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Complex 3, Ph2P(O)C5H4FeC 5H4P(O)PPh2 (dppfO2, to a acetone solution of [Pd(dppf)(H2O)2](OTf)2 (1; 20.0 mg; 0.02 mmol) was added fumaric acid (3.2 mg; 0.02 mmol, To this reaction mixture was added excess Et3N, and this mixture was stirred for 4 h to give a brown precipitate. The orange filtrate upon slow evaporation gave crystals of 3. Anal. Calcd: C, 69.64; H, 4.81. Found: C, 68.95; H, 4.21. 1H NMR (400 MHz, CDCl3, ppm, 7.64-7.26 (m, 20H, Ph, 4.71-4.25 (m, 10H, cp, 31P{1H} NMR (CDCl3, 121 MHz, ppm, 28.77 (s, Crystal data for compound 3: C34H 28FeO2P2H2O, Mr, 604.37, monoclinic, space group P21/c, a, 22.552(6) Å, 10.590(3) Å, c, 12.220(3) Å, β, 95.9305
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