Homolytic bond strengths and formation rates in half-sandwich chromium alkyl complexes: Relevance for controlled radical polymerization

Angewandte Chemie - International Edition

Volumn 47, Issue 32, 2008, Pages 6069-6072

  Champouret, Yohan ^a   Baisch, Ulrich ^a   Poli, Rinaldo ^a   Tang, Liming ^b   Conway, Julia L ^b   Smith, Kevin M ^b,c  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b UNIVERSITY OF PRINCE EDWARD ISLAND   (Canada)

^c UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

Chromium; Homolytic bond cleavage; Poly(vinyl acetate); Polymerization; Stereoelectronic effects

Indexed keywords

ABS RESINS; BOND STRENGTH (CHEMICAL); CHEMICAL PROPERTIES; CHEMICAL REACTIONS; CHROMIUM; CHROMIUM COMPOUNDS; DYES; INITIATORS (CHEMICAL); MONOMERS; POLYMERS; SUBSTITUTION REACTIONS; VANADIUM COMPOUNDS;

HOMOLYTIC BOND CLEAVAGE; POLY(VINYL ACETATE); POLYMERIZATION; STEREOELECTRONIC EFFECTS;

POLYVINYL ACETATES;

EID: 53549113020     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200801498     Document Type: Article

References (27)

1. Macromolecular Engineering: Precise Synthesis, Materials Properties, Applications (Eds.: K. Matyjaszewski, Y. Gnanou, L. Leibler), Wiley-VCH, Weinheim, 2007.
2. R. Poli, Angew. Chem. 2006, 118, 5180-5192;
3. Angew. Chem. Int. Ed. 2006, 45, 5058-5070.
4. M. Destarac, D. Charmot, X. Franck, S. Z. Zard, Macromol. Rapid Commun. 2000, 21, 1035-1039.
5. M. Destarac, W. Bzducha, D. Taton, I. Gauthier-Gillaizeau, S. Z. Zard, Macromol. Rapid Commun. 2002, 23, 1049-1054.
6. M. Wakioka, K. Y. Baek, T. Ando, M. Kamigaito, M. Sawamoto, Macromolecules 2002, 35, 330-333.
7. J. Xia, H.-J. Paik, K. Matyjaszewski, Macromolecules 1999, 32, 8310-8314.
8. H.-J. Paik, M. Teodorescu, J. Xia, K. Matyjaszewski, Macromolecules 1999, 32, 7023-7031.
9. A. Debuigne, J. R. Caille, R. Jérôme, Angew. Chem. 2005, 117, 1125-1128;
10. Angew. Chem. Int. Ed. 2005, 44, 1101-1104.
11. A. Debuigne, J.-R. Caille, R. Jérôme, Macromolecules 2005, 38, 5452-5458.
12. S. Maria, H. Kaneyoshi, K. Matyjaszewski, R. Poli, Chem. Eur. J. 2007, 13, 2480-2492.
13. A. Debuigne, Y. Champouret, R. Jérôme, R. Poli, C. Detrembleur, Chem. Eur. J. 2008, DOI: 10.1002/chem.200800371.
14. J. C. Doherty, K. H. D. Ballem, B. O. Patrick, K. M. Smith, Organometallics 2004, 23, 1487-1489.
15. V. C. Gibson, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, D. J. Williams, Eur. J. Inorg. Chem. 2001, 1895-1903.
16. L. A. Macadams, W. K. Kim, L. M. Liable-Sands, I. A. Guzei, A. L. Rheingold, K. H. Theopold, Organometallics 2002, 21, 952-960.
17. L. A. Macadams, G. P. Buffone, C. D. Incarvito, A. L. Rheingold, K. H. Theopold, J. Am. Chem. Soc. 2005, 127, 1082-1083.
18. J. L. Conway, K. H. D. Ballem, R. Poli, B. O. Patrick, K. M. Smith, unpublished results.
19. M. Lee, Y. Minoura, J. Chem. Soc. Faraday Trans. 1 1978, 74, 1726-1737.
20. M. Lee, T. Morigami, Y. Minoura, J. Chem. Soc. Faraday Trans. 1 1978, 74, 1738-1749.
21. M. Lee, K. Utsumi, Y. Minoura, J. Chem. Soc. Faraday Trans. 1 1979, 75, 1821-1829.
22. M. B. Gillies, K. Matyjaszewski, P.-O. Norrby, T. Pintauer, R. Poli, P. Richard, Macromolecules 2003, 36, 8551-8559.
23. K. Matyjaszewski, R. Poli, Macromolecules 2005, 38, 8093-8100.
24. B. B. Wayland, C.-H. Peng, X. Fu, Z. Lu, M. Fryd, Macromolecules 2006, 39, 8219-8222.
25. P. H. M. Budzelaar, R. De Gelder, A. W. Gal, Organometallics 1998, 17, 4121-4123.
26. A. P. Dove, V. C. Gibson, E. L. Marshall, A. J. P. White, D. J. Williams, Dalton Trans. 2004, 570-578.
27. S. K. Hao, J. I. Song, P. Berno, S. Gambarotta, Organometallics 1994, 13, 1326-1335.