A new five-membered ring forming process based on palladium(0)-catalyzed arylative cyclization of allenyl enones

Organic Letters

Volumn 10, Issue 13, 2008, Pages 2633-2636

  Tsukamoto, Hirokazu ^a   Kondo, Yoshinori ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ALKADIENE; ALLENE; PALLADIUM;

ALKYLATION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; OXIDATION REDUCTION REACTION; SYNTHESIS;

ALDEHYDES; ALKADIENES; ALKYLATION; CATALYSIS; CYCLIZATION; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PALLADIUM;

EID: 49149098334     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol800509z     Document Type: Article

References (44)

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37. 3.
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43. 13a (Chemical Equation Presented)
44. The difference results from the slower reductive elimination from π-allylpalladium(II) than that from σ-alkenylpalladium(II). β-Hydrogen elimination prior to reductive elmination would promote reductive cyclization of 7, leading to the formation of 8n and 8′n.