Chemistry: A catalytic foothold for fluorocarbon reactions

Science

Volumn 321, Issue 5893, 2008, Pages 1168-1169

  Perutz, Robin N ^a  

^a UNIVERSITY OF YORK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

FLUOROCARBON;

CATALYSIS; CHEMICAL REACTION; CHEMISTRY; TEMPERATURE EFFECT;

ACIDITY; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; ELECTRON; FLUORINATION; PRIORITY JOURNAL; SEMICONDUCTOR; SHORT SURVEY; SYNTHESIS;

EID: 50649095901     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1161182     Document Type: Short Survey

References (14)

1. G. Sandford, Philos. Trans. R. Soc. London Ser. A 358, 455 (2000).
2. A. M. Morawski et al., Magn. Res. Med. 52, 1255 (2004).
3. Y. C. Hong, H. S. Uhm, Phys. Plasmas 10, 3410 (2003).
4. M. K. So et al., Env. Sci. Tech. 38, 4056 (2004).
5. C. Douvris, O. V. Ozerov, Science 321, 1188 (2008).
6. J. E. Huheey, E. A. Keiter, R. L. Keiter, Inorganic Chemistry (HarperCollins, New York, ed. 4, 1993), appendix E.
7. G. Sandford, Tetrahedron 59, 437 (2003).
8. T. Braun, R. N. Perutz, in Comprehensive Organometallic Chemistry III, R. H. Crabtree, D. M. P. Mingos, Eds. (Elsevier, Oxford, 2006), chapter 1.26.
9. J. Vela et al., J. Am. Chem. Soc. 127, 7857 (2005).
10. T. Wang, B. J. Alfonso, J. Love, Org. Lett. 9, 5629 (2007).
11. V. J. Scott, R. Çelenligil-Çetin, O. V. Ozerov, J. Am. Chem. Soc. 127, 2852 (2005).
12. C. A. Reed, Chem. Commun. 2005, 1669 (2005).
13. C. A. Reed, Z. Xie, R. Bau, A. Benesi, Science 262, 402 (1993).
14. The catalyst loading, defined as the mole ratio of catalyst per reactive C-F bond in the substrate, is between 0.036% and 0.5%. The turnover number, defined as the number of C-F bonds in the substrate reacted per molecule of catalyst, is between 200 and 2700.