Structure and properties of [CrIIIF(NCMe)5](BF 4)2·MeCN: A nonaqueous source of Cr IIIF2+ and a building block for new Prussian-blue-like magnetic materials

Inorganic Chemistry

Volumn 47, Issue 17, 2008, Pages 7768-7774

  Nelson, Kendric J ^a   DiPasquale, Antonio G ^b   Rheingold, Arnold L ^b   Daniels, Matthew C ^a   Miller, Joel S ^a  

^a UNIVERSITY OF UTAH   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 51849136851     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800837f     Document Type: Article

References (102)

1. (a) Fehrmann, K. R. A.; Garner, C. S. J. Am. Chem. Soc. 1960, 82, 6294.
2. (b) Vaughn, J. W.; Krainc, B. J. Inorg. Chem. 1965, 4, 1077.
3. (c) Vaughn, J. W.; Seiler, G. J. Inorg. Chem. 1974, 13, 598.
4. (d) Wong, C. F. C.; Kirk, A. D. Can. J. Chem. 1975, 53, 3388.
5. (e) Vaughn, J. W. Inorg. Chem. 1981, 20, 2397.
6. (f) Díaz, C.; Seguí, A.; Ribas, J.; Solans, X.; Font-Altaba, M.; Solans, A.; Casabó, J. Trans. Met. Chem. 1984, 9, 469.
7. (g) Beveridge, K. A.; Bushneil, G. W.; Kirk, A. D. Acta Crystallogr., Sect. C 1985, 41, 899.
8. (h) Sanzenbacher, R.; Böttcher, A.; Elias, H.; Hüber, M.; Haase, W.; Glerup, J.; Jensen, T. B.; Neuburger, M.; Zehnder, M.; Springborg, J.; Olsen, C. E. Inorg. Chem. 1996, 35, 7493.
9. (i) Ouellette, W.; Prosvirin, A. V.; Chieffo, V.; Dunbar, K. R.; Hudson, B.; Zubieta, J. Inorg. Chem. 2006, 45, 9346.
10. (a) Babel, D. Struct. Bonding (Berlin) 1967, 3, 1.
11. (b) Steiner, M.; Krüger, W.; Babel, D. Solid State Commun. 1971, 9, 227.
12. (c) Heger, G.; Geller, R.; Babel, D. Solid State Commun. 1971, 9, 335.
13. (d) Tressaud, A.; Dance, J.-M. Struct. Bonding (Berlin) 1982, 52, 87.
14. (e) Babel, D. Comments Inorg. Chem. 1986, 5, 285.
15. (f) Tressaud, A.; Bartlett, N. J. Solid State Chem. 2001, 162, 333.
16. (g) Strempfer, J.; RUtt, U.; Bayrakci, S. P.; Brückel, T.; Jauch, W. Phys. Rev. B: Condens. Matter Mater. Phys. 2004, 69, 014417.
17. (h) Margadonna, S.; Karotsis, G. J. Mater. Chem. 2007, 17, 2013.
18. (a) O'Donnell, T. A.; Stewart, D. F. Inorg. Chem. 1966, 5, 1434.
19. (b) O'Donnell, T. A.; Stewart, D. F.; Wilson, P. Inorg. Chem. 1966, 5, 1438.
20. (c) Canterford, J. H.; O'Donnell, T. A. Inorg. Chem. 1966, 5, 1442.
21. (d) Kiplinger, J. L.; Richmond, T. G.; Osterberg, C. E. Chem. Rev. 1994, 94, 373.
22. (e) Su, M.; Chu, S. J. Am. Chem. Soc. 1997, 119, 10178.
23. (f) Au, C.-T.; Zhou, X. J. Chem. Soc., Faraday Trans. 1997, 93, 485.
24. (g) Chen, Q.; Freiser, B. S. J. Phys. Chem. A 1998, 102, 3343.
