High selectivity for l-cysteine residue at axial solvated site of trigonal-bipyramidal palladium(II) complex with tripodal tetradentate phosphine

Journal of Organometallic Chemistry

Volumn 693, Issue 24, 2008, Pages 3638-3642

  Aizawa, Sen ichi ^a   Sano, Takahiro ^a   Fujita, Yoshiaki ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

Author keywords

l Cysteine residue; Selective coordination; Thiolate sulfur atom; Trigonal bipyramidal palladium(II)

Indexed keywords

ACETONITRILE; AMINATION; AMINES; AMINO ACIDS; ATOMIC PHYSICS; ATOMS; COORDINATION REACTIONS; DYES; NANOSTRUCTURED MATERIALS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC ACIDS; PALLADIUM; PHOSPHORUS COMPOUNDS; PLATINUM; PLATINUM COMPOUNDS; SOLUTIONS; SOLVENT EXTRACTION; SULFUR;

AQUEOUS SOLUTIONS; AXIAL POSITIONS; COORDINATION SITES; CYSTEINE RESIDUES; DIPHENYLPHOSPHINO; EXTRACTANTS; GLUTATHIONE; HIGH SELECTIVITIES; L-CYSTEINE RESIDUE; NMR SPECTROSCOPIES; PALLADIUM COMPLEXES; PHENYLPHOSPHINE; PLATINUM COMPLEXES; REDUCED FORMS; SELECTIVE COORDINATION; SOLVATED COMPLEXES; SULFUR ATOMS; THIOLATE; THIOLATE SULFUR ATOM; TRIGONAL-BIPYRAMIDAL PALLADIUM(II);

PALLADIUM COMPOUNDS;

GLUTA;

EID: 54049112556     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2008.09.001     Document Type: Article

References (22)

1. Aizawa S., Iida T., and Funahashi S. Inorg. Chem. 35 (1996) 5163-5167
2. Fernández D., Seijo M.I.G., Kégl T., Peto{combining double acute accent}cz G., Kollár L., and Fernández M.E.G. Inorg. Chem. 41 (2002) 4435-4443
3. Aizawa S., Iida T., Kawamoto T., Funahashi S., Yamada S., and Nakamura M. Bull. Chem. Soc. Jpn. 75 (2002) 91-97
4. Aizawa S., Kawamoto T., and Saito K. Inorg. Chim. Acta 357 (2004) 2191-2194
5. Aizawa S., Kobayashi T., and Kawamoto T. Inorg. Chim. Acta 338 (2005) 2319-2326
6. Centore R., Roviello G., and Tuzi A. Inorg. Chim. Acta 358 (2005) 2112-2116
7. Aizawa S., Hase T., and Wada T. J. Organomet. Chem. 692 (2007) 813-818
8. Pearson G., Muir M.M., and Venanzi L.M. J. Chem. Soc. (1965) 5521-5528
9. Lever B.P. Inorganic Electronic Spectroscopy. 2nd ed. (1984), Elsevier, Amsterdam (Chapter 6), pp. 527-528
10. Aizawa S., and Funahashi S. Anal. Sci. 12 (1996) 27-30
11. DuBois D.L., and Miedaner A. J. Am. Chem. Soc. 109 (1987) 113-117
12. lohe L., Benohr H.Ch., Sies H., Waller H.D., and Wendel A. Glutathione (1974), Academic Press, New York
13. King R.B., Kapoor R.N., Saran M.S., and Kapoor P.N. Inorg. Chem. 10 (1971) 1851-1869
14. Aizawa S., Saito K., Kawamoto T., and Matsumoto E. Inorg. Chem. 45 (2006) 4859-4866
15. -1)) 551 (3.31), 409 (3.82).
16. -1)) 449 (3.52), 360 (3.95).
17. Appleton T.G. Coord. Chem. Rev. 166 (1997) 313-359
18. It is assumed that the nitrogen-bound complexes with l-cys and l-pen are monocationic complexes with thiolate and carboxyl groups while those with l-met and l-ala would be dicationic ones with a carboxyl group if they were formed. Such a difference in the positive charge can make a difference in extractability of the nitrogen-bound complexes.
19. Aizawa S., Sone Y., Kawamoto T., Yamada S., and Nakamura M. Inorg. Chim. Acta 338 (2002) 235-239
20. Miyoshi K., Sugiura Y., Ishizu K., Iitaka Y., and Nakamura H. J. Am. Chem. Soc. 102 (1980) 6130-6136
21. Levina A., Zhang L., and Lay P.A. Inorg. Chem. 42 (2003) 767-784
22. Shtyrlin V.G., Zyavkina Y.I., Ilakin V.S., Garipov R.R., and Zakharov A.V. J. Inorg. Biochem. 99 (2005) 1335-1346