Reactivity of 13,13-dibromo-2,4,9,11-tetraoxadispiro[5.0.5.1]tridecane toward organolithiums: Remarkable resistance to the DMS rearrangement

Journal of Organic Chemistry

Volumn 73, Issue 15, 2008, Pages 5732-5744

  Eccles, Wendy ^a   Jasinski, Marcin ^a   Kaszynski, Piotr ^a   Zienkiewicz, Katarzyna ^a   Stulgies, Baldur ^a   Jankowiak, Aleksandra ^a  

^a VANDERBILT UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; BUTANE; CHEMICAL REACTIONS; CYCLOHEXANE; ETHERS; FULLERENES; HEALTH; LIQUEFIED PETROLEUM GAS; METHYLATION; NANOSTRUCTURES; NEGATIVE IONS; NONMETALS; OXYGEN; PROPANE; SULFUR COMPOUNDS;

ALLENES; CARBENE; CARBENES; CHEMICAL EQUATIONS; DFT CALCULATIONS; DIOXANE RINGS; ELECTROPHILIC CHARACTER; ELEVATED TEMPERATURES; INDUCTIVE EFFECTS; LUMO ENERGY; ORGANOLITHIUMS; OXYGEN ATOMS; POSITIVE CHARGES; REACTIVITY (CHEMICAL);

ACTIVATION ENERGY;

13,13 DIBROMO 2,4,9,11 TETRAOXADISPIRO[5.0.5.1]TRIDECANE; ALLENE DERIVATIVE; BICYCLO[1.1.0]BUTANE; BUTANE; CARBENOID; CARBON; CYCLOHEXANE; CYCLOPROPANE DERIVATIVE; DECANE; DIOXANE; HYDROGEN; LITHIUM; ORGANOLITHIUM COMPOUND; SPIRO COMPOUND;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DOERING MOORE SKATTEBOL REACTION; ENERGY; GAS CHROMATOGRAPHY; GEOMETRY; HIGH TEMPERATURE; MASS SPECTROMETRY; METHYLATION; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM MECHANICS; REACTION ANALYSIS; STRUCTURE ANALYSIS; THERMODYNAMICS;

EID: 48249139462     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo800054p     Document Type: Article

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