Dichotomic reactivity of a stable silylene toward terminal alkynes: Facile C-H bond insertion versus autocatalytic formation of silacycloprop-3-ene

Angewandte Chemie - International Edition

Volumn 47, Issue 17, 2008, Pages 3250-3253

  Yao, Shenglai ^a   Van Wüllen, Christoph ^b   Sun, Xiao Ying ^b   Driess, Matthias ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b Rheinland Pfälzische Technische Universität Kaiserslautern Landau   (Germany)

Author keywords

Cycloaddition; Heterocycles; Silicon; Silylation; Small ring systems

Indexed keywords

CHEMICAL REACTIONS; CHEMICAL REACTIVITY; HYDROCARBONS; LIGHTING; PORT TERMINALS; SILANES;

CYCLOADDITION; HETEROCYCLES; SILICON; SILYLATION; SMALL RING SYSTEMS;

ACETYLENE;

EID: 51049085635     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200704939     Document Type: Article

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