A kinetic evaluation of the thermal oxidation of a phenol stabilised polybutadiene

Polymer Degradation and Stability

Volumn 93, Issue 9, 2008, Pages 1689-1694

  Coquillat, M ^b   Verdu, J ^a   Colin, X ^a   Audouin, L ^a   Celina, M ^c  

^a CNRS   (France)

^b SNPE   (France)

^c SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

Kinetics; Phenolic antioxidant; Polybutadiene; Thermal oxidation

Indexed keywords

BUTADIENE; CHEMICAL OXYGEN DEMAND; CHROMATOGRAPHIC ANALYSIS; CONCENTRATION (PROCESS); NONMETALS; OXIDATION; OXYGEN; PHENOLS; RATE CONSTANTS;

BUTYL PHENOL; IMPROVED MODELS; INDUCTION TIME; INITIAL RATE; KINETIC EVALUATIONS; KINETIC MODELLING; KINETICS; MODEL REFINEMENT; OXYGEN REACTION; PEROXY RADICALS; PHENOLIC ANTIOXIDANT; POLYBUTADIENE; STABILISER; STATIONARY STATES; TELECHELIC; THERMAL OXIDATION; WEIGHT CHANGES;

LIQUID CHROMATOGRAPHY;

EID: 50849120010     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2008.05.031     Document Type: Article

References (37)

