Phenol oxidation kinetics in water solution using iron(3)-oxide-based nano-catalysts

Water Research

Volumn 42, Issue 14, 2008, Pages 3848-3856

  Zelmanov, Grigory ^a   Semiat, Raphael ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

Fenton like process; Inorganic ions; Iron oxide; Nano catalyst; Organic pollutants; Phenol; Radical scavenger; Water treatment

Indexed keywords

HYDROGEN PEROXIDE; IONS; IRON OXIDES; NANOCATALYSTS; NANOPARTICLES; ORGANIC POLLUTANTS; OXIDATION; PEROXIDES; PHENOLS; SODIUM; WATER POLLUTION; WATER TREATMENT;

CATALYTIC BEHAVIOR; CHEMICAL OXIDATION; FENTON-LIKE PROCESS; HYDROGEN PEROXIDE CONCENTRATION; INORGANIC IONS; NANO-CATALYST; ORGANIC CONTAMINANT; RADICAL SCAVENGERS;

CHEMICALS REMOVAL (WATER TREATMENT);

BICARBONATE; CALCIUM; CHLORINE; IRON OXIDE; MAGNESIUM; NANOPARTICLE; PHENOL; PHOSPHATE; SCAVENGER; SODIUM; SULFATE;

CATALYSIS; IRON OXIDE; KINETICS; ORGANIC COMPOUND; ORGANIC POLLUTANT; OXIDATION; PHENOL; SCAVENGING (CHEMISTRY); SOLUTION; WATER TREATMENT;

ARTICLE; CHEMICAL REACTION KINETICS; NANOCATALYSIS; NANOCATALYST; OXIDATION; PRIORITY JOURNAL; WATER POLLUTANT; WATER POLLUTION; WATER TREATMENT;

EID: 50449084775     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.watres.2008.05.009     Document Type: Article

References (31)

1. Andreozzi R., Caprio V., Insola A., and Marotta R. Advanced oxidation process for water purification and recovery. Catalysis Today 53 (1999) 51-59
2. Bach A., Zelmanov G., and Semiat R. Cold catalytic recovery of loaded activated carbon using iron oxide nano-particles. Water Research 42 (2008) 163-168
3. Bali U., Catalkaya E.C., and Sengul F. Photochemical degradation and mineralization of phenol: a comparative study. Journal of Environmental Science and Health 38A 10 (2003) 2259-2275
4. Beltran F.J., Gonzalez M., Rivas F.J., and Alvarez P. Fenton reagent advanced oxidation of poly-nuclear aromatic hydrocarbons in water. Water, Air and Soil Pollution 105 (1998) 685-700
5. Bertanza G., Collivignarelli C., and Pedrazzani R. The role of chemical oxidation in combined chemical-physical and biological processes: experiences of industrial wastewater treatment. Water Science and Technology 44 5 (2001) 109-116
6. Buxton G.V., Greenstock C.L., Helman W.P., and Ross A.B. Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution. Journal of Physical and Chemical Reference Data 17 (1988) 513-886
7. Catalkaya E.C., Bali U., and Sengul F. Photochemical degradation and mineralization of 4-chlorophenol. Environmental Science and Pollution Research International 10 2 (2003) 113-120
8. Chan K.H., and Chu W. Modeling the reaction kinetics of Fenton's process on the removal of atrazine. Chemosphere 51 (2003) 305-311
9. Cheng S., Tsai S.J., and Lee Y.F. Photo catalytic decomposition of phenol over titanium dioxide of various structures. Catalysis Today 26 (1995) 87-96
10. De Heredia J.B., Torregrosa J., Dominguez J.R., and Peres J.A. Kinetic model for phenolic compound oxidation by Fenton's reagent. Chemosphere 45 (2001) 85-90
11. 2. Chemosphere 55 (2004) 715-723
12. Fenton H.J.H. Oxidation of tartaric acid in the presence of iron. Journal of the Chemical Society 65 (1894) 899-910
13. Hernandez R., Zappi M., Colucci J., and Jones R. Comparing the performance of various advanced oxidation processes for treatment of acetone contaminated water. Journal of Hazardous Materials 92 (2002) 33-50
14. Iwasaki M., Hara M., and Ito S. Synthesis of nanometer-sized hematite single crystals through NAC-FAS method. Journal of Material Science 35 (2000) 943-949
15. Kamat P.V., and Meisel D. Nano-particles in advanced oxidation processes. Current Opinion in Colloid and Interface Science 7 (2002) 282-287
16. Lin S.-S., and Gurol M.D. Catalytic decomposition of hydrogen peroxide on iron-oxide: kinetics, mechanism and implications. Environmental Science & Technology 32 (1998) 1417-1423
17. Lu M.C., Chen J.N., and Chang C.P. Effect of inorganic ions on the oxidation of dichlorvos insecticide with Fenton's reagent. Chemosphere 35 10 (1997) 2285-2293
18. Maciel R., Sant'Anna G.L., and Dezotti Jr. M. Phenol removal from high salinity effluents using Fenton's reagent and photo-Fenton reactions. Chemosphere 57 (2004) 711-719
19. Neyens E., and Baeyens J. A review of classic Fenton's peroxidation as an advanced oxidation technique. Journal of Hazardous Materials B98 (2003) 33-50
20. Oliveros E., Legrini O., Holb M., Muller T., and Braun A. Industrial wastewater treatment: large scale development of a light-enhanced Fenton reaction. Chemical Engineering and Processing 36 (1997) 397-405
21. Perez M., Torrades F., Garcia-Hortal J.A., Domenech X., and Peral J. Removal of organic contaminants in paper pulp treatment effluents under Fenton and photo-Fenton conditions. Applied Catalysis 36 (2002) 63-74
22. Safarzadeh-Amiri A., Bolton J.R., and Cater S.R. Ferrioxalate-mediated photo degradation of organic pollutants in contaminated water. Water Research 31 (1997) 787-798
23. Safarzadeh-Amiri A., Bolton J.R., and Cater S.R. The use of iron in advanced oxidation processes. Journal of Advanced Oxidation Technologies 1 1 (1996) 18-26
24. Sigman M.E., Buchanan A.C., and Smith S.M. Application of advanced oxidation process technologies to extremely high TOC aqueous solutions. Journal of Advanced Oxidation Technologies 2 (1997) 415-423
25. Stein G., and Weiss J. Some free radical reaction of phenol. Journal of the Chemical Society (1951) 3265-3274 [Abstracts]
26. Stramel R.D., and Thomas Y.K. Photochemistry of iron-oxide colloids. Journal of Colloid and Interface Science 110 (1986) 121-129
27. Toledo L.S., Bernardes Silva A.C., Augusti R., and Lago R.M. Application of Fenton's reagent to regenerate activated carbon saturated with organochloro compounds. Chemosphere 50 (2003) 1049-1054
28. 2 and ZnO. Chemosphere 41 (2000) 1193-1197
29. Walling C. Fenton's reagent revised. Accounts of Chemical Research 8 (1975) 125-131
30. Zelmanov G., and Semiat R. Iron(3) oxide-based nano-particles as catalysts in advanced organic aqueous oxidation. Water Research 42 (2008) 492-498
31. Zelmanov, G., Semiat, R. Phosphate removal from water and its recovery by using iron(3) oxide-based nano-adsorbent, submitted for publication.