Synthesis, characterization, and computational studies of 6-(RR′N)-nido-5,7-C2B8H11: A polyborane cluster with a cage-boron having an exopolyhedral dative boron-nitrogen double bond

Journal of the American Chemical Society

Volumn 130, Issue 34, 2008, Pages 11494-11502

  Li, Yuqi ^a   Sneddon, Larry G ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL STUDIES;

BORANE DERIVATIVE; BORON; CARBORANE DERIVATIVE; HYDROGEN; IONIC LIQUID; NITROGEN;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 50249103387     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja803297b     Document Type: Article

References (45)

1. (a) Kusari, U.; Li, Y.; Bradley, M. G.; Sneddon, L. G. J. Am. Chem. Soc. 2004, 126, 8662-8663.
2. (b) Li, Y.; Kusari, U.; Carroll, P. J.; Bradley, M. G.; Sneddon, L. G. Pure Appl. Chem. 2006, 78, 1349-1355.
3. (c) Bluhm, M. E.; Bradley, M. G.; Butterick, R. III; Kusari, U.; Sneddon, L. G. J. Am. Chem. Soc. 2006, 128, 7748-7749.
4. Miller, H. C.; Muetterties, E. L. Inorg. Synth. 1967, 10, 88-91.
5. Hertler, W. R.; Klanberg, F.; Mutterties, E. L. Inorg. Chem. 1967, 6, 1696-1706.
6. (a) Beck, J. S.; Kahn, A. P.; Sneddon, L. G. Organometallics 1986, 5, 2552-2553.
7. (b) Beck, J. S.; Sneddon, L. G. Inorg. Chem. 1990, 29, 295-302.
8. Shriver, D. F.; Drezdzon, M. A. The Manipulation of Air-Sensitive Compounds; 2nd ed., Wiley: New York, 1986.
9. Garrett, P. M.; George, T. A.; Hawthorne, M. F. Inorg. Chem. 1969, 8, 2008-2009.
10. (a) Garrett, P. M.; Smart, J. C.; Ditta, G. S.; Hawthorne, M. F. Inorg. Chem. 1969, 8, 1907-1910.
11. (b) Tebbe, F. N.; Garrett, P. M.; Hawthorne, M. F. J. Am. Chem. Soc. 1968, 90, 869-879.
12. (c) Teixidor, F.; Vinas, C.; Rudolph, R. W. Inorg. Chem. 1986, 25, 3339-3345.
13. Garrett, P. M.; Ditta, G. S.; Hawthorne, M. F. J. Am. Chem. Soc. 1971, 93, 1265-1266.
14. Frisch, M. J.; et al. Gaussian 03, revision B.05; Gaussian, Inc.: Pittsburgh, PA, 2003.
15. Merrick, J. P.; Moran, D.; Radom, L. J. Phys. Chem. A 2007, 111, 11683-11700.
16. Only the endo-CH and boron-bridging hydrogens are shown in these drawings. Each cage carbon and boron also has one additional terminal hydrogen.
17. Paetzold, P. Adv. Inorg. Chem. 1987, 31, 123-170.
18. Sugie, M.; Takeo, H.; Matsumura, C. J. Mol. Spedrosc. 1987, 123, 286-292.
19. Boese, R.; Niederprum, N.; Blaser, D. Struct. Chem. 1992, 3, 399-406.
20. Almenningen, A.; Gundersen, G.; Mangerud, M.; Seip, R. Acta. Chem. Scand. A 1981, 35, 341-357.
21. Pawelke, G.; Burger, H. Appl. Organomet. Chem. 1996, 10, 147-174.
22. (a) Atoji, M.; Lipscomb, W. N. J. Chem. Phys. 1957, 27, 195.
23. (b) Wagner, T.; Eigendorf, U.; Herberich, G. E.; Englert, U. Struct. Chem. 1994, 5, 233-237.
24. (a) Gilbert, T. M. J. Phys. Chem. 2004, 108, 2550-2554.
25. (b) Ostby, K-A.; Gundersen, G.; Haaland, A.; Noth, H. Dalton Trans. 2005, 2284-2291.
26. Avent, A. G.; Hitchcock, P. B.; Lappert, M. F.; Liu, D-S.; Mignani, G.; Richard, C.; Roche, E. J. Chem. Soc., Chem. Commun. 1995, 855-856.
27. Crespi, A. M.; Shriver, D. F. Organometallics 1985, 4, 1830-1835.
28. (a) Roth, A.; Meyer, F.; Paetzold, P. Collect. Czech. Chem. Commun. 1997, 62, 1299-1309.
29. (b) Paetzold, P. Eur. J. Inorg. Chem. 1998, 2, 143-154.
30. Williams, R. E. Chem. Rev. 1992, 92, 177-207.
31. Kendall, D. S.; Lipscomb, W. N. Inorg. Chem. 1973, 12, 546-551.
32. (a) Stibr, B.; Plesek, J.; Hermanek, S. Collect. Czech. Chem. Commun. 1974, 39, 1805-1809.
33. (b) Stibr, B.; Plesek, J.; Hermanek, S. Chem. Ind. (London) 1972, 963-964.
34. (c) Wermer, J. R.; Hosmane, N. S.; Alexander, J. J.; Siriwardane, U.; Shore, S. G. Inorg. Chem. 1986, 25, 4351-4354.
35. Su, K.; Carroll, P. J.; Sneddon, L. G. J. Am. Chem. Soc. 1993, 115, 10004-10017.
36. Hong, D.; Rathmill, S. E.; Carroll, P. J.; Sneddon, L. G. J. Am. Chem. Soc. 2003, 125, 16058-16073.
37. Ostby, K.-A.; Haaland, A.; Gundersen, G.; Noth, H. Organometallics 2005, 24, 5318-5328.
38. (a) Tebbe, F. N.; Garrett, P. M.; Hawthorne, M. F. J. Am. Chem. Soc. 1966, 88, 609-608.
39. (b) Tebbe, F. N.; Garrett, P. M.; Hawthorne, M. F. J. Am. Chem. Soc. 1968, 90, 869-879.
40. (a) For general reviews of reactions in ionic liquids, see: Ionic Liquids in Synthesis; Wassersheid, P., Welton, T., Eds.; Wiley-VCH: Weinheim, Germany, 2003.
41. (b) Dyson, P. J. Appl. Organomet. Chem. 2002, 16, 495-500.
42. (c) Zhao, H.; Malhotra, S. V. Aldrich Chimica Acta 2002, 35, 75-83.
43. (d) Sheldon, R. Chem. Commun. 2001, 2399-2407.
44. (e) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2002, 39, 3772-3789.
45. (f) Dupont, J.; de Souza, R. F.; Suarez, P. A. Z. Chem. Rev. 2002, 102, 3667-3692.