Natural origin of ascorbic acid: Validation by 13C NMR and IRMS

Food Chemistry

Volumn 112, Issue 3, 2009, Pages 715-720

  Albertino, Andrea ^a   Barge, Alessandro ^a   Cravotto, Giancarlo ^a   Genzini, Luca ^a   Gobetto, Roberto ^a   Vincenti, Marco ^a  

^a UNIVERSITY OF TURIN   (Italy)

Author keywords

13C SNIF NMR; Ascorbic acid; EA IRMS; GC C IRMS

Indexed keywords

ASCORBIC ACID;

ARTICLE; EXTRACTION; FRUIT; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 49349113102     PISSN: 03088146     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.foodchem.2008.05.114     Document Type: Article

References (20)

1. Amarengo W.L.F., and Perrin D.D. Purification of laboratory chemicals (1998), Butterworth-Heinemann, Oxford
2. Coplen T.B. Reporting of stable hydrogen, carbon, and oxygen isotopic abundances. Pure and Applied Chemistry 66 (1994) 273-276
3. Coplen T.B. Reporting of stable hydrogen, carbon, and oxygen isotopic abundances. Geothermics 24 (1995) 708-712
4. Coplen T.B., Brand W.A., Gehre M., Groning M., Meijer H.A.J., Toman B., et al. After two decades a second anchor for the VPDB delta C-13 scale. Rapid Communications in Mass Spectrometry 20 (2006) 3165-3166
5. Davey M.W., Van Montagu M., Inze D., Sanmartin M., Kanellis A., Smirnoff N., et al. Plant L-ascorbic acid: chemistry, function, metabolism, bioavailability and effects of processing. Journal of the Science of Food and Agriculture 80 (2000) 825-860
6. De Wilt H.G.J. A gas chromatografic-mass study on TMS derivatives of sorbose, 2-ket-l-gulonic acid and ascorbic acid. Journal of Chromatography 63 (1971) 379-385
7. Deutsch J.C. Dehydroascorbic acid. Journal of Chromatography A 881 (2000) 299-307
8. EC Regulation No. 2676/90. Laying down analytical methods for the wine sector. Official Journal of European Communities L272 (1990) 64-73
9. Forina, M., Lanteri, S., Armanino, C., Casolino, C., & Casale, M. V-PARVUS (2007). An extendable package of programs for explorative data analysis, classification and regression analysis. Dip. Chimica e Tecnologie Farmaceutiche ed Alimentari, University of Genova. Free available at .
10. Gensler M., Rossmann A., and Schmidt H.L. Detection of added l-ascorbic-acid in fruit juices by isotope ratio mass-spectrometry. Journal of Agricultural and Food Chemistry 43 (1995) 2662-2666
11. Jones D.M., Carter J.F., Eglinton G., Jumeau E.J., and Fenwick C.S. Determination of delta-C-13 values of sedimentary straight chain and cyclic alcohols by gas-chromatography isotope ration mass-spectrometry. Biological Mass Spectrometry 20 (1991) 641-646
12. Klee M.S. In: Grob R.L. (Ed). Modern practice of gas chromatography. 2nd ed. (1985), Wiley, New York p. 187
13. Lee S.K., and Kader A.A. Pre-harvest and postharvest factors influencing vitamin C content of horticultural crops. Postharvest Biology and Technology 20 (2007) 207-220
14. Martin G.J., Martin M.L., Mabon F., and Michon M.J. A new method for the identification of the origin of ethanols in grain and fruit spirits: high field quantitative deuterium nuclear magnetic resonance at the natural abundance level. Journal of Agricultural and Food Chemistry 31 (1983) 311-315
15. Ogrinc N., Kosir I.J., Spangenberg J.E., and Kidric J. The application of NMR and MS methods for detection of adulteration of wine, fruit juices, and olive oil. A review. Analytical and Bioanalytical Chemistry 376 (2003) 424-430
16. Reid L.M., O'Donnell C.P., and Downey G. Recent technological advances for the determination of food authenticity. Trends in Food Science & Technology 17 (2006) 344-353
17. Rossmann A. Determination of stable isotope ratios in food analysis. Food Reviews International 17 (2001) 347-381
18. Tenailleau E., Lancelin P., Robins R.J., and Akoka S. NMR approach to the quantification of nonstatistical C-13 distribution in natural products: Vanillin. Analytical Chemistry 76 (2004) 3818-3825
19. Versini, C., Camin, F., Ziller, L., Frassanito, R., Mattivi, & F., Rossmann, A., (2005). Development of a novel method to analyse positional C13 values of ascorbic acid to detect undeclared addition of industrially produced vitamin C in fruit juices. In Poster, FASIS conference, Nantes.
20. Zhang B.L., Trierweiler M., Jouitteau C., and Martin G.J. Consistency of NMR and mass spectrometry determinations of natural-abundance site-specific carbon isotope ratios. The case of glycerol. Analytical Chemistry 71 (1999) 2301-2306