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Volumn , Issue 17, 2008, Pages 2739-2745

N-heterocyclic benzhydrylamines as new N,N-bidentate ligands in palladium complexes: Synthesis, characterization and catalytic activity

Author keywords

Benzhydrylamines; N,N ligands; Nitriles; Palladium

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; PALLADIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

EID: 53249129204     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200800154     Document Type: Article
Times cited : (29)

References (27)
  • 1
    • 2042507954 scopus 로고
    • and the references cited therein;
    • a) N. Miyaura, A. Suzuki, Chem. Rev. 1995, 95, 2457-2483 and the references cited therein;
    • (1995) Chem. Rev , vol.95 , pp. 2457-2483
    • Miyaura, N.1    Suzuki, A.2
  • 5
    • 33747071481 scopus 로고    scopus 로고
    • and the references cited therein. For recent review see
    • For recent review see: J.-P. Corbet, G. Mignani, Chem. Rev. 2006, 106, 2651-2710 and the references cited therein.
    • (2006) Chem. Rev , vol.106 , pp. 2651-2710
    • Corbet, J.-P.1    Mignani, G.2
  • 7
    • 35348925030 scopus 로고    scopus 로고
    • For recent phosphane-free catalytic systems, see: a
    • For recent phosphane-free catalytic systems, see: a) Z.-X. Wang, Z.-Y. Chai, Eur. J. Inorg. Chem. 2007, 4492-4499;
    • (2007) Eur. J. Inorg. Chem , pp. 4492-4499
    • Wang, Z.-X.1    Chai, Z.-Y.2
  • 17
    • 85163236554 scopus 로고    scopus 로고
    • Crystal data and structure refinements for 2a, 2c, and 2d: Analyses were carried out by using a Siemens SMART three-circle diffractometer equipped with a CCD bidimensional detector with Mo-Kα monochromatized radiation (λ, 0.71073 Å, Crystal data 2a: C19H18Cl2N2Pd, Mw, 451.65, monoclinic, space group Cc; dimensions: a, 8.5312(1) Å, b, 18.0606(3) Å, c, 12.2962(2) Å, β, 95.703(1)°, V, 1885.20(5) Å3; Z, 4; μ, 1.270 mm-1; 19418 reflections measured at room temperature; independent reflections: 5422 [5098 Fo > 4σ (Fo, data were collected up to a 2Θmax value of 60.12° 99.6% coverage, Number of variables: 217; R 1, 0.0202, wR2, 0.0432, S, 1.03
    • 2 = 0.0945). Data reduction was performed with the SAINT software. The absorption correction was based on multiple and symmetry-equivalent reflections in the data set by using the SADABS program based on the method of Blessing. The structures were solved by direct methods and refined by full-matrix least-squares with use of the SHELX-TL package. CCDC-677262 (for 2a), -677263 (for 2c), and -677264 (for 2d) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.


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