[CrIII(NCMe)6]3+ - A labile Cr III source enabling formation of Cr[M(CN)6] (M = V, Cr, Mn, Fe) Prussian blue-type magnetic materials

Inorganic Chemistry

Volumn 46, Issue 24, 2007, Pages 10093-10107

  Nelson, Kendric J ^a   Daniels, Matthew C ^a   Reiff, William M ^b   Troff, Shayla A ^a   Miller, Joel S ^a  

^a UNIVERSITY OF UTAH   (United States)

^b NORTHEASTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37249031389     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic7008489     Document Type: Article

References (78)

1. Verdaguer, M.; Girolami, G. S. In Magnetism - Molecules to Materials; Miller, J. S., Drillon, M., Eds.; Wiley-VCH: Weinheim, Germany, 2005; Vol. 5, pp 283-346.
2. Morin, B. G.; Hahm, C.; Epstein, A. J.; Miller, J. S. J. Appl. Phys. 1994, 75, 5782.
3. Miller, J. S. Adv. Mater. 1994, 6, 322.
4. Landee, C. P.; Melville, D.; Miller, J. S. In NATO ARW Molecular Magnetic Materials; Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds.; Kluwer Academic Publishers: London, 1991; Vol. E198, p 395.
5. Prigodin, V. N.; Raju, N. P.; Pokhodnya, K. I.; Miller, J. S.; Epstein, A. J. Adv. Mater. 2002, 14, 1230.
6. Ludi, A.; Güdel, H. U. Struct. Bonding 1973, 14, 1.
7. Dunbar, K. R.; Heintz, R. A. Prog. Inorg. Chem. 1997, 45, 283.
8. Mallah, T.; Thiébaut, S.; Verdaguer, M.; Veillet, P. Science 1993, 262, 1554.
9. Buschmann, W. E.; Paulson, S. C.; Wynn, C. M.; Girtu, M.; Epstein, A. J.; White, H. S.; Miller, J. S. Adv. Mater. 1997, 9, 645.
10. Buschmann, W. E.; Paulson, S. C.; Wynn, C. M.; Girtu, M.; Epstein, A. J.; White, H. S.; Miller, J. S. Chem. Mater. 1998, 10, 1386.
11. (a) Ferlay, S.; Mallah, T.; Ouahes, R.; Veillet, P.; Verdaguer, M. Nature 1995, 378, 701.
12. (b) Dujardin, E.; Ferlay, S.; Phan, X.; Desplanches, C.; Moulin, C. C. D.; Sainctavit, P.; Baudelet, F.; Dartyge, E.; Veillet, P.; Verdaguer, M. J. Am. Chem. Soc. 1998, 120, 11347.
13. (c) Ferlay, S.; Mallah, T.; Ouahes, R.; Veillet, P.; Verdaguer, M. Inorg. Chem. 1999, 38, 229.
14. (d) Verdaguer, M.; Bleuzen, A.; Marvaud, V.; Vaissermann, J.; Seuleiman, M.; Desplanches, C.; Scuiller, A.; Train, C.; Garde, R.; Gelly, G.; Lomenech, C.; Rosenman, I.; Veillet, P.; Cartier, C.; Villain, F. Coord. Chem. Rev. 1999, 190-192, 1023.
15. (e) Verdaguer, M.; Bleuzen, A.; Train, C.; Garde, R.; Fabrizi de Biani, F.; Desplanches, C. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 2959.
16. (f) K. Hashimoto, S. Ohkoshi, Philos. Trans. R. Soc. London, Ser. A 1999, 357, 2977.
17. (a) Hatlevik, Ø.; Buschmann, W. E.; Zhang, J.; Manson, J. L.; Miller, J. S. Adv. Mater. 1999, 11, 914.
18. (b) Holmes, S. M.; Girolami, G. S. J. Am. Chem. Soc. 1999, 121, 5593.
19. (a) Swaddle, T. W. Coord. Chem. Rev. 1974, 14, 217.
20. (b) Prasad, D.-R.; Ramasami, T.; Ramaswamy, D.; Santappa, M. Inorg. Chem. 1980, 19, 3181.
