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Gas-phase studies were performed with 1-propene and 1-pentene; the reaction with 1-hexene is expected to be identical
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Gas-phase studies were performed with 1-propene and 1-pentene; the reaction with 1-hexene is expected to be identical.
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22
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The recombination rate may be slowed by solvation of a token ligand from the solvent bath or coordination of the alkyl portion of the pentadiene ligand, and therefore, re-formation of the parent complex may take 100's of picoseconds. 26,50,51
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A comparison of the observed peak height ratio for the 1937 and 2030 cm-1 peaks and the reported peak heights for the 1929, 1937, and 2030 cm-1 peaks supports the hypothesis that the 1929 and 1937 cm -1 peaks are likely overlapped in these experiments
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-1 peaks are likely overlapped in these experiments.
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42
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34547374581
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Rise time constants for this fast rise of both 32b peaks were independently verified, and there is excellent agreement of all reported time constants when the rise times were not fixed
-
32b peaks were independently verified, and there is excellent agreement of all reported time constants when the rise times were not fixed.
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49
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The M-H stretch was not resolvable in these spectra most likely because the amplitude is extremely small, as is consistent with previous reports for an analogous cobalt complex, (e.g., see (a) Edgell, W. F.; Summitt, R. J. Am. Chem. Soc. 1961, 83, 1772.
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