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Volumn 108, Issue 38, 2004, Pages 14340-14347

Methanol oxidation on a copper catalyst investigated using in situ X-ray photoelectron spectroscopy

Author keywords

[No Author keywords available]

Indexed keywords

ANISOTROPY; CATALYSTS; COMPOSITION; GRAIN BOUNDARIES; METHANOL; OXIDATION; OXYGEN; PHOTONS; POLYCRYSTALLINE MATERIALS; SURFACE PHENOMENA; VACUUM; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 4944266771     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp040080j     Document Type: Article
Times cited : (217)

References (58)
  • 1
    • 84994725497 scopus 로고    scopus 로고
    • Somorjai, G. A. Introduction to Surface Chemistry and Catalysis; Wiley & Sons: New York, 1994.
  • 23
    • 84994691122 scopus 로고    scopus 로고
    • We have used a modified Phoibos 150 hemispherical analyzer made by SPECS GmbH, Berlin, Germany.
  • 24
    • 84994757791 scopus 로고    scopus 로고
    • 2molecule. For a detailed discussion of this effect see ref 25.
  • 28
    • 84994707292 scopus 로고    scopus 로고
    • NIST X-ray Photoelectron Spectroscopy Database, Version 3.4 (Web Version), http://srdata.nist.gov/xps/.
  • 34
    • 84994699990 scopus 로고    scopus 로고
    • 2= 3:1 at a total pressure of 0.6 mbar the transmission of the gas phase varies between 0.980 (at hv = 580 eV) and 0.998 (at hv = 1300 eV). (The values were calculated using the web interface of the Center for X-ray Optics at Lawrence Berkeley National Laboratory, Berkeley, CA: http://www-cxro.lbl.gov/opticaLconstants/ gastrn2.html.) The error in the calculation of the depth-dependent Cu:O stoichiometry that is caused by attenuation effects in the gas phase is therefore smaller than 2%, well within the error bars in Figure 4.
  • 41
    • 84994752422 scopus 로고    scopus 로고
    • Bluhm, H.; Hävecker, M.; Knop-Gericke, A.; Kleimenov, E.; Teschner, D.; Schlögl, R.; Bukhtiyarov, V. I. Manuscript in preparation.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.