25. (h) Bosque, R.; Clot, E.; Fantacci, S.; Maseras, F.; Eisenstein, O.; Perutz, R. N.; Renkema, K. B.; Coulton, K. G. J. Am. Chem. Soc. 1998, 120, 12634.
26. (i) Jakt, M.; Johannissen, L.; Rzepa, H. S.; Widdowson, D. A.; Wilhelm, R. J. Chem. Soc., Perkin Trans. 2002, 576.
27. (j) Gerard, H.; Davidson, E. R.; Eisenstein, O. Mol. Phys. 2002, 100,533.
28. (k) Reinhold, M.; McGrady, J. E.; Perutz, R. N. J. Am. Chem. Soc. 2004, 126, 5258.
29. (l) Colmenares, F.; Torrens, H. J. Phys. Chem. A 2005, 109, 10587.
30. (m) Lyon, J. T.; Andrews, L. Inorg. Chem. 2007, 46, 4799.
31. (a) Blasse, G. Chem. Mater. 1994, 6, 1465.
32. (b) Ainslie, B. J.; Davey, S. T.; Szebesta, D.; Williams, J. R.; Moore, M. W.; Whitley, T.; Wyatt, R. J. Non-Cryst. Solids 1995, 184, 225.
33. (c) MacFarlane, D. R. Ceram. Int. 1996, 22, 535.
34. (d) Fujihara, S. Recent Res. Dev. Mater. Sci. 2002, 3, 619.
35. (a) van Slageren, J.; Sessoli, R.; Gatteschi, D.; Smith, A. A.; Helliwell, M.; Winpenny, R. E. P.; Cornia, A.; Barra, A.-L.; Jansen, A. G. M.; Rentschler, E.; Timco, G. A. Chem.-Eur. J. 2002, 8, 277.
36. (b) Larsen, F. K.; Overgaard, J.; Parsons, S.; Rentschler, E.; Smith, A. A.; Timco, G. A.; Winpenny, R. E. P. Angew. Chem., Int. Ed. 2003, 42, 5978.
37. (c) Heath, S. L.; Laye, R. H.; Muryn, C. A.; Lima, N.; Sessoli, R.; Shaw, R.; Teat, S. J.; Timco, G. A.; Winpenny, R. E. P. Angew. Chem., Int. Ed. 2004, 43, 6132.
38. (d) Affronte, M.; Casson, I.; Evangelisti, M.; Candini, A.; Carretta, S.; Muryn, C. A.; Teat, S. J.; Timco, G. A.; Wernsdorfer, W.; Winpenny, R. E. P. Angew. Chem., Int. 2005, 44, 6496.
39. Christou, G.; Gatteschi, G.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25 (11), 66.
40. (b) Gatteschi, D.; Hendrickson, D. N.; Sessoli, R.; Villain, J. Molecular Nanomagnets; Oxford University Press: New York, 2006.
41. Gao, E.-Q.; Liu, N.; Cheng, A.-L.; Gao, S. Chem. Commun. 2007, 2470.
42. (a) Paul, G.; Choudhury, A.; Sampathkumaran, E. V.; Rao, C. N. R. Angew. Chem., Int. Ed. 2002, 41, 4297.
43. (b) Paul, G.; Choudhury, A.; Rao, C. N. R. Chem. Mater. 2003, 15, 1174.
44. (c) Behera, J. N.; Paul, G.; Choudhury, A.; Rao, C. N. R. Chem. Commun. 2004, 456.
45. (d) Rao, C. N. R.; Sampathkumaran, E. V.; Nagarajan, R.; Paul, C.; Behera, J. N.; Choudhury, A. Chem. Mater. 2004, 16, 1441.
46. (e) Behera, J. N.; Gopalkrishnan, K. V.; Rao, C. N. R. Inorg. Chem. 2004, 43, 2636.
47. (f) Behera, J. N.; Rao, C. N. R. J. Am. Chem. Soc. 2006, 128, 9334.
48. (g) Behera, J. N.; Rao, C. N. R. Inorg. Chem. 2006, 45, 9475.
49. (h) Behera, J. N.; Rao, C. N. R. Dalton Trans. 2007, 669.
