Corrosion mechanism of model zinc-magnesium alloys in atmospheric conditions

Corrosion Science

Volumn 50, Issue 8, 2008, Pages 2216-2231

  Prosek, T ^a   Nazarov, A ^a   Bexell, U ^b   Thierry, D ^a   Serak, J ^c  

^a FRENCH CORROSION INSTITUTE   (France)

^b DALARNA UNIVERSITY   (Sweden)

^c INSTITUTE OF CHEMICAL TECHNOLOGY   (Czech Republic)

Author keywords

A. Zinc; B. IR spectroscopy; C. Atmospheric corrosion; Magnesium; Scanning Kelvin probe

Indexed keywords

ALLOYS; AUGER ELECTRON SPECTROSCOPY; CHROMATOGRAPHIC ANALYSIS; CORROSION; ELECTROLYTIC REDUCTION; ELECTROPLATING; FOURIER TRANSFORM INFRARED SPECTROSCOPY; INFRARED SPECTROSCOPY; ION CHROMATOGRAPHY; LIGHT METALS; MAGNESIUM; MAGNESIUM ALLOYS; MECHANISMS; METALLIC COMPOUNDS; METALS; NONMETALS; OXYGEN; PHOTOMASKS; PROTECTIVE COATINGS; SODIUM CHLORIDE; SPECTROSCOPIC ANALYSIS; ZINC; ZINC ALLOYS; ZINC PLATING;

A. ZINC; ATMOSPHERIC CONDITIONS; AUGER ELECTRON SPECTROSCOPY (AES); B. IR SPECTROSCOPY; C. ATMOSPHERIC CORROSION; CHLORIDE ENVIRONMENT; CORROSION BEHAVIOUR; CORROSION MECHANISMS; CORROSION PRODUCTS; CORROSION STABILITY; ELECTROCHEMICAL MEASUREMENTS; EXPOSURE TESTING; HUMID AIR; ION CHROMATOGRAPHY (IC); METAL SURFACES; OXYGEN REDUCTIONS; PURE MAGNESIUM; SCANNING KELVIN PROBE; STABLE PASSIVITY; SUPERIOR CORROSION; WEIGHT LOSSES; ZINC COATINGS;

MAGNESIUM PRINTING PLATES;

CORROSION; ELECTROCHEMISTRY; INFRARED SPECTROSCOPY; MAGNESIUM COMPOUNDS; NONMETALS; OXYGEN; PROTECTIVE COATINGS; SODIUM CHLORIDE; ZINC;

EID: 50349098825     PISSN: 0010938X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.corsci.2008.06.008     Document Type: Article

References (33)

