Thermal oxidation of polybutadiene. Part 1: Effect of temperature, oxygen pressure and sample thickness on the thermal oxidation of hydroxyl-terminated polybutadiene

Polymer Degradation and Stability

Volumn 92, Issue 7, 2007, Pages 1326-1333

  Coquillat, M ^a,b   Verdu, J ^a   Colin, X ^a   Audouin, L ^a   Neviere R ^b  

^a CNRS   (France)

^b SNPE   (France)

Author keywords

Kinetics; Oxygen pressure effect; Polybutadiene; Thermal oxidation

Indexed keywords

ABSORPTION; GRAVIMETRIC ANALYSIS; OXYGEN; PRESSURE EFFECTS; SPECTROPHOTOMETRY; THERMAL EFFECTS; THERMOOXIDATION;

INFRARED SPECTROPHOTOMETRY; OXYGEN PRESSURE; OXYGEN PRESSURE EFFECTS;

POLYBUTADIENES;

EID: 34250838554     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2007.03.020     Document Type: Article

References (27)

1. Bunyuan P., Cunliffe A.V., and Davis A. The degradation and stabilisation of solid rocket propellants. Polym Degrad Stab 40 (1993) 239-250
2. Nordling P.M., Lee T.C.P., and Tobolsky A.V. Structure and reactivity in oxidation of elastomers. Rubber Chem Technol 38 (1965) 1198-1213
3. Kuzminskii A.S., Degteva T.G., and Lapteva K.A. The mechanism of oxidation of synthetic rubbers. Rubber Chem Technol 29 3 (1956) 573-582
4. Bevilacqua E.M. In: Lundberg W.O. (Ed). Oxidation and antioxidants in rubber, vol. 2. New York: Interscience Publication 2 18 (1966) 874-882
5. Shelton J.R. Oxidation and stabilization of rubbers. Rubber Chem Technol 56 (1983) 71-78
6. Adam C., Lacoste J., and Lemaire J. Photo-oxidation of elastomeric materials. Part 1-photo-oxidation of polybutadienes. Polym Degrad Stab 24 3 (1989) 185-200
7. Beavan S.W., and Philips D. Mechanistic studies on the photo-oxidation of commercial poly(butadiene). Eur Polym J 10 (1974) 593-603
8. Tobolsky A.V., Metz D.J., and Mesrobian R.B. Low temperature autoxidation of hydrocarbons: the phenomenon of maximum rates. J Am Chem Soc 72 (1959) 1942
9. Bolland J.L., and Gee G. Kinetic studies in the chemistry of rubber and related materials. III. Thermo-chemistry and mechanisms of olefin oxidation. Trans Faraday Soc 42 (1946) 244-252
10. Mayo F.R. Ind Eng Chem 52 (1960) 614
11. Rincon-Rubio L.M., Fayolle B., Audouin L., and Verdu J. A general solution of the closed-loop kinetic scheme for the thermal oxidation of polypropylene. Polym Degrad Stab 74 (2001) 177-188
12. Celina M., Graham A., Gillen K., Assink R., and Minier L. Thermal degradation studies of a polyurethane propellant binder. Rubber Chem Technol 73 (2000) 678-693
13. Colin X., Audouin L., and Verdu J. Determination of thermal oxidation rate constants by an inverse method. Application to polyethylene. Polym Degrad Stab 86 (2004) 309-321
14. Sinturel C., and Billingham N.C.A. Theoretical model for diffusion-limited oxidation applied to oxidation profiles monitored by chemiluminescence in hydroxyterminated polybutadiene. Polym Int 49 (2000) 937-942
15. Audouin L., Langlois V., Verdu J., and De Bruign J.L.M. Review: the role of oxygen diffusion in polymer ageing. Kinetic and mechanical aspect. J Mater Sci 29 (1994) 569-583
16. Van Amerongen G.J. Rubber Chem Technol (1947) 20
17. Audouin L., Achimsky L., and Verdu J. In: Hamid S.H. (Ed). Handbook of polymer degradation. 2nd ed. (2000), Marcel Dekker Inc, New York 727
18. Celina M., and Gillen K.T. Oxygen permeability measurements on elastomers at temperature up to 225 °C. Macromolecules 38 7 (2005) 2754-2763
19. Richaud E., Farcas F., Bartoloméo P., Fayolle B., Audouin L., and Verdu J. Effect of oxygen pressure on the oxidation kinetics of unstabilised polypropylene. Polym Degrad Stab 91 (2005) 398-405
20. Reich L., and Stivala S.S. (1969), Marcel Dekker Inc., New York 455-504 [Chapter 8]
21. Verdu J. On the autoaccelerated character of the branched oxidation of polyolefins. Macromol Symp 115 (1997) 165-180
22. Achimsky L., Audouin L., Verdu J., Rychly J., and Matisova-Rychla L. On a transition at 80 °C in polypropylene oxidation kinetics. Polym Degrad Stab 58 3 (1997) 283-289
23. Colin X., Fayolle B., Audouin L., and Verdu J. About a quasi-universal character of unstabilised polyethylene thermal oxidation kinetics. Polym Degrad Stab 80 1 (2003) 67-74
24. Khelidj N., Colin X., Audouin L., Verdu J., Monchy-Leroy C., and Prunier V. Oxidation of polyethylene under irradiation at low temperature and low dose rate. Part II. Low temperature thermal oxidation. Polym Degrad Stab 91 7 (2006/7) 1598-1605
25. Bauman R.G., and Maron S.H. Oxidation of polybutadiene. I: rate of oxidation. J Polym Sci 22 (1956) 1-12
26. Kuzminskii A.S., Degteva T.G., and Lapteva K.A. Vysokomol Soedin (1949) 117-128
27. Degteva T.G., and Kuzminskii A.S. Zh Prikl Khim 29 1 (1956) 90-97