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0006989344
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For triplet sensitized isomerization of unsubstituted Dewar benzene, see
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For triplet sensitized isomerization of unsubstituted Dewar benzene, see: Turro, N. J.; Ramanurthy, V.; Katz, T. J. Nouv. J. Chem. 1977, 1, 363.
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Saltiel, J.; Wang, S.; Ko, D.-H.; Gormin, D. A. J. Phys. Chem. A 1998, 102, 5383.
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14
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48249158568
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The lack of this effect for the DETX-sensitized reactions is likely due to the higher concentration of DETX (∼4 wt , which will tend to favor energy transfer to nearby sensitizers (P*, S → P, S*) over energy transfer to nearby co-sensitizers (P*, C → P, C*) when ET(C) > ET(S) and [S] ≈ [C
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T(S) and [S] ≈ [C].
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16
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48249155265
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The measured rate constant for energy transfer, kq, from KC* to DB3 in ethyl acetate is 2 × 108 M -1 s-1. According to eq 9 in ref 4, kq, kd ket/ket, k-d, where ket is the first-order rate constant for triplet energy transfer in an encounter of KC* and DB3, kd is the rate constant for diffusional formation of the encounter/cage complex, and k-d is the rate constant for dissociation of the encounter/cage pair. Taking kd as 1.5 × 1010 M-1 s-1 and k-d as 3 × 1010 s-1 in ethyl acetate4 yields a value forint of 4 × 108 s-1. This value corresponds to the rate constant for triplet energy transfer within a solvent cage where KC* and DB
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-1.
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19
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0011454957
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A small amount of long-range resonance energy transfer allowed by the long KC* lifetime may also contribute to the larger action sphere: Anderson, R. W, Hochstrasser, R. M, Lutz, H, Scott, G. W J. Chem. Phys. 1974, 61, 2500
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A small amount of long-range resonance energy transfer allowed by the long KC* lifetime may also contribute to the larger action sphere: Anderson, R. W.; Hochstrasser, R. M.; Lutz, H.; Scott, G. W J. Chem. Phys. 1974, 61, 2500.
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3, which corresponds to a maximum action sphere radius of ∼13 Å.
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3, which corresponds to a maximum action sphere radius of ∼13 Å.
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48249138358
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Calculations of the weight percentages of reactants and co-sensitizers in the functionalized polymers are based on the fractional weight equivalent of the corresponding molecularly doped materials
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Calculations of the weight percentages of reactants and co-sensitizers in the functionalized polymers are based on the fractional weight equivalent of the corresponding molecularly doped materials.
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23
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48249123033
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U.S. Patent Application 2005136357 Al, June 23, 2005
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Farid, S. Y.; Robello, D. R.; Dinnocenzo, J. P.; Merkel, P. B.; Ferrar, L. S.; Roh, Y. U.S. Patent Application 2005136357 Al, June 23, 2005.
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