1. M. Vlot, R. Bleeker, T. Maalman, E. van Perlstein, MagiZincTM: a new generation of hot-dip galvanised products, in: Proceedings of the Galvanized Steel Sheet Forum, ILZRO and IZA, Dusseldorf, Germany, 2006.
2. T. Koll, K. Ullrich, J. Faderl, J. Hagler, A. Spalek, Properties and potential applications of ZnMg-alloy-coatings on steel sheet by PVD, in: Proceedings of the Galvatech '04, International Conference on Zinc and Zinc Alloy Coated Steel Sheet, 6th, Association for Iron and Steel Technology, April 4-7, Chicago, IL, United States, 2004, pp. 803-812.
3. C. Schwerdt, M. Riemer, S. Koehler, B. Schuhmacher, M. Steinhorst, A. Zwick, A study of the application related properties of novel Zn-Mg coated steel sheet produced in a continuous pilot line, in: Proceedings of the Galvatech '04, International Conference on Zinc and Zinc Alloy Coated Steel Sheet, 6th, Association for Iron & Steel Technology, April 4-7, Chicago, IL, United States, 2004, pp. 783-793.
4. Schuhmacher B., Schwerdt C., Seyfert U., and Zimmer O. Innovative steel strip coatings by means of PVD in a continuous pilot line: process technology and coating development. Surf. Coat. Technol. 163-164 (2003) 703-709
5. Townsend H.E. On the effects of magnesium on the atmospheric corrosion resistance of galvanized sheet steel. Corrosion 44 (1988) 229-230
6. Dagbert C., Boulif R., Galland J., and Cabrillac C. Effect of galvanizing bath additives on atmospheric corrosion resistance of galvanized steels. Mater. Tech. 78 (1990) 11-16
7. Zhang X.G. Corrosion and Electrochemistry of Zinc (1996), Plenum Press, New York p. 260
8. Zhang X.G. Corrosion and Electrochemistry of Zinc (1996), Plenum Press, New York p. 180
9. Hosking N.C., Strom M.A., Shipway P.H., and Rudd C.D. Corrosion resistance of zinc-magnesium coated steel. Corros. Sci. 49 (2007) 3669-3695
10. N.C. Hosking, M.A. Strom, P.H. Shipway, C.D. Rudd, Next generation galvanized steel for the automotive industry, in: Proceedings of the Eurocorr, Freiburg im Breisgau, Germany, September 9-13, 2007.
11. Hausbrand R., Rohwerder M., Stratmann M., Schwerdt C., Schuhmacher B., and Grundmeier G. Model study on the corrosion of magnesium-containing zinc coatings on steel sheet. Proceedings of the Galvatech '01, International Conference on Zinc and Zinc Alloy Coated Steel Sheet, Brussels, Belgium, June 26-28 (2001), Verlag Stahleisen GmbH, Düsseldorf, Germany 161-167
12. Hausbrand R., Stratmann M., and Rohwerder M. Delamination resistant zinc alloys: simple concept and results on the system zinc-magnesium. Steel Res. Int. 74 (2003) 453-458
13. Okamoto H. Comment on Mg-Zn (Magnesium-Zinc). J. Phase Equilib. 15 (1994) 129-130
14. Barton K., Cuc T.D., and Bartonova S. Eifluss der Kationenzusammensetzung von Chloridlösungen beim Modellieren von Korrosionseinflüssen der Küstenatmosphären. Mater. Corros. 28 (1977) 17-19
15. Cole I.S., Ganther W.D., Paterson D.A., King G.A., Furman S.A., and Lau D. A holistic model for atmospheric corrosion: part 2 - experimental measurement of deposition of marine salts in a number of long range studies. Corros. Eng. Sci. Technol. 38 (2003) 259-266
16. Memming R. Semiconductor Electrochemistry (1998), Wiley VCH, Weinheim-New York-Chichester p. 23
17. Stratmann M., and Streckel H. On the atmospheric corrosion of metals which are covered with thin electrolyte layers. I. Verification of the experimental technique. Corros. Sci. 30 (1990) 681-696
18. Nazarov A., and Thierry D. Rate-determining reactions of atmospheric corrosion. Electrochim. Acta 49 (2004) 2717-2724
19. 2 and NaCl on the atmospheric corrosion of zinc; a laboratory study. J. Electrochem. Soc. 145 (1998) 2993-2999
20. Jönsson M., Persson D., and Thierry D. Corrosion product formation during NaCl induced atmospheric corrosion of magnesium alloy AZ91D. Corros. Sci. 49 (2007) 1540-1558
21. A.P. Nazarov, D. Thierry, Atmospheric corrosion of metals contaminated by NaCl deposition, in: Proceedings of Eurocorr '98, The Netherlands, 1998.
22. Nazarov A., and Thierry D. Probing the atmospheric corrosion of metals; zinc. Prot. Met. 42 (2006) 437-451
23. Neufeld A.K., Cole I.S., Bond A.M., and Furman S.A. The initiation mechanism of corrosion of zinc by sodium chloride particle deposition. Corros. Sci. 44 (2002) 555-572
24. Henrich V.E., and Cox P.A. The Surface Science of Metal Oxides (2000), Cambridge University Press p. 9
25. M. Stratmann, R. Hausbrand, M. Rohwerder, C. Wapner, G. Grundmeier, Surface modification of iron based alloys for improved corrosion resistance and adhesion, in: 13th Asian-Pacific Corrosion Control Conference, Tsukuba, Japan, Paper PL-5, November 25, 2003.
26. Prosek T., Thierry D., Taxén C., and Maixner J. Effect of cations on corrosion of zinc and carbon steel covered with chloride deposits under atmospheric conditions. Corros. Sci. 49 (2007) 2676-2693
27. Ishikawa T., Matsumoto K., Yasukawa A., Kandori K., Nakayama T., and Tsubota T. Influence of metal ions on the formation of artificial zinc rusts. Corros. Sci. 46 (2003) 329-342
28. Lindström R., Svensson J.-E., and Johansson L.G. The influence of salt deposits on the atmospheric corrosion of zinc; the important role of the sodium ion. J. Electrochem. Soc. 149 (2002) B57-B64
29. M. Pourbaux, Atlas d'Équilibres Électrochimiques, Paris, 1963.
30. Zhang X.G. Corrosion and Electrochemistry of Zinc (1996), Plenum Press, New York-London pp. 93-124
31. Huang J.-H., and Liu C.-P. The influence of magnesium and hydrogen introduction in sputtered zinc oxide thin films. Thin Solid Films 498 (2006) 152-157
32. Vetter K.J. Electrochemische Kinetik (1961), Springer-Verlag, Berlin
33. Pickiring H.W., and Vagner C. Electrolytic dissolution of binary alloys containing a noble metal. J. Electrochem. Soc. 114 (1967) 698-706