Reactions of terphenylbismuth dihalides with KSi(SiMe3) 3, K2Si2(SiMe3)4 and Na2[Fe(CO)]4: Reduction vs. metathesis

European Journal of Inorganic Chemistry

Volumn , Issue 16, 2008, Pages 2515-2521

  Wolf, Robert ^a   Fischer, Jelena ^a   Fischer, Roland C ^a   Fettinger, James C ^a   Power, Philip P ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Bismuth; Iron; Silicon; Terphenyl

Indexed keywords

BISMUTH; CHLORINE COMPOUNDS; IRON COMPOUNDS; REDUCING AGENTS; REDUCTION; SILICON; SILICON COMPOUNDS; SPECTROSCOPIC ANALYSIS; ULTRAVIOLET VISIBLE SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

% REDUCTIONS; BISMUTH CENTRES; DIBISMUTHENE; DIHALIDES; IR AND UV-VIS SPECTROSCOPY; METATHESIS CHEMISTRY; REDUCING POWER; SALT METATHESIS; SPECTROSCOPIC METHOD; TERPHENYLS;

BISMUTH COMPOUNDS;

EID: 53249156264     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200701334     Document Type: Article

References (59)

1. M. Yoshifuji, I. Shima, N. Inamoto, K. Hirotsu, T. Higuchi, J. Am. Chem. Soc. 1981, 103, 4587-4589.
2. A. H. Cowley, J. E. Kilduff, T. H. Newman, M. Pakulski, J. Am. Chem. Soc. 1982, 104, 5820-5821.
3. A. H. Cowley, J. G. Lasch, N. C. Norman, M. Pakulski, J. Am. Chem. Soc. 1983, 105, 5506-5507.
4. A. H. Cowley, Polyhedron 1984, 3, 389-432.
5. A. H. Cowley, N. C. Norman, Prog. Inorg. Chem. 1986, 34, 1-63.
6. L. Weber, Chem. Rev. 1992, 92, 1839-1906.
7. a) K. M. Flynn, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 1983, 105, 2085-2086;
8. b) R. A. Bartlett, H. V. Rasika Dias, K. M. Flynn, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 1987, 109, 5699-5703 and ref. therein;
9. c) R. A. Bartlett, H. V. Rasika Dias, K. M. Flynn, H. Hope, B. D. Murray, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 1987, 109, 5693-5698 and references cited therein.
10. M. Yoshfuji, Pure Appl. Chem. 1999, 71, 503-512.
11. A.-M. Caminade, J.-P. Majoral, R. Mathieu, Chem. Rev. 1991, 91, 575-612.
12. N. Tokitoh, Y. Arai, R. Okazaki, S. Nagase, Science 1997, 277, 78-81.
13. B. Twamley, C. D. Sofield, M. M. Olmstead, P. P. Power, J. Am. Chem. Soc. 1999, 121, 3357-3367.
14. L. Balázs, H. J. Breunig, Coord. Chem. Rev. 2006, 248, 603-621.
15. a) L. Balázs, H. J. Breunig, Angew. Chem. 2002, 114, 2411-2414;
16. Angew. Chem. Int. Ed. 2002, 41, 2309-2312;
17. b) G. Balázs, L. Balazs, H. J. Breunig, E. Lork, Organometallics 2003, 22, 2919-2924.
18. Y. Wang, B. Quillen, X.-J. Yang, P. Wie, Z. Chen, C. S. Wannere, P. v. R. Schleyer, G. H. Robinson, J. Am. Chem. Soc. 2005, 127, 7672-7673.
19. T. Sasamori, N. Takeda, M. Fujio, M. Kimura, S. Nagase, N. Tokitoh, Angew. Chem. 2002, 114, 147-150;
20. Angew. Chem. Int. Ed. 2002, 41, 139-141.
21. T. Sasamori, N. Takeda, T. Norihori, Phosphorus Sulfur Silicon Relat. Elem. 2001, 168-169, 413.
22. B. Schiemenz, P. P. Power, Angew. Chem. 1996, 108, 2288-2290;
23. Angew. Chem. Int. Ed. Engl. 1996, 35, 2150-2152.
24. Reviews: a) P. P. Power, ACS Symp. Ser. 2006, 91, 179-191;
25. b) P. P. Power, Appl. Organomet. Chem. 2005, 19, 488-493;
26. c) P. P. Power, Chem. Commun. 2003, 17, 2091-2101;
