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Volumn 47, Issue 11, 2008, Pages 2046-2048

A self-assembled spin cage

Author keywords

Host guest systems; Molecular recognition; Palladium; Radicals; Self assembly

Indexed keywords

NITROGEN COMPOUNDS; PALLADIUM; SPIN DYNAMICS;

EID: 53549130431     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200704924     Document Type: Article
Times cited : (66)

References (31)
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    • Self-assembled ionic hosts: a) M. Fujita, D. Oguro, M. Miyazawa, H. Oka, K. Yamaguchi, K. Ogura, Nature 1995, 378, 469-472;
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    • (2002) Angew. Chem. Int. Ed , vol.41 , pp. 1488-1508
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    • Cagelike compounds with spins at metal centers: Reviews: a E. J. L. McInnes, S. Piligkos, G. A. Timco, R. E. P. Winpenny, Coord. Chem. Rev. 2005, 249, 2577-2590;
    • Cagelike compounds with spins at metal centers: Reviews: a) E. J. L. McInnes, S. Piligkos, G. A. Timco, R. E. P. Winpenny, Coord. Chem. Rev. 2005, 249, 2577-2590;
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    • radical cages: c T. Okubo, S. Kitagawa, M. Kondo, H. Matsuzaka, T. Ishii, Angew. Chem. 1999, 111, 980-983;
    • radical cages: c) T. Okubo, S. Kitagawa, M. Kondo, H. Matsuzaka, T. Ishii, Angew. Chem. 1999, 111, 980-983;
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    • (1999) Angew. Chem. Int. Ed , vol.38 , pp. 931-933
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    • detailed conditions are described in the Supporting Information
    • b) Y. A. Ibrahim, A. H. M. Elwahy, A. A. Abbas, Tetrahedron 1994, 50, 11489-11498; detailed conditions are described in the Supporting Information.
    • (1994) Tetrahedron , vol.50 , pp. 11489-11498
    • Ibrahim, Y.A.1    Elwahy, A.H.M.2    Abbas, A.A.3
  • 21
    • 53549112440 scopus 로고    scopus 로고
    • 6 salt) and the ESR spectra of 2 recorded at several microwave powers are shown in Figures S1 and S2, respectively, of the Supporting Information.
    • 6 salt) and the ESR spectra of 2 recorded at several microwave powers are shown in Figures S1 and S2, respectively, of the Supporting Information.
  • 22
    • 53549094645 scopus 로고    scopus 로고
    • 2] is shown in Figure S3 of the Supporting Information.
    • 2] is shown in Figure S3 of the Supporting Information.
  • 23
    • 53549085945 scopus 로고    scopus 로고
    • The quality of the crystals was improved by adding 1-adamantanol as a template
    • The quality of the crystals was improved by adding 1-adamantanol as a template.
  • 24
    • 53549132225 scopus 로고    scopus 로고
    • The ESR spectra of 2 recorded at different concentrations and temperatures are shown in Figures S4 and S5 of the Supporting Information.
    • The ESR spectra of 2 recorded at different concentrations and temperatures are shown in Figures S4 and S5 of the Supporting Information.
  • 26
    • 0035805361 scopus 로고    scopus 로고
    • The nitrosyl radicals 3 and 4 that were used as guests were prepared by the improved Ullman's procedure described in the following reference: C. Hirel, K. E. Vostrikova, J. Pecaut, V. I. Ovcharenko, P. Rey, Chem. Eur. J. 2001, 7, 2007-2014.
    • The nitrosyl radicals 3 and 4 that were used as guests were prepared by the improved Ullman's procedure described in the following reference: C. Hirel, K. E. Vostrikova, J. Pecaut, V. I. Ovcharenko, P. Rey, Chem. Eur. J. 2001, 7, 2007-2014.
  • 27
    • 53549123244 scopus 로고    scopus 로고
    • 2·3: Elemental analysis calcd for C128H 104N52O36Pd6·C 21H21N2O2·21H2O: C 41.65, H 3.92, N 17.60; found: C 41.75, H 4.04, N 17.38. 2·(4) 2: Elemental analysis calcd for C128H 104N52O36Pd6·2C 17H19N2O2·22H2O: C 42.78, H 4.12, N 17.25; found: C 42.82, H 4.10, N 17.11. The extraction experiments are described in Section 7 of the Supporting Information
    • 2O: C 42.78, H 4.12, N 17.25; found: C 42.82, H 4.10, N 17.11. The extraction experiments are described in Section 7 of the Supporting Information.
  • 28
    • 53549132498 scopus 로고    scopus 로고
    • The χT versus T plots of 2 and 2·3 are shown in Figure S6 of the Supporting Information.
    • The χT versus T plots of 2 and 2·3 are shown in Figure S6 of the Supporting Information.
  • 31
    • 53549115318 scopus 로고    scopus 로고
    • The enclathration of neutral molecules is described in the Supporting Information
    • The enclathration of neutral molecules is described in the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.