21. (c) Xu, F.-C.; Krause, H. R.; Swaddle, T.W. Inorg. Chem. 1985, 24, 267.
22. (d) Lincoln, S. F. Helv. Chim. Acta 2005, 88, 523.
23. Sato, O.; Gu. Z.; Etoh, H.; Ichiyanagi, J.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Chem. Lett. 1997, 37.
24. (a) Shriver, D. F.; Shriver, S. A.; Anderson, S. E. Inorg. Chem. 1965, 4, 725.
25. (b) Brown, D. B.; Shriver, D. F.; Schwartz, L. H. Inorg. Chem. 1968, 7, 77.
26. (c) House, J. E., Jr.; Bailar, J. C., Jr. Inorg. Chem. 1969, 8, 672.
27. (d) Reguera, E;, Bertrán, J. F.; Nuñez, I. Polyhedron 1994, 13, 1619.
28. Dostal, A.; Schröder, U.; Scholz, F. Inorg. Chem. 1995, 34, 1711.
29. Coronado, E.; Giménez-López, M. C.; Levchenko, G.; Romero, F. M.; García-Baonza, V.; Milner, A.; Paz-Pasternak, M. J. Am. Chem. Soc. 2005, 127, 4580.
30. (a) Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Science 1996, 271, 49.
31. (b) Sato, O.; Gu, Z.; Etoh, H.; Ichiyanagi, J.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Chem. Lett. 1997, 37.
32. Buschmann, W. E.; Miller, J. S. Inorg. Chem. 2000, 39, 2411.
33. Nelson, K. J.; Giles, I. D.; Troff, S. A.; Arif, A. M.; Miller, J. S. Inorg. Chem. 2006, 45, 8922.
34. Hatlevik, Ø.; Arif, A. M.; Miller, J. S. J. Phys. Chem. Solids 2004, 65, 61.
35. Le Maguerès, P.; Ouahab, L.; Briard, P.; Even, J.; Bertault, M.; Toupet, L.; Rámos, J.; Gómez-García, C. J.; Delhaès, P. Mol. Cryst. Liq. Cryst. 1997, 305, 479.
36. Gritzner, G.; Danksagmüller, K.; Gutmann, V. J. Electroanal. Chem. 1978, 90, 203.
37. The thermal instability likely contributes to the deviations in the elemental analyses data, and therefore, a larger tolerance was allowed in fitting the chemical composition.
38. -1 and those reported in the literature is likely shifted due to the spectra being measured in MeCN in our experiments.
39. 15 where electron transfer occurs. However, in the preparation reported here, no electron transfer is needed to obtain the product.
40. Miller, J. S.; Kravitz, S. H; Kirschner, S.; Ostrowski, P.; Nigrey, P. J. J. Chem. Ed. 1978, 55, 181.
41. Nakamoto, K. In Infrared and Raman Spectra of Inorganic and Coordination Compounds Part B: Applications in Coordination, Organometallic, and Bioinorganic Chemistry, 5th ed.; Wiley-Inter-science: New York, 1997; p 111.
42. Martínez-Garcia, R.; Knobel, M.; Reguera, E. J. Phys. Chem. B 2006, 110, 7296.
43. Eller, S.; Fischer, R. D. Inorg. Chem. 1990, 29, 1289.
44. Ghosh, S. N. J. Inorg. Nucl. Chem. 1974, 36, 2465.
45. (a) Vertelmann, E. J. M.; Maccallini, E.; Gournis, D.; Rudolf, P.; Bakas, T.; Luzon, J.; Broer, R.; Pugzlys, A.; Lummen, T. T. A.; van Loosdrecht, P. H. M.; van Koningsbruggen, P. J. Chem. Mater. 2006, 18, 1951.
46. (b) Matsuda, T.; Tokoro, H.; Hashimoto, K.; Ohkoshi, S. Dalton Trans. 2006, 5046.
47. -1 value would be consistent. These oxidation states do not fit the magnetic data and are therefore considered less likely.
48. Shriver, D. F.; Atkins, P. W. Inorganic Chemistry, 3rd ed.; Oxford University Press, 1999.
49. Katafias, A.; Impert, O.; Kita, P.; Wrzeszcz, G. Trans. Met. Chem. 2004, 29, 855.
50. Chatlas, J.; Impert, O.; Katafias, A.; Kita, P.; Wrzeszcz, G.; Eriksen, J.; Monsted, O.; Mills, A. Trans. Met. Chem. 2004, 29, 634.
51. Tuwar, S. M.; Nandibewoor, S. T.; Raju, J. R. Trans. Met. Chem. 1991, 16, 335.
52. (a) Greenwood, N. N.; Gibb, T. C. In Mössbauer Spectroscopy; Chapman and Hall, Ltd.: London, 1971; pp 169-182.
53. (b) Sato, O.; Einaga, Y.; Fujishima, A.; Hashimoto, K. Inorg. Chem. 1999, 38, 4405.
54. Boudreaux, E. A.; Mulay, L. N. In Theory and Applications of Molecular Paramagnetism; Wiley-Interscience: New York, 1976; p 159.
55. Figgis, B. N.; Lewis, J.; Mabbs, F. J. Chem. Soc. 1960, 2480.
56. Baker, J. M.; Bleaney, B.; Bowers, K. D. Proc. Phys. Soc. 1956, B 69, 1205.
57. Cooke, A. H.; Duffus, H. J. Proc. Phys. Soc. 1955, A 68, 32.
58. Kamimura, H. J. Phys. Soc. Jpn. 1956, 11, 1171.
59. Udachin, Y. N. Dyatkina, M. E. J. Struct. Chem. 1967, 8, 325.
60. Figgis, B. N.; Gerloch, M.; Mason, R. Proc. Roy. Soc. London 1969, A 309, 91.
61. Sharpe, A. G. In The Chemistry of Cyano Complexes of the Transition Metals; Academic Press: New York, 1976.
62. 6 has a g value of 1.98.
63. Entley, W. R.; Girolami, G. S. Science 1995, 268, 397.
64. (a) Stumpf, H. O.; Pei, Y.; Kahn, O.; Sletten, J.; Renard, J. P. J. Am. Chem. Soc. 1993, 115, 6738.
65. (b) Stumpf, H. O.; Ouahab, L.; Pei, Y.; Bergerat, P.; Kahn, O. J. Am. Chem. Soc. 1994, 116, 3866.
66. (a) Néel, L. Ann. Phys. 1948, 3, 137.
67. (b) Smart, J. S. Am. J. Phys. 1955, 23, 356.
68. max = peak maximum of the temperature at low frequency, and Δ log ω = difference in the logarithms of the high and low frequencies (ω).
69. (a) Buschmann, W. E.; Ensling, J.; Gütlich, P.; Miller, J. S. Chem. - Eur. J. 1999, 5, 3019.
70. (b) Sendek, M.; Csach, K.; Kavecansky, V.; Lukácová, M.; Marysko, M.; Mitróová, Z.; Zentko, A. Phys. Status Solidi A 2003, 196, 225.
71. Kurtz, W.; Babel, D. Solid State Commun. 1983, 48, 277.
72. Entley, W. R.; Girolami, G. S. Inorg. Chem. 1994, 33, 5165.
73. Ito, A.; Suenaga, M.; Ôno, K. J. Chem. Phys. 1968, 48, 3597.
74. Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Science 1996, 272, 704.
75. Matsuda, T.; Tokoro, H.; Hashimoto, K.; Ohkoshi, S. Dalton Trans. 2006, 5046.
76. Egan, L.; Kamenev, K.; Papanikolaou, D.; Takabayashi, Y.; Margadonna, S. J. Am. Chem. Soc. 2006, 128, 6034.
77. Carlin, R. In Magnetochemistry; Springer-Verlag: New York, 1986.
78. Smart, J. S. In Effective Field Theories of Magnetism; W. B. Saunders: Philadelphia, PA, 1966.