TiCl4 and Grignard reagent-promoted ring-opening reactions of various epoxides: synthesis of γ-hydroxy-α,α-difluoromethylenephosphonates

Tetrahedron Letters

Volumn 49, Issue 42, 2008, Pages 6046-6049

  Pajkert, Romana ^a   Kolomeitsev, Alexander A ^b   Milewska, Magdalena ^a   Röschenthaler, Gerd Volker ^b   Koroniak, Henryk ^a  

^a ADAM MICKIEWICZ UNIVERSITY   (Poland)

^b UNIVERSITY OF BREMEN   (Germany)

Author keywords

Difluoromethylenephosphonates; Epoxide ring opening reactions; Halohydrins; Lewis acids

Indexed keywords

3,4 EPOXY 1,1 DIFLUOROBUTYLPHOSPHONATE; DIETHYL GAMMA HYDROXY ALPHA,ALPHA DIFLUOROMETHYLENEPHOSPHONATE DERIVATIVE; EPOXIDE; GRIGNARD REAGENT; LITHIUM DIETHYL DIFLUOROMETHYLENEPHOSPHONATE DERIVATIVE; PHOSPHONIC ACID DERIVATIVE; TITANIUM TETRACHLORIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CROSS COUPLING REACTION; FLUORINE NUCLEAR MAGNETIC RESONANCE; RING OPENING;

EID: 50549094332     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2008.07.146     Document Type: Article

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