27. d) B. Twamley, S. T. Haubrich, P. P. Power, Adv. Organomet. Chem. 1999, 44, 1-65;
28. e) J. A. C. Clyburne, N. McMullen, Coord. Chem. Rev. 2000, 210, 73-99.
29. C. Marschner, Eur. J. Inorg. Chem. 1998, 221-226.
30. R. Fischer, T. Konopas, J. Baumgartner, C. Marschner, Organometallics 2004, 23, 1899-1907.
31. 3Bi with dichlorosilanes and have been crystallographically characterized. However, these species decompose quickly at low temperatures: a) S. Seidl, K. Hassler, J. Organomet. Chem. 1988, 374, 27;
32. b) G. M. Kolleger, H. Siegl, K. Hassler, K. Gruber, Organometallics 1996, 15, 4337-4338.
33. G. Linti, W. Köstler, Z. Anorg. Allg. Chem. 2002, 628, 63-66.
34. a) F. Calderazzo, A. Morvillo, G. Pelizzi, R. Poli, J. Chem. Soc., Chem. Commun. 1983, 507-508;
35. b) K. H. Whitmire, J. M. Cassidy, Acta Crystallogr., Sect. C 1992, 48, 917-919;
36. c) G. Balázs, H. Breunig, E. Lork, Organometallics 2002, 21, 2584-2586;
37. d) L. Balázs, H. Breunig, E. Lork, Z. Naturforsch.; Teil B 2005, 60, 180-182;
38. e) L. Balázs, H. Breunig, E. Lork, C. Silvestru, Eur. J. Inorg. Chem. 2003, 1361-1365;
39. f) A. J. Ashe III, J. W. Kampf, D. B. Puranik, S. M. Al-Taweel, Organometallics 1992, 11, 2743-2745;
40. g) L. Balázs, H. Breunig, E. Lork, A. Soran, C. Silvestru, Inorg. Chem. 2006, 45, 2341-2346.
41. 4 or higher oligomers with Bi-Bi bond lengths ranging from 2.941 to 3.209 Å (median 3.019 Å).
42. a) S. Müller-Becker, W. Frank, J. Schneider, Z. Anorg. Allg. Chem. 1993, 619, 1073-1082;
43. b) K. H. Whitmire, S. Hoppe, O. Sydora, J. J. Lolas, C. M. Jones, Inorg. Chem. 2000, 39, 85-97 and references cited therein;
44. c) E. V. Dikarev, B. Li, Inorg. Chem. 2004, 43, 3461-3466 and references cited therein.
45. C. v. Hänisch, D. Nikolova, Eur. J. Inorg. Chem. 2006, 4770-4773.
46. L. Xu, S. Bobev, J. El-Bahraoui, S. C. Sevov, J. Am. Chem. Soc. 2000, 122, 1838-1839.
47. J. M. Cassidy, K. H. Whitmire, Inorg. Chem. 1991, 20, 2788-2795.
48. H. Strong, P. J. Krusic, J. S. Filippo Jr, Inorg. Synth. 1990, 28, 203-207.
49. A. H. Cowley, N. C. Norman, M. Pakulski, J. Am. Chem. Soc. 1984, 106, 6844-6845.
50. a) T. Gröer, M. Scheer, J. Chem. Soc., Dalton Trans. 2000, 647-653;
51. b) T. Gröer, M. Scheer, Organometallics 2000, 19, 3683-3691.
52. [8b]) may likely be excluded due to the large size of the substituents.
53. A. B. Pangborn, M. A. Giardello, R. H. Grubbs, R. K. Rosen, F. J. Timmers, Organometallics 1996, 15, 1518-1520.
54. H. Hope, Prog. Inorg. Chem. 1995, 41, 1-19.
55. R. H. Blessing, Acta Crystallogr., Sect. A 1995, 51, 33-38.
56. G. M. Sheldrick, SADABS, Version 2.10, Siemens Area Detector Absorption Correction, University of Göttingen, Göttingen, Germany, 2003.
57. G. M. Sheldrick (private communication) TWINABS "An Empirical Correction for Absorption Anisotropy Applied to Twinned Crystals", v.1.05, University of Göttingen, Göttingen, Germany, 2003.
58. G. M. Sheldrick, SHELXTL, Version 6.1, Bruker AXS, Inc., Madison, WI, 2002.
59. G. M. Sheldrick, SHELXS97 and SHELXL97, University of Göttingen, Göttingen, Germany, 2002.