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Crystallographic data for 10: C40H24B 1N3O1·CH3OH, M r= 605.47, monoclinic, a=11.032(6, b=19.682(8, c= 15.304(9) Å, β=96.020(18)°, V=3305(3) Å3, T=123(2) K, space group P21/a, Z=4, ρ=1.217 g cm-3, μ(MoKα, 0.075 mm-1, 24698 reflections measured, 5778 unique (R int= 0.1496) which were used in all calculations, R(F2)=0.1679 (all data, R1=0.0979 (I>2σ(I, GOF=1.039. Crystallographic data for 11: C58H36BN3O, M r=801.71, orthorhombic, a= 24.337(4, b=17.749(3, c=22.934(3) Å, V=9906(2) Å3, T= 123(2) K, space group Pbcn no. 60, Z=8, 1=1.075 g c
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1=0.0974 (I>2σ(I)), GOF=1.073. CCDC-680553 (10) and CCDC-680554 (11) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif. The SQUEEZE program in PLATON was used for analysis to remove the solvent densities: a) P. van der Sluis, A. L. Spek, Acta Crystallogr. Sect. A 1990, 46, 194;
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Gaussian03 (Revision B.05): M. J. Frisch et al., see Supporting Information.
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Gaussian03 (Revision B.05): M. J. Frisch et al., see Supporting Information.
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