Development of a membrane reactor for decomposing hydrogen sulfide into hydrogen using a high-performance amorphous silica membrane

Journal of Membrane Science

Volumn 325, Issue 1, 2008, Pages 16-19

  Akamatsu, Kazuki ^a   Nakane, Masataka ^a   Sugawara, Takashi ^a   Hattori, Tadashi ^b   Nakao, Shin ichi ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b NAGOYA INDUSTRIAL SCIENCE RESEARCH INSTITUTE   (Japan)

Author keywords

Chemical vapor deposition; Hydrogen; Hydrogen sulfide; Membrane reactor; Silica membrane

Indexed keywords

BIOREACTORS; CHEMICAL VAPOR DEPOSITION; HYDROGEN; MEMBRANES; NONMETALS; OXYGEN; SILICA; SULFUR DETERMINATION;

AMORPHOUS SILICA; CVD METHOD; HYDROGEN PERMEANCE; MEMBRANE REACTOR; MEMBRANE REACTORS; SILICA MEMBRANE; TETRAMETHOXY SILANE;

HYDROGEN SULFIDE;

HYDROGEN; HYDROGEN SULFIDE; NITROGEN; OXYGEN; SILICON DIOXIDE; TETRAMETHOXYSILANE;

ARTICLE; CATALYSIS; DECOMPOSITION; MEMBRANE REACTOR; MEMBRANE TECHNOLOGY; PRIORITY JOURNAL;

EID: 53249113130     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2008.08.005     Document Type: Article

References (14)

1. Tsuru T., Yamaguchi K., Yoshioka T., and Asaeda M. Methane steam reforming by microporous catalytic membrane reactors. AIChE J. 50 (2004) 2794
2. Nomura M., Seshimo M., Aida H., Nakatani K., Gopalakrishnan S., Sugawara T., Ishikawa T., Kawamura M., and Nakao S.-I. Preparation of a catalyst composite silica membrane reactor for steam reforming reaction by using a counter diffusion CVD. Ind. Eng. Chem. Res. 45 (2006) 3950
3. Itoh N., Tamura E., Hara S., Takahashi T., Shono A., Satoh K., and Namba T. Hydrogen recovery from cyclohexane as a chemical hydrogen carrier using a palladium membrane reactor. Catal. Today 82 (2003) 119
4. Battersby S., Teoxeora P.W., Beltramini J., Duke M.C., Rudolph V., and da Costa J.C.D. An analysis of the Peclet and Damkohker numbers for dehydrogenation reactions using molecular sieve silica (MSS) membrane reactors. Catal. Today 116 (2006) 12
5. Kameyama T., Dokiya M., Fujishige M., Yokokawa H., and Fukuda K. Possibility for effective production of hydrogen from hydrogen sulfide by means of a porous vycor glass membrane. Ind. Eng. Chem. Fundam. 20 (1981) 97
6. 2 films. Chem. Eng. Sci. 44 (1989) 1829
7. Zaman J., and Chakma A. A simulation study on the thermal decomposition of hydrogen sulfide in a membrane reactor. Int. J. Hydrogen Energy 20 (1995) 21
8. Kameyama T., Dokiya M., Fujishige M., Yokokawa H., and Fukuda K. Production of hydrogen from hydrogen sulfide by means of selective diffusion membranes. Int. J. Hydrogen Energy 8 (1983) 5
9. Ohashi H., Ohya H., Aihara M., Negishi Y., and Semenova S.I. Hydrogen production from hydrogen sulfide using membrane reactor integrated with porous membrane having thermal and corrosion resistance. J. Membr. Sci. 146 (1998) 39
10. Edlund D.J., and Pledger W.A. Themolysis of hydrogen sulfide in a metal-membrane reactor. J. Membr. Sci. 77 (1993) 255
11. Nomura M., Ono K., Gopalakrishnan S., Sugawara T., and Nakao S.-I. Preparation of a stable silica membrane by a counter diffusion chemical vapor deposition method. J. Membr. Sci. 251 (2005) 151
12. Ohta Y., Akamatsu K., Sugawara T., Nakao A., Miyoshi A., and Nakao S. Development of pore size-controlled silica membranes for gas separation by chemical vapor deposition. J. Membr. Sci. 315 (2008) 93
13. Yoshino Y., Suzuki T., Nair B.N., Taguchi H., and Ito N. Development of tubular substrates, silica based membranes and membrane modules for hydrogen separation at high temperature. J. Membr. Sci. 267 (2005) 8
14. Breck D.W. Zeolite Molecular Sieves: Structure, Chemistry, and Use (1974), John Wiley & Sons, New York p. 636