Hydrogenation of white phosphorus to phosphane with rhodium and iridium trihydrides

Angewandte Chemie - International Edition

Volumn 37, Issue 16, 1998, Pages 2255-2257

  Peruzzini, Maurizio ^a   Ramirez, José Antonio ^b   Vizza, Francesco ^a  

^a CNR   (Italy)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

Iridium; P ligands; Phosphanes; Phosphorus; Rhodium

Indexed keywords

EID: 0031690027     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19980904)37:16<2255::aid-anie2255>3.0.co;2-h     Document Type: Article

References (45)

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2. Reviews: a) M. Di Vaira, M. Peruzzini, P. Stoppioni, Polyhedron 1987, 6, 351-382; b) O. J. Scherer, Comments Inorg. Chem. 1987, 6, 1-22; c) O. J. Scherer, Angew. Chem. 1990, 102, 1137-1155; Angew. Chem. Int. Ed. Engl. 1990, 29, 1104-1122; d) M. Scheer, E. Herrmann, Z. Chem. 1990, 29, 41-55; e) O. J. Scherer in Multiple Bonds and Low Coordination in Phosphorus Chemistry (Eds.: M. Regitz, O. J. Scherer), Thieme, Stuttgart, Germany, 1990; chap 3.
3. Reviews: a) M. Di Vaira, M. Peruzzini, P. Stoppioni, Polyhedron 1987, 6, 351-382; b) O. J. Scherer, Comments Inorg. Chem. 1987, 6, 1-22; c) O. J. Scherer, Angew. Chem. 1990, 102, 1137-1155; Angew. Chem. Int. Ed. Engl. 1990, 29, 1104-1122; d) M. Scheer, E. Herrmann, Z. Chem. 1990, 29, 41-55; e) O. J. Scherer in Multiple Bonds and Low Coordination in Phosphorus Chemistry (Eds.: M. Regitz, O. J. Scherer), Thieme, Stuttgart, Germany, 1990; chap 3.
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6. Reviews: a) M. Di Vaira, M. Peruzzini, P. Stoppioni, Polyhedron 1987, 6, 351-382; b) O. J. Scherer, Comments Inorg. Chem. 1987, 6, 1-22; c) O. J. Scherer, Angew. Chem. 1990, 102, 1137-1155; Angew. Chem. Int. Ed. Engl. 1990, 29, 1104-1122; d) M. Scheer, E. Herrmann, Z. Chem. 1990, 29, 41-55; e) O. J. Scherer in Multiple Bonds and Low Coordination in Phosphorus Chemistry (Eds.: M. Regitz, O. J. Scherer), Thieme, Stuttgart, Germany, 1990; chap 3.
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11. a) O. J. Scherer, J. Braun, P. Walter, G. Heckmann, G. Wolmershäuser, Angew. Chem. 1991, 103, 861-863; Angew. Chem. Int. Ed. Engl. 1991, 30, 850-852; b) C. E. Laplaza, W. M. Davis, C. C. Cummins, Angew. Chem. 1995, 107, 2181-2183; Angew. Chem. Int. Ed. Engl. 1995, 34, 2042-2044; c) M. J. A. Johnson, A. L. Odom, C. C. Cummins, Commun. 1997, 1523-1524;
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18. 2 dimolybdenum complex has been recently reported: J. E. Davies, M. S. Mays, P. R. Raithby, G. P. Shields, P. K. Tompkin, Chem. Commun. 1997, 361-362.
19. 2 dimolybdenum complex has been recently reported: J. E. Davies, M. S. Mays, P. R. Raithby, G. P. Shields, P. K. Tompkin, Chem. Commun. 1997, 361-362.
20. 2 dimolybdenum complex has been recently reported: J. E. Davies, M. S. Mays, P. R. Raithby, G. P. Shields, P. K. Tompkin, Chem. Commun. 1997, 361-362.
21. 2 dimolybdenum complex has been recently reported: J. E. Davies, M. S. Mays, P. R. Raithby, G. P. Shields, P. K. Tompkin, Chem. Commun. 1997, 361-362.
22. 2 dimolybdenum complex has been recently reported: J. E. Davies, M. S. Mays, P. R. Raithby, G. P. Shields, P. K. Tompkin, Chem. Commun. 1997, 361-362.
23. 2 dimolybdenum complex has been recently reported: J. E. Davies, M. S. Mays, P. R. Raithby, G. P. Shields, P. K. Tompkin, Chem. Commun. 1997, 361-362.
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32. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
33. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
34. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
35. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
36. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
37. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
38. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
39. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
40. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
41. Complexes containing the bicyclotetraphosphane ligand: Zr, Hf: a) O. J. Scherer, M. Swarowsky, H. Swarowsky, G. Wolmershäuser, Angew. Chem. 1988, 100, 738-739; Angew. Chem. Int. Ed. Engl. 1988, 27, 694-695; Co: b) O. J. Scherer, M. Swarowsky, G. Wolmershäuser, Organometallics 1989, 8, 841-842; c) M. Scheer, U. Becker, J. C. Huffman, M. C. Chisholm, J. Organomet. Chem. 1993, 461, C1-C3; Rh: d) A. P. Ginsberg, W.E. Lindsell, K.J. McCullough, C. R. Sprinkle, A. J. Welch, J. Am. Chem. Soc. 1986, 108, 403-416; e) M. Scheer, C. Troitzsch, P. G. Jones, Angew. Chem. 1992, 104, 1137-1139; Angew. Chem. Int. Ed. Engl. 1992, 31, 1377-1379; f) M. Scheer, C. Troitzsch, L. Hilfert, M. Dargatz, E. Kleinpeter, P. G. Jones, J. Sieler, Chem. Ber. 1995, 128, 251-257; Ir: g) M. Scheer, U. Becker, E. Matern. Chem. Ber. 1996, 129, 721-724; Pt: h) M. Scheer, M. Dargatz, A. Rufinska, J. Organomet. Chem. 1992, 440, 327-333.
42. G = 28.87
43. 3.
44. 3): O. J. Scherer, G. Schwarz, G. Wolmershäuser, Z. Anorg. Allg. Chem. 1996, 622, 951.
45. 4; which is relevant to this hypothesis, has been recently described: C. Bianchini, S. Moneti, M. Peruzzini, F. Vizza, Inorg. Chem. 1997, 36, 5818-5825.