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Volumn 27, Issue 15, 2008, Pages 3806-3810

Unusual hydrogenation of fumarate anion followed by metal-carbon bond formation: Synthesis and characterization of two metallochelates

Author keywords

[No Author keywords available]

Indexed keywords

CARBON BONDS; FUMARATE; SYNTHESIS AND CHARACTERIZATION;

EID: 50549098208     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800341p     Document Type: Article
Times cited : (19)

References (45)
  • 35
    • 50549089295 scopus 로고    scopus 로고
    • Complex 3, Ph2P(O)C5H4FeC 5H4P(O)PPh2 (dppfO2, to a acetone solution of [Pd(dppf)(H2O)2](OTf)2 (1; 20.0 mg; 0.02 mmol) was added fumaric acid (3.2 mg; 0.02 mmol, To this reaction mixture was added excess Et3N, and this mixture was stirred for 4 h to give a brown precipitate. The orange filtrate upon slow evaporation gave crystals of 3. Anal. Calcd: C, 69.64; H, 4.81. Found: C, 68.95; H, 4.21. 1H NMR (400 MHz, CDCl3, ppm, 7.64-7.26 (m, 20H, Ph, 4.71-4.25 (m, 10H, cp, 31P{1H} NMR (CDCl3, 121 MHz, ppm, 28.77 (s, Crystal data for compound 3: C34H 28FeO2P2H2O, Mr, 604.37, monoclinic, space group P21/c, a, 22.552(6) Å, 10.590(3) Å, c, 12.220(3) Å, β, 95.9305
    • int = 0.0790, R1 = 0.0735 and wR2 = 0.1319.
  • 39
    • 0004140470 scopus 로고    scopus 로고
    • SMART/SAINT;, Inc, Madison, WI
    • SMART/SAINT; Bruker AXS, Inc., Madison, WI, 2004.
    • (2004) Bruker AXS
  • 40
    • 50549099873 scopus 로고    scopus 로고
    • Sheldrick, G. M. SHELX-97, Program for the Solution and Refinement of Crystal Structures; University of Göttingen, Göttingen, Germany, 1998.
    • Sheldrick, G. M. SHELX-97, Program for the Solution and Refinement of Crystal Structures; University of Göttingen, Göttingen, Germany, 1998.
  • 41
    • 50549089673 scopus 로고    scopus 로고
    • Farrugia, L. J. WinGX: An Integrated System of Windows Programs for the Solution, Refinement and Analysis for Single Crystal X-ray Diffraction Data, version 1.65.04; Department of Chemistry, University of Glasgow, Glasgow, U.K, 2003
    • Farrugia, L. J. WinGX: An Integrated System of Windows Programs for the Solution, Refinement and Analysis for Single Crystal X-ray Diffraction Data, version 1.65.04; Department of Chemistry, University of Glasgow, Glasgow, U.K., 2003.
  • 43
    • 50549084482 scopus 로고    scopus 로고
    • Sheldrick, G. M. SADABS, Bruker Nonius Area Detector Scaling and Absorption Correction, version 2.05; University of Göttingen, Göttingen, Germany, 1999
    • Sheldrick, G. M. SADABS, Bruker Nonius Area Detector Scaling and Absorption Correction, version 2.05; University of Göttingen, Göttingen, Germany, 1999.
  • 44
    • 33646767009 scopus 로고    scopus 로고
    • Farrugia, L. J. ORTEP-3 for Windows, version 1.08. J. Appl. Crystallogr. 1997, 30, 565
    • Farrugia, L. J. ORTEP-3 for Windows, version 1.08. J. Appl. Crystallogr. 1997, 30, 565.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.