[1,2]-Wittig rearrangement of (benzyloxy)acetamides

Synlett

Volumn , Issue 15, 2008, Pages 2345-2347

  Hameury, Thomas ^a   Guillemont, Jérôme ^b   Van Hijfte, Luc ^b   Bellosta, Véronique ^a   Cossy, Janine ^a  

^a CNRS   (France)

^b Janssen Cilag Research Center   (France)

Author keywords

1,2 Wittig rearrangement; Amides; Phase transfer catalysis

Indexed keywords

(BENZYLOXY)ACETAMIDE DERIVATIVE; ACETAMIDE DERIVATIVE; ALPHA HYDROXYAMIDE DERIVATIVE; AMIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; ETHERIFICATION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SUBSTITUTION REACTION; WITTIG REARRANGEMENT;

EID: 52949101355     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1078268     Document Type: Article

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35. minor in all cases.
36. minor = 5.0 Hz. Therefore, the syn stereochemistry remained ambiguous in this latter case.