembarz, E. Fischer, K.-C. Röber, R. Ohff, H. Crahmer, J. Prakt. Chem. 1969, 311, 889-891;
36. b) G. Götz, H. U. Kibbel, Z. Chem. 1975, 15, 278-280;
37. c) M. Hvastijová, J. Kohout, H. Köhler, G. Ondrejovič, Z. Anorg. Allg. Chem. 1988, 566, 111-120;
38. d) M. Hvastijová, J. Kohout, J. Klimc?íková, H. Köhler, J. Coord. Chem. 1987, 15, 409-412;
39. e) J. Mroziński, J. Kohout, M. Hvastijová, H. Köhler, Transition Met. Chem. 1986, 11, 481-484.
40. V. Chandrasekhar, R. Azhakar, V. Krishnan, A. Athimoolam, B. M. Pandian, J. Am. Chem. Soc. 2006, 128, 6802-6803.
41. G. R. Desiraju, T. Steiner, The Weak Hydrogen Bond in Structural Chemistry and Biology, Oxford University Press, Oxford, 1999.
42. J. Tercero, C. Diaz, J. Ribas, J. Mahía, M. A. Maestro, Inorg. Chem. 2002, 41, 5373-5381.
43. T. Kajiwara, A. Kamiyama, T. Ito, Chem. Commun. 2002, 1256-1257.
44. MAGMUN4.1 is freely available through http://www.ucs.mun.ca/ ~lthomp/magmun.html. The program may be used for scientific purposes only. Reference to it should be quoted appropriately.
45. L. Zherlitsyna, N. Auner, M. Bolte, Y. Pozdniakova, O. Shchegolikhina, K. Lyssenko, V. Pashchenko, B. Wolf, M. Lang, F. Schütz, M. Kollar, F. Sauli, P. Kopietz, Eur. J. Inorg. Chem. 2007, 4827-4838.
46. M. F. Iskander, T. E. Khalil, W. Haase, R. Werner, I. Svoboda, H. Fuess, Polyhedron 2001, 20, 2787-2798.
47. H. Matsushima, H. Hamada, K. Watanabe, M. Koikawa, T. Tokii, J. Chem. Soc., Dalton Trans. 1999, 971-977;
48. E. Spodine, A. M. Atria, J. Valenzuela, J. Jalocha, J. Manzur, A. M. García, M. T. Garland, O. Peña, J.-Y. Saillard, J. Chem. Soc., Dalton Trans. 1999, 3029-3034.
49. G. M. Sheldrick, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
50. G. M. Sheldrick, SHELXTL, Version 6.10, Bruker Analytical X-ray Systems, Madison, WI, USA, 2001.