50. Choudhury, A.; Natarajan, S.; Rao, C. N. R. Chem. Commun. 1999, 1305.
51. (a) Buschmann, W. E.; Miller, J. S. Chem.-Eur. J. 1998, 1731.
52. (b) Buschmann, W. E.; Miller, J. S.; Bowman-James, K.; Miller, C. N. Inorg. Synth. 2002, 33, 83.
53. (c) Henitz, R. A.; Smith, J. A.; Szalay, P. S.; Weisgerber, A.; Dunbar, K. A.; Beck, K.; Coucouvanis, D. Inorg. Synth. 2002, 33, 75.
54. Hatlevik, Ø.; Arif, A. M.; Miller, J. S. J. Phys. Chem. Solids 2004, 65, 61.
55. Nelson, K. J.; Daniels, M. C.; Reiff, W. M.; Troff, S. A.; Miller, J. S. Inorg. Chem. 2007, 46, 10093.
56. (a) Chia, Y.; King, E. Discuss. Faraday Soc. 1960, 29, 109.
57. (b) Moore, P.; Basolo, F. Inorg. Chem. 1965, 4, 1670.
58. (a) Swaddle, T. W.; King, E. L. Inorg. Chem. 1965, 4, 532.
59. (b) Vaughn, J. W.; King, E. L. Inorg. Chem. 1985, 24, 4221.
60. (a) Schläfer, H. L.; Gausmann, H.; Zander, H. Inorg. Chem. 1967, 6, 1528.
61. (b) Kurzak, K.; Kołkowicz, A.; Bartecki, A. Bull. Polish Acad. Sci. Chem. 1989, 37, 423.
62. Van Der Kooy, A.; Gellings, P. J. J. Inorg. Nucl. Chem. 1970, 32, 3301.
63. (a) Verdaguer, M.; Girolami, G. S. In Magnetism - Molecules to Materials V; Miller, J. S., Drillon, M., Eds.; Wiley-VCH: Weinheim, Germany, 2005; Vol. 5, p 283.
64. (b) Hashimoto, K.; Ohkoshi, S. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 2977.
65. (c) Verdaguer, M.; Bleuzen, A.; Marvaud, V.; Vaissermann, J.; Seuleiman, M.; Desplanches, C.; Scuiller, A.; Train, C.; Garde, R.; Gelly, G.; Lomenech, C.; Rosenman, I.; Veillet, P.; Cartier, C.; Villain, F. Coord. Chem. Rev. 1999, 190-192, 1023.
66. (d) Verdaguer, M.; Bleuzen, A.; Train, C.; Garde, R.; Fabrizi de Biani, F.; Desplanches, C. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 2959.
67. (a) Ribas, J.; Casabó, J.; Serra, M.; Coronas, J. M. Inorg. Chim. Acta 1979, 36, 41.
68. (b) Ribas, J.; Casabó, J.; Monfort, M.; Alvarez, M. L.; Coronas, J. M. J. Inorg. Nucl. Chem. 1980, 42, 707.
69. (c) Ribas, J.; Serra, M.; Escuer, A.; Coronas, J. M. J. Inorg. Nucl. Chem. 1981, 43, 3113.
70. (d) Serra, M.; Escuer, A.; Ribas, J. Thermochim. Acta 1982, 56, 183.
71. (e) Corbella, M.; Serra, M.; Martínez-Sarrión, L.; Ribas, J. Thermochim. Acta 1982, 57, 283.
72. (f) Ribas, J.; Martínez, M. L.; Serra, M.; Monfort, M.; Escuer, A.; Navarro, N. Trans. Met. Chem. 1983, 8, 87.
73. (g) Ribas, J.; Monfort, M. Trans. Met. Chem. 1984, 9, 407.
74. (h) Corbella, M.; Monfort, M.; Ribas, J. Z. Anorg. Allg. Chem. 1986, 543, 233.
