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Volumn 634, Issue 5, 2008, Pages 938-940

The first homoleptic bis(trifluoromethanesulfonyl)amide complex of yttrium: [bmim][Y(Tf2N)4]

Author keywords

Coordinating anions; Crystal structure; Ionic liquids; Yttrium

Indexed keywords


EID: 53849121606     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700545     Document Type: Article
Times cited : (32)

References (27)
  • 6
  • 14
    • 36749029259 scopus 로고    scopus 로고
    • Ionic Liquids as Versatile Media in Lanthanide Chemistry
    • R. Rogers, K. Seddon Eds, Ionic Liquids IV
    • (e) A.-V. Mudring: Ionic Liquids as Versatile Media in Lanthanide Chemistry, in: R. Rogers, K. Seddon (Eds.) Ionic Liquids IV, ACS Symposium Series 975, 2007, 172.
    • (2007) ACS Symposium Series , vol.975 , pp. 172
    • Mudring, A.-V.1
  • 19
    • 53849085258 scopus 로고    scopus 로고
    • α radiation, λ = 71.073 pm). The data were corrected for Lorentz and polarization effects. A numerical absorption correction (XShape, Stoe) was applied for all data. The structure was solved by direct methods (SIR 92; A. Altomare, G. Cascarano, C. Giacovazzo, J. Appl. Crystallogr. 1993, 26, 343.),
    • α radiation, λ = 71.073 pm). The data were corrected for Lorentz and polarization effects. A numerical absorption correction (XShape, Stoe) was applied for all data. The structure was solved by direct methods (SIR 92; A. Altomare, G. Cascarano, C. Giacovazzo, J. Appl. Crystallogr. 1993, 26, 343.),
  • 20
    • 53849148002 scopus 로고    scopus 로고
    • and refined against F2 with all measured reflections (SHELXL-97 (G.M. Sheldrick, SHELXL-97; Programs for Crystal Structure Analysis, Universität Göttingen, 1997, All non-hydrogen atoms were refined anisotropically, bmim][Y(Tf2N)4, C 16H15F24N6O16S 8Y; 1348.73 g mol-1; T, 170(2) K; 2θmin, 2.40°; 2θmax, 50.0°; indices: -24 < I < 24; -17 < k < 17; -17 < l < 17; ρcalc, 1.944 g cm-3; 16361 reflection intensities measured with I 0 > 2σ(I0) of which 3874 were symmetrically independent, Rint, 0.0993, F (000, 2656, μ, 1.79 mm -1. Monoclinic, C2/c (no. 15, a, 2096.(1, b, 1451.5(1, c, 1608.55(9) pm, β, 109.669(6)°, V, 4608.1(5) pm3
    • 0): 0.0438/0.0736 and for all data: 0.1099/0.0883. The last cycles of refinement included atomic positions and anisotropic thermal parameters for all the non-hydrogen atoms. Further details of the crystal structure investigation may be obtained from Cambridge Crystallographic Data Centre, UK, http://www.ccdc.cam.ac.uk or from CCDC, 12 Union Road, Cambridge CB2 1EZ, UK; Phone +44 1223 336408, Fax: +44 1223 336033; email; deposit@ccdc.cam.ac.uk on quoting the CSD number 670125.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.