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Volumn , Issue 28, 2008, Pages 4360-4368

Mild oxidative addition of C-H bonds to a hydrido-bridged dinuclear complex of iridium(II) induced by the coordination of heteroatomic ligands

Author keywords

C H activation; Cooperative effects; Iridium; P ligands; S ligands

Indexed keywords

ACTIVATION ANALYSIS; DIMETHYL SULFOXIDE; IRIDIUM COMPOUNDS; LIGANDS; PHOSPHORUS COMPOUNDS;

EID: 53649085143     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800469     Document Type: Article
Times cited : (8)

References (67)
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    • PC was observed in the cases of complexes 2a-e. We suppose that the delocalization of electrons in the diiridacycle of 2a-e might give rise to ylidic character of the P-C bond, which would cause this increase in the coupling constants.
    • PC was observed in the cases of complexes 2a-e. We suppose that the delocalization of electrons in the diiridacycle of 2a-e might give rise to "ylidic" character of the P-C bond, which would cause this increase in the coupling constants.
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    • - bimetallic system with bridging hydrides. For example: a E. Sola, V. I. Bakhmutov, F. Torres, A. Elduque, J. A. López, F. J. Lahoz, H. Werner, L. A. Oro, Organometallics 1998, 17, 683-696;
    • - bimetallic system with bridging hydrides. For example: a) E. Sola, V. I. Bakhmutov, F. Torres, A. Elduque, J. A. López, F. J. Lahoz, H. Werner, L. A. Oro, Organometallics 1998, 17, 683-696;
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    • We have also examined the reactions using other donor molecules such as amines aniline and pyridine, N-heterocyclic carbenes, and sulfides. However these reactions resulted in the quantitative recovery of complex 1 or the formation of complicated mixtures
    • We have also examined the reactions using other donor molecules such as amines (aniline and pyridine), N-heterocyclic carbenes, and sulfides. However these reactions resulted in the quantitative recovery of complex 1 or the formation of complicated mixtures.
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    • D. C. Creagh, W. J. McAuley in International Tables for X-ray Crystallography (Ed.: A. J. C. Wilson), Kluwer Academic Publishers, Boston, MA, 1992; C, Table 4.2.6.8, pp. 219-222;
    • c) D. C. Creagh, W. J. McAuley in International Tables for X-ray Crystallography (Ed.: A. J. C. Wilson), Kluwer Academic Publishers, Boston, MA, 1992; vol. C, Table 4.2.6.8, pp. 219-222;
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    • D. C. Creagh, J. H. Hubbel in International Tables for X-ray Crystallography (Ed.: A. J. C. Wilson), Kluwer Academic Publishers, Boston, MA, 1992; C, Table 4.2.4.3, pp. 200-206.
    • d) D. C. Creagh, J. H. Hubbel in International Tables for X-ray Crystallography (Ed.: A. J. C. Wilson), Kluwer Academic Publishers, Boston, MA, 1992; vol. C, Table 4.2.4.3, pp. 200-206.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.