1. Layton L., Christiansen A., and Carpenter R. HTPB propellant aging. J Spacecr Rockets 18 (1981) 211
2. Bunyuan P., Cunliffe A.V., and Davis A. The degradation and stabilisation of solid rocket propellants. Polym Degrad Stab 40 (1993) 239-250
3. Hamshere B., and Rawson P. Ageing studies on a composite propellant containing a new organo-copper burn rate catalyst (1993), DSTO Materials Research Laboratory
4. Celina M., Graham A., Gillen K., Assink R., and Minier L. Thermal degradation studies of a polyurethane propellant binder. Rub Chem Tech 73 (2000) 678-693
5. Torry S, Cunliffe A, Tod D, Maxe I, Mullenger D. Ageing effects on insensitive munitions based on HTPB composites. MSIAC Insensitive Munitions Workshop, May 22-27; 2005.
6. Celina M., Skutnik Elliott J., Winters S., Assink R., and Minier L. Correlation of antioxidant depletion and mechanical performance during thermal degradation of an HTPB elastomer. Polym Degrad Stab 91 8 (2006) 1870-1879
7. Shelton J.R. Oxidation and stabilization of rubbers. Rub Chem Tech 56 (1983) 71-78
8. Ahlblad G., Reitberger T., Terselius B., and Stenberg B. Thermal oxidation of hydroxyl-terminated polybutadiene rubber I. Chemiluminescence studies. Polym Degrad Stab 65 2 (1999) 179-184
9. Coquillat M., Verdu J., Colin X., Audouin L., and Nevière R. Thermal oxidation of polybutadiene. Part 1: effect of temperature, oxygen pressure and sample thickness on the thermal oxidation of hydroxyl-terminated polybutadiene. Polym Degrad Stab 92 (2007) 1326-1333
10. McNeill J.C., and Stevenson W.T.K. Polym Degrad Stab 11 (1985) 123-143
11. Sinturel C., and Billingham N.C. A theoritical model for diffusion-limited oxidation applied to oxidation profiles monitored by chemiluminescence in hydroxy terminated polybutadiene. Polym Int 49 (2000) 937-942
12. Coquillat M., Verdu J., Colin X., Audouin L., and Nevière R. Thermal oxidation of polybutadiene. Part 2: mechanistic and kinetic schemes for additive-free non-crosslinked polybutadiene. Polym Degrad Stab 92 (2007) 1334-1342
13. Coquillat M., Verdu J., Colin X., Audouin L., and Nevière R. Thermal oxidation of polybutadiene. Part 3: molar mass changes of additive-free non-crosslinked polybutadiene. Polym Degrad Stab 92 (2007) 1343-1349
14. Shanina E.L., and Belyakov V. Phenol antioxidant consumption rate in polypropylene. Polym Degrad Stab 27 (1990) 309-317
15. Montens S.J., Shanina E.L., Zaikov G.E., and Mukmeneva N.A. Peculiarities of inhibiting the autooxidation of solid polypropylene with 4,4′-bis(2,6-di-tert-butylphenol). Polym Degrad Stab 51 (1996) 51-56
16. See for instance. Emmanuel N.M., and Buchachenko A.L. Chemical physics of polymer degradation and stabilisation (1987), UNO Science Press, Utrecht, The Netherlands p. 146, [chapter 6]
17. See for instance. Gillen K.T., and Clough K.L. J Polym Sci Part A Polym Chem 23 (1985) 2683
18. Pospisil J., Nespurek S., and Zweifel H. The role of quinone methides in thermostabilization of hydrocarbon polymers II. Properties and activity mechanisms. Polym Degrad Stab 54 (1996) 15-21
19. Haber F., and Weiss J. The catalytic decomposition of hydrogen peroxide by iron salts. Proc R Soc London Ser A 72 861 (1934) 332-351
20. Russell G. The rates of oxidation of aralkyl hydrocarbons. Polar effects in free radical reactions 1,2. J Am Chem Soc 78 5 (1956) 1047-1054
21. Uri N. Physico-chemical aspect of autoxidation. In: Lundberg W.E. (Ed). Autoxidation and antioxidants vol. 2 (1961) 55-90 [chapter 1]
22. Richaud E, Verdu J, Colin X, Audouin L. Int J Chem Kinet, in press.
23. Denisov E.T., and Afanas'ev I.B. Oxidation and antioxidants in organic chemistry and biology (2005), Taylor & Francis, New York p. 137-44, [chapter 6]
24. Bowwell F.G., and Zhang X.M.A.N. Acidities and homolytic bond dissociation enthalpies of 4-substituted-2,6-di-tert-butylphenols. J Phys Org Chem 8 (1995) 535
25. Mulder P., Saastad O.W., and Griller D. O-H bond dissociation energies in para-substituted phenols. J Am Chem Soc 110 12 (1988) 4090-4092
26. Zhu Q., Zhang X.-M., and Fry A.J. Polym Degrad Stab 57 1 (1997) 43-50
27. Denisov E.T. A new semiempirical method of estimation of activity and bond dissociation energies in antioxidants. Polym Degrad Stab 49 (1995) 71-75
28. Bolland J., and Ten Have P. Kinetic studies in the chemistry of rubber and related materials. V. The inhibitory effect of phenolic compounds on the thermal oxidation of ethyl linoleate. Discuss Faraday Soc 2 (1947) 252-260
29. Shlyapnikov Y.A., and Torsueva E.S. Oxidation of atactic polypropylene in the presence of 2,6-di-tert-butyl-4-phenylphenol. Polym Degrad Stab 49 (1995) 361-364
30. Kennerly G.W., and Patterson W.L. Kinetic studies of petroleum antioxidants. Ind Eng Chem 48 10 (1956) 1917-1924
31. Ingold K. J Inst Pet 45 (1959) 244
32. Pederson C.J. Mechanism of antioxidant action in gasoline. Ind Eng Chem 48 (1956) 1881-1884
33. Shelton J. Mechanism of antioxidant action in the stabilization of hydrocarbon systems. J Appl Polym Sci 2 (1959) 345-350
34. Richaud E. Durabilité des géotextiles à base de Polypropylène. PhD thesis, ENSAM, Paris; 2006.
35. Shanina E.L., Roginskii V.A., and Zaikov G. Vyosokolmolek Soed 28 (1986) 1971
36. Van Amerongen G. The permeability of different rubbers to gases and its relation to diffusivity and solubility. Rub Chem Tech 20 (1947) 494
37. Colin X., Audouin L., and Verdu J. Determination of thermal oxidation rate constants by an inverse method. Application to polyethylene. Polym Degrad Stab 86 2 (2004) 309-321