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We note, however, that in his pioneering studies of these repulsive hydration forces between mica surfaces, 19 Pashley reported that the CHC of caesium ions (above which hydration repulsion between mica surfaces was observed) was ca. 1 mM, well below the value at which we observe no hydration repulsion; we have no immediate explanation for this discrepancy (and in the case of the other alkali metal ions our results are generally in good agreement with the early Pashley experiments, 18 see inset to Fig. 3); we note that in other experiments from our group in caesium salt solutions, not shown, we occasionally observed short-ranged repulsion which we attributed to unidentified species adsorbed on the mica
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3 solution, in which far fewer measurements were taken; however, the apparently lower adhesion energy in the higher salt concentration may indicate that more Cs atoms condense on the surface from the 100 mM solution
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3 solution, in which far fewer measurements were taken; however, the apparently lower adhesion energy in the higher salt concentration may indicate that more Cs atoms condense on the surface from the 100 mM solution
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