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Enaminones can exist in different protonation and oxidation levels. They are potential redox-noninnocent ligands in the sense they can be N,O-coordinated to transition metal ions (i) as closed-shell anions, (ii) radical-anions and (iii) as dianions. See for example selected references with other ligands:
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Chemical Crystallography Laboratory, Oxford, UK, In order to measure the distortions of the coordination polyhedron from the square pyramid to the trigonal bipyramid, the Addison parameter (τ) has been calculated according to the literature procedures
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