메뉴 건너뛰기




Volumn 111, Issue 25, 2007, Pages 8789-8795

The influence of the metal spin state in the iron-catalyzed alkene isomerization reaction studied with ultrafast infrared spectroscopy

Author keywords

[No Author keywords available]

Indexed keywords

FREE ALKENES; PENTADIENE LIGANDS; RUTHENIUM-ASSISTED ALKENE ISOMERIZATION;

EID: 34447508239     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp068576j     Document Type: Article
Times cited : (26)

References (55)
  • 19
    • 34547256541 scopus 로고    scopus 로고
    • Gas-phase studies were performed with 1-propene and 1-pentene; the reaction with 1-hexene is expected to be identical
    • Gas-phase studies were performed with 1-propene and 1-pentene; the reaction with 1-hexene is expected to be identical.
  • 22
    • 34547342028 scopus 로고    scopus 로고
    • Coordination of the second alkene was presumed to be limited by the gas-phase collision rate
    • Coordination of the second alkene was presumed to be limited by the gas-phase collision rate.
  • 36
    • 34547269099 scopus 로고    scopus 로고
    • The recombination rate may be slowed by solvation of a token ligand from the solvent bath or coordination of the alkyl portion of the pentadiene ligand, and therefore, re-formation of the parent complex may take 100's of picoseconds. 26,50,51
    • 26,50,51
  • 40
    • 34547296672 scopus 로고    scopus 로고
    • A comparison of the observed peak height ratio for the 1937 and 2030 cm-1 peaks and the reported peak heights for the 1929, 1937, and 2030 cm-1 peaks supports the hypothesis that the 1929 and 1937 cm -1 peaks are likely overlapped in these experiments
    • -1 peaks are likely overlapped in these experiments.
  • 42
    • 34547374581 scopus 로고    scopus 로고
    • Rise time constants for this fast rise of both 32b peaks were independently verified, and there is excellent agreement of all reported time constants when the rise times were not fixed
    • 32b peaks were independently verified, and there is excellent agreement of all reported time constants when the rise times were not fixed.
  • 49
    • 1642411971 scopus 로고    scopus 로고
    • Spin-Forbidden Reactions in Transition Metal Chemistry
    • Cundari, T. R, Ed, Marcel Dekker, Inc: New York
    • Harvey, J. N. Spin-Forbidden Reactions in Transition Metal Chemistry. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker, Inc: New York, 2001; Vol. 291.
    • (2001) Computational Organometallic Chemistry , vol.291
    • Harvey, J.N.1
  • 52
    • 0009568907 scopus 로고    scopus 로고
    • The M-H stretch was not resolvable in these spectra most likely because the amplitude is extremely small, as is consistent with previous reports for an analogous cobalt complex, e.g, see (a) Edgell, W. F, Summitt, R. J. Am. Chem. Soc. 1961, 83, 1772
    • The M-H stretch was not resolvable in these spectra most likely because the amplitude is extremely small, as is consistent with previous reports for an analogous cobalt complex, (e.g., see (a) Edgell, W. F.; Summitt, R. J. Am. Chem. Soc. 1961, 83, 1772.
  • 55
    • 34547276849 scopus 로고    scopus 로고
    • Sweany, R. L. Matrix Studies of Tansition Metal Hydrides. In Transition Metal Hydrides; Dedieu, A., Ed.; Wiley-VCH: New York, 1991.
    • (d) Sweany, R. L. Matrix Studies of Tansition Metal Hydrides. In Transition Metal Hydrides; Dedieu, A., Ed.; Wiley-VCH: New York, 1991.)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.