Asymmetric friedel-crafts alkylation of indoles with methyl (E)-2-Oxo-4-aryl-3-butenoates catalyzed by Sc(OTf)3/pybox

Chemistry - A European Journal

Volumn 14, Issue 12, 2008, Pages 3630-3636

  Desimoni, Giovanni ^a   Faita, Giuseppe ^a   Toscanini, Marco ^a   Boiocchi, Massimo ^a  

^a UNIVERSITY OF PAVIA   (Italy)

Author keywords

Asymmetric catalysis; Enantioselectivity; Friedel Crafts reaction; Indoles; N ligands

Indexed keywords

ACIDS; CHEMICAL REACTIONS; ENANTIOSELECTIVITY; ESTERS; FRIEDEL-CRAFTS REACTION; HYDROCARBONS; ORGANIC COMPOUNDS; SCANDIUM; SCANDIUM COMPOUNDS; SUGAR (SUCROSE);

ABSOLUTE CONFIGURATION; ASYMMETRIC CATALYSIS; DIELS-ALDER; ELECTRONIC CHARACTERS; EXCELLENT YIELDS; FRIEDEL-CRAFTS; FRIEDEL-CRAFTS ALKYLATION; INDOLE RINGS; INDOLES; METHYL ESTERS; MUKAIYAMA ALDOLS; N LIGANDS; OCTAHEDRAL COMPLEXES; PYRUVATES; SC(OTF)3; SCANDIUM TRIFLATE; STABLE ENOL; STEREOINDUCTION; SUBSTITUTED INDOLES; TRIFLATE; TRIISOPROPYLSILYL; X-RAY CRYSTAL STRUCTURES;

CRYSTAL STRUCTURE;

(4'S,5'S) 2,6 BIS(4' (TRIISOPROPYLSILYL)OXYMETHYL 5' PHENYL 1',3' OXAZOLIN 2' YL)PYRIDINE; (4'S,5'S)-2,6-BIS(4'-(TRIISOPROPYLSILYL)OXYMETHYL-5'-PHENYL-1',3'-OXAZOLIN-2'-YL)PYRIDINE; BUTYRIC ACID DERIVATIVE; ESTER; INDOLE DERIVATIVE; MESYLIC ACID DERIVATIVE; ORGANOMETALLIC COMPOUND; OXAZOLE DERIVATIVE; PYRIDINE DERIVATIVE; SCANDIUM; SCANDIUM TRIFLATE;

ALKYLATION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKYLATION; BUTYRATES; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; ESTERS; INDOLES; MESYLATES; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXAZOLES; PYRIDINES; SCANDIUM; STEREOISOMERISM;

EID: 53849129938     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200701908     Document Type: Article

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