75. (i) Johda, M.; Suzuki, M.; Uehara, A. Bull. Chem. Soc. Jpn. 1989, 62, 738.
76. Le Maguerès, P.; Ouahab, L.; Briard, P.; Even, J.; Bertault, M.; Toupet, L.; Rámos, J.; Gómez-García, C. J.; Delhaès, P. Mol. Cryst. Liq. Cryst. 1997, 305, 479.
77. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518.
78. Miller, J. S.; Kravitz, S. H.; Kirschner, S.; Ostrowski, P.; Nigrey, P. J. J. Chem. Educ 1978, 55, 181;
79. Quant. Chem. Prog. Exch. 1978, 10, 341.
80. Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, C.; Giacovazzo, C.; Guagliardi, A.; Moliteni, A. G. G.; Polidori, G.; Spagna, R. SIR97, Release 1.02.
81. Sheldrick, G. M. SHELX97, Release 97-2; University of Göttingen: Göttingen, Germany, 1997. Includes SHELXS97, SHELXL97, CIFT-AB, programs for crystal structure analysis.
82. Ghosh, D. C.; Bhattacharyya, S. Indian J. Chem., Sect. A 2006, 45A, 1789.
83. Cotton, F. A.; Daniels, L. M.; Murillo, C. A.; Pascual, I. J. Am. Chem. Soc. 1997, 119, 10223.
84. (a) Min, K. S.; Arif, A. M.; Miller, J. S. Inorg. Chim. Acta 2007, 360, 1854.
85. (b) Gorrell, I. B.; Gerard, P. Inorg. Chem. 1990, 29, 2452.
86. (c) Zhu, Q.; Nelson, K. J.; Shum, W. W.; DiPasquale, A.; Rheingold, A. L.; Miller, J. S. Inorg. Chim. Acta 2008, 361, [online]DOI:, 10.1016/j.ica.2008.04.015.
87. Crabtree, R. H.; Hlatky, G. G.; Holt, E. M. J. Am. Chem. Soc. 1983, 105, 7302.
88. Babel, D. Z. Anorg. Allg. Chem. 1974, 406, 23.
89. Nakamoto, K. In Infrared and Raman Spectra of Inorganic and Coordination Compounds Part B: Applications in Coordination, Organometallic, and Bioinorganic Chemistry, 5th ed.; Wiley-Interscience: New York, 1997; pp 184.
90. Boudreaus, E. A.; Mulay, L. N. In Theory and Applications of Molecular Paramagnetism; Wiley-Interscience; New York, 1976; pp 167.
91. a+0.8·z(MeCN) composition were noted.
92. (a) Ludi, A.; Güdel, H. U. Struct. Bonding (Berlin) 1973, 14, 1.
93. (b) Dunbar, K. R.; Heintz, R. A. Prog. Inorg. Chem. 1997, 45, 283.
94. 18b
95. (a) Stumpf, H. O.; Pei, Y.; Kahn, O.; Sletten, J.; Renard, J. P. J. Am. Chem. Soc. 1993, 115, 6738.
96. (b) Stumpf, H. O.; Ouahab, L.; Pei, Y.; Bergerat, P.: Kahn, O. J. Am. Chem. Soc. 1994, 116, 3866.
97. (a) Néel, L. Ann. Phys. 1948, 3, 137.
98. (b) Smart, J. S. Am. J. Phys. 1955, 23, 356.
99. max = peak maximum of the temperature at low frequency, Δlog ω = difference in the logarithms of the high and low frequencies (ω).
100. (a) Buschmann, W. E.; Ensling, J.; Gütlich, P.; Miller, J. S. Chem.-Eur. J. 1999, 5, 3019.
101. (b) Sendek, M.; Csach, K.; Kavecansky, V.; Lukácová, M.; Marysko, M.; Mitróová, Z.; Zentko, A. Phys. Status Solidi A 2003, 196, 225.
102. (c) Nelson, K. J.; Giles, I. D.; Troff, S. A.; Arif, A. M.; Miller, J. S. Inorg. Chem. 2006, 45, 8922.