메뉴 건너뛰기




Volumn 127, Issue 20, 2005, Pages 7324-7325

Radical addition to "cation pool". Reverse process of radical cation fragmentation

Author keywords

[No Author keywords available]

Indexed keywords

CATION; HEPTYL IODIDE; HEXABUTYLDISTANNANE; IODINE DERIVATIVE; N ACYLIMINIUM ION; ORGANOHALOGEN DERIVATIVE; ORGANOTIN COMPOUND; RADICAL; UNCLASSIFIED DRUG;

EID: 19744377011     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0511218     Document Type: Article
Times cited : (62)

References (48)
  • 4
    • 0034545467 scopus 로고    scopus 로고
    • and references therein
    • (b) Moeller, K. D. Tetrahedron 2000, 56, 9527 and references therein.
    • (2000) Tetrahedron , vol.56 , pp. 9527
    • Moeller, K.D.1
  • 20
    • 0025332098 scopus 로고
    • Radical addition to stable iminium ions has been reported in the literature: (a) Clerici, A.; Porta, O. Tetrahedron Lett. 1990, 31, 2069.
    • (1990) Tetrahedron Lett. , vol.31 , pp. 2069
    • Clerici, A.1    Porta, O.2
  • 22
    • 0001156668 scopus 로고
    • Radical addition to protonated heteroatomatics such as pyridine and quinoline has also been reported. For example: (c) Minisci, F.; Fontana, F.; Pianese, G.; Yan, Y. M. J. Org. Chem. 1993, 58, 4207.
    • (1993) J. Org. Chem. , vol.58 , pp. 4207
    • Minisci, F.1    Fontana, F.2    Pianese, G.3    Yan, Y.M.4
  • 40
    • 19744369748 scopus 로고    scopus 로고
    • note
    • The yield decreased with the decrease of the concentration of 2 presumably due to the decrease of radical trapping efficiency: 74% (0.05 M), 46% (0.025 M), 27% (0.01 M).
  • 43
    • 0025003489 scopus 로고
    • It has been reported that 10-methylacridinium ion reacts with distannane via electron-transfer-mediated radical chain mechanism to yield the dimeric product, (a) Fukuzumi, S.; Kitano, T.; Mochida, K. J. Am. Chem. Soc. 1990, 112, 3246.
    • (1990) J. Am. Chem. Soc. , vol.112 , pp. 3246
    • Fukuzumi, S.1    Kitano, T.2    Mochida, K.3
  • 45
    • 19744364649 scopus 로고    scopus 로고
    • note
    • Preliminary DFT calculations indicate that the ionization energy of the carbamate is 8.44 eV, whereas that of the radical is 6.